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Lumduan Mangsup Sutatip Siripaisarnpipat Narongsuk Chaichit 《Analytical sciences》2003,19(9):1345-1346
The reaction between CoCl2 x 6H2O and 2-1-(2-thiazolylazo)-p-cresol (TAC) in acetone resulted in six coordinated cobalt(III) complex, [Co(TAC)2]Cl3. Two TAC ligands coordinate with cobalt ion forming four five membered chelate rings. The cobalt ion is octahedrally coordinated by a phenolic oxygen, azo nitrogen and nitrogen in thiazole rings. Three chloride ions are disordered. 相似文献
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