全文获取类型
收费全文 | 4067篇 |
免费 | 108篇 |
国内免费 | 13篇 |
专业分类
化学 | 3123篇 |
晶体学 | 10篇 |
力学 | 63篇 |
数学 | 594篇 |
物理学 | 398篇 |
出版年
2021年 | 36篇 |
2020年 | 35篇 |
2019年 | 37篇 |
2016年 | 68篇 |
2015年 | 75篇 |
2014年 | 78篇 |
2013年 | 159篇 |
2012年 | 124篇 |
2011年 | 128篇 |
2010年 | 91篇 |
2009年 | 85篇 |
2008年 | 112篇 |
2007年 | 128篇 |
2006年 | 151篇 |
2005年 | 143篇 |
2004年 | 123篇 |
2003年 | 125篇 |
2002年 | 124篇 |
2001年 | 81篇 |
2000年 | 61篇 |
1999年 | 62篇 |
1998年 | 67篇 |
1997年 | 52篇 |
1996年 | 73篇 |
1995年 | 56篇 |
1994年 | 60篇 |
1993年 | 66篇 |
1992年 | 78篇 |
1991年 | 78篇 |
1990年 | 56篇 |
1989年 | 82篇 |
1988年 | 68篇 |
1987年 | 82篇 |
1986年 | 68篇 |
1985年 | 94篇 |
1984年 | 100篇 |
1983年 | 59篇 |
1982年 | 92篇 |
1981年 | 78篇 |
1980年 | 74篇 |
1979年 | 91篇 |
1978年 | 68篇 |
1977年 | 79篇 |
1976年 | 63篇 |
1975年 | 55篇 |
1974年 | 72篇 |
1973年 | 47篇 |
1972年 | 22篇 |
1971年 | 41篇 |
1970年 | 23篇 |
排序方式: 共有4188条查询结果,搜索用时 15 毫秒
1.
2.
Julia K Pruns Jens-Peter Vietzke Manfred Strassner Claudius Rapp Ulrich Hintze Wilfried A K?nig 《Rapid communications in mass spectrometry : RCM》2002,16(3):208-211
A new solvent-free sample preparation method using silver trifluoroacetate (AgTFA) was developed for the analysis of low molecular weight paraffins and microcrystalline waxes by laser desorption/ionization time-of-flight mass spectrometry (LDI-TOFMS). Experiments show that spectral quality can be enhanced by dispersing AgTFA directly in liquid paraffins without the use of additional solvents. This preparation mixture is applied directly to the MALDI probe. Solid waxes could be examined by melting prior to analysis. The method also provides sufficiently reproducible spectra that peak area ratios between mono- and bicyclic alkane peaks indicated variations in the cycloalkane content of paraffin samples. Dehydrogenation of hydrocarbons observed during the desorption/ionization process was studied by analysis of alkane standards. 相似文献
3.
4.
The control of piecewise-deterministic processes is studied where only local boundedness of the data is assumed. Moreover the discount rate may be zero. The value function is shown to be solution to the Bellman equation in a weak sense; however the solution concept is strong enough to generate optimal policies. Continuity and compactness conditions are given for the existence of nonrelaxed optimal feedback controls. 相似文献
5.
The contributions to the coefficient functions of the quark and the mixed quark-gluon condensate to mesonic correlators are calculated for the first time to all orders in the quark masses, and to lowest order in the strong coupling constant. Existing results on the coefficient functions of the unit operator and the gluon condensate are reviewed. The proper factorization of short- and long-distance contributions in the operator product expansion is discussed in detail. It is found that to accomplish this task rigorously the operator product expansion has to be performed in terms ofnon-normal-ordered condensates. The resulting coefficient functions are improved with the help of the renormalization group. The scale invariant combination of dimension 5 operators, including mixing with the mass operator, which is needed for the renormalization group improvement, is calculated in the leading order.Supported by the German Bundesministerium für Forschung und Technologie, under the contract 06 TM 761 相似文献
6.
Manfred Sommer 《Constructive Approximation》2006,23(2):211-227
Hermite interpolation of 2n + k data by spline spaces of order k with n variable knots counting multiplicities is studied.
A characterization of the minimal spline spaces which admit a solution of the interpolation problem is obtained. A sufficient
condition on uniqueness of interpolating spline functions is given. 相似文献
7.
8.
Arthur G. Maki John C. Grecu Brenda Winnewisser Manfred Winnewisser 《Journal of Molecular Spectroscopy》2003,222(2):198-212
High-resolution spectra of 15N12C12C15N and 14N13C13C14N have been measured and analyzed from 200 to 3600 cm−1. All the vibrational levels below 900 cm−1 have been observed and characterized. The Fermi resonance between ν2 and 2ν4 has been studied and the resonance constant has been determined for several cases. Several Σ− states have been directly observed for the first time for each isotopomer, the (0001111)0f, (0011111)0f, and (0002222)0f states. The pattern of the energy levels for clusters of l-type resonance coupled levels, such as 0001131,3, has been determined for cyanogen for the first time. Among other things this involved the determination of the vibrational l-type resonance constant, r45. Many of the power series constants, αi and xij, and higher order constants have been determined. 相似文献
9.
Ulf Pindur Ludwig Pfeuffer Manfred Eitel Martina Rogge Manfred Haber 《Monatshefte für Chemie / Chemical Monthly》1991,122(4):291-298
Summary Diels-Alder reactions of 2- and 3-vinylindoles with aryne, 1,4-benzo- and 1,4-naphtho-quinone lead to new six-ring annellated carbazoles. Molecular modeling studies predict that the compounds with coplanar framework are able to intercalate with the B-DNA. 相似文献
10.
Manfred Brun Peter Hubner Dieter Oelkrug 《Fresenius' Journal of Analytical Chemistry》1992,344(4-5):209-213
Summary A theoretical model is derived that describes the influence of lateral light diffusion in a scattering medium on the absorptivity of an absorber spot on top of the substrate. The model uses the lateral resolved reflectivity under point irradiation that has been analyzed experimentally with a scanning-micro-laser-reflectometer. The model allows quantification of the absorptivity by one single equation that contains only the mean radial diffusion length of light and the spot area. Experiment and theory are applied to typical substrates for thin layer chromatography (alumina, silica, cellulose). The diffusion lengths in these substrates are given and the absorptivities of the spots are calculated as a function of the spot area. 相似文献