Effect of Pr-Ca substitution on the transport and magnetic behavior of LaMnO3 perovskite

The effect of simultaneous substitution of a fluctuating cation and a divalent cation in LaMnO₃ perovskite modifies the properties of the material to exhibit large valence colossal magnetoresistance (CMR) effect. A good example of these properties is (La_1−2x Pr _x Ca _x )MnO₃ (LPCMO) type CMR material. In this communication it is reported that, with the increase in x (for x=0.1, 0.15, 0.2), the T _c varies between 100 and 120 K with improvisation in metal-insulator transition. Interestingly, resistance increases with x from few hundred ohms to few kilo ohms with corresponding decrease in the unit cell volume. The results of the studies using X-ray diffraction (XRD), electrical resistivity, magnetoresistance and ac susceptibility measurements on LPCMO samples for understanding the structural, transport and magnetic properties are discussed in detail.     

Triol protection with 6-benzoyl-3,4-dihydro-(2H)-pyran

6-Benzoyl-3,4-dihydro-(2H)-pyran will protect 1,2,3-triols such as glycerol as their corresponding spiro-[5-phenyl-3,6,8-trioxabicyclo[3.2.1]octane-4,2[prime or minute]-tetrahydropyran]s and 1,2,4-triols (less efficiently) as the corresponding trioxabicyclo[3.2.2]nonanes; the hexol mannitol is converted into the corresponding bis-protected product.     

Measuring a cosmological distance-redshift relationship using only gravitational wave observations of binary neutron star coalescences

Detection of gravitational waves from the inspiral phase of binary neutron star coalescence will allow us to measure the effects of the tidal coupling in such systems. Tidal effects provide additional contributions to the phase evolution of the gravitational wave signal that break a degeneracy between the system's mass parameters and redshift and thereby allow the simultaneous measurement of both the effective distance and the redshift for individual sources. Using the population of O(10(3)-10(7)) detectable binary neutron star systems predicted for 3rd generation gravitational wave detectors, the luminosity distance-redshift relation can be probed independently of the cosmological distance ladder and independently of electromagnetic observations. We conclude that for a range of representative neutron star equations of state the redshift of such systems can be determined to an accuracy of 8%-40% for z<1 and 9%-65% for 1相似文献   

Cr(VI) Oxidation of Cholesterol—A Kinetic Study Using N-Cetylpicolinium Dichromates,A Class of Novel Phase Transfer Oxidants

Kinetics and Catalysis - Kinetic study of cholesterol oxidation has been studied using a series of N-cetylpicolinium dichromates (CPDC), a class of phase transfer oxidants, in acetic acid medium...     

A Photoaffinity Displacement Assay and Probes to Study the Cyclin‐Dependent Kinase Family

The CDK family plays a crucial role in the control of the cell cycle. Dysregulation and mutation of the CDKs has been implicated in cancer and the CDKs have been investigated extensively as potential therapeutic targets. Selective inhibition of specific isoforms of the CDKs is crucial to achieve therapeutic effect while minimising toxicity. We present a group of photoaffinity probes designed to bind to the family of CDKs. The site of crosslinking of the optimised probe, as well as its ability to enrich members of the CDK family from cell lysates, was investigated. In a proof of concept study, we subsequently developed a photoaffinity probe‐based competition assay to profile CDK inhibitors. We anticipate that this approach will be widely applicable to the study of small molecule binding to protein families of interest.     

Elastic properties of the Ta–V system: bcc Ta0.33V0.67 and C15 TaV2

Resonant ultrasound spectroscopy was used to measure the elastic constants of bcc Ta_0.33V_0.67 over the temperature range 3.5–300?K; the results were compared to earlier measurements on C15 TaV₂. The temperature dependence of the polycrystalline shear modulus is completely different in the two phases; that of the bcc phase decreases with temperature whereas that of the C15 phases increases in an anomalous fashion. This difference is consistent with a model involving doubly-degenerate levels at the X point of the Brillouin zone in the C15 phase with the Fermi level lying near the doubly degenerate level. This model accounted for the unusual behaviour of the C15 phase. Debye temperatures were determined from the ultrasonic measurements: 295?K for the C15 phase and 315?K for the bcc phase.     

Structural characteristics of different types of nanoparticles synthesised in mesomorphic metal alkanoates

The class of thermotropic ionic liquid crystals (LCs) of the metal alkanoates possesses a number of unique properties, such as intrinsic ionic conductivity, high dissolving ability and ability to form time-stable mesomorphic glasses. These ionic LCs can be used as nanoreactors for the synthesis and stabilisation of different types of nanoparticles (NPs). Thus, some semiconductors, metals and core/shell NPs were chemically synthesised in the thermotropic ionic liquid crystalline phase (smectic A) of the cadmium octanoate (CdC₈) and of the cobalt octanoate (CoC₈). By applying the scanning electron microscopy, the cadmium and cobalt octanoate composites containing CdS, Au, Ag and core/shell Au/CdS NPs have been studied. NPs’ sizes and dispersion distribution of the NPs’ size in the nanocomposites have been obtained.     

Irradiation of a cone by a magnetic dipole

Th electromagnetic field produced by a magnetic dipole in thepresence of a perfectly conducting cone of arbitrary cross-sectionis determined. The solution is used to find out how a currenton the cone travelling towards the apex is reflected. Some valuesof the reflection coefficient are calculated. In particular,it is shown that there is a sort of resonance with the reflectionincreasing significantly as the cone approaches a plane.     

Robertson-Walker Fluid Sources Endowed with Rotation Characterised by Quadratic Terms in Angular Velocity Parameter

Einstein's equations for a Robertson-Walker fluid source endowed with rotation are presented up to and including quadratic terms in angular velocity parameter. A family of analytic solutions are obtained for the case in which the source angular velocity is purely time-dependent. A subclass of solutions is presented which merge smoothly to homogeneous rotating and non-rotating central sources. The particular solution for dust endowed with rotation is presented. In all cases explicit expressions, depending sinusoidally on polar angle, are given for the density and internal supporting pressure of the rotating source. In addition to the non-zero axial velocity of the fluid particles it is shown that there is also a radial component of velocity which vanishes only at the poles. The velocity four-vector has a zero component between poles.     

Letter: Slowly Rotating, Compact Fluid Sources Embedded in Kerr Empty Space-Time

Spherically symmetric static fluid sources are endowed with rotation and embedded in Kerr empty space-time up to and including quadratic terms in an angular velocity parameter using Darmois junction conditions. The boundary behaviour of the metric tensor and partial derivatives is used to develop a series solution of Einstein's equation's for the rotating fluid. The boundary of the rotating source is expressed explicitly in terms of sinusoidal functions of the polar angle. As an example of the analysis the Schwarzschild interior solution is endowed with rotation and the equation of the fluid boundary is generated together with surface behaviour of the fluid density and angular velocity.