Bioaccumulation and excretion of arsenic compounds by a marine unicellular alga,polyphysa peniculus

Polyphysa peniculus was grown in artificial seawater in the presence of arsenate, arsenite, monomethylarsonate and dimethylarsinic acid. The separation and identification of some of the arsenic species produced in the cells as well as in the growth medium were achieved by using hydride generation–gas chromatography–atomic absorption spectrometry methodology. Arsenite and dimethylarsinate were detected following incubation with arsenate. When the alga was treated with arsenite, dimethylarsinate was the major metabolite in the cells and in the growth medium; trace amounts of monomethylarsonate were also detected in the cells. With monomethylarsonate as a substrate, the metabolite is dimethylarsinate. Polyphysa peniculus did not metabolize dimethylarsinic acid when it was used as a substrate. Significant amounts of more complex arsenic species, such as arsenosungars, were not observed in the cells or medium on the evidence of flow injection–microwave digestion–hydride generation–atomic absorption spectrometry methodology. Transfer of the exposed cells to fresh medium caused release of most cell–associated arsenicals to the surrounding environment.     

Orientation and relaxation of polymer–clay solutions studied by rheology and small-angle neutron scattering

The influence of shear on viscoelastic solutions of poly(ethylene oxide) (PEO) and clay [montmorillonite, i.e., Cloisite NA+ (CNA)] was investigated with rheology and small-angle neutron scattering (SANS). The steady-state viscosity and SANS were used to measure the shear-induced orientation and relaxation of the polymer and clay platelets. Anisotropic scattering patterns developed at much lower shear rates than in pure clay solutions. The scattering anisotropy saturated at low shear rates, and the CNA clay platelets aligned with the flow, with the surface normal parallel to the gradient direction. The cessation of shear led to partial and slow randomization of the CNA platelets, whereas extremely fast relaxation was observed for laponite (LRD) platelets. These PEO–CNA networklike solutions were compared with previously reported PEO–LRD networks, and the differences and similarities, with respect to the shear orientation, relaxation, and polymer–clay interactions, were examined. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3102–3112, 2004     

Multi-State Second-Order Nonlinear Optical Switches Incorporating One to Three Benzazolo-Oxazolidine Units: A Quantum Chemistry Investigation

This contribution employs quantum chemistry methods to describe the variations of the second nonlinear optical responses of molecular switches based on benzazolo-oxazolidine (BOX) units, connected by π-linkers, along their successive opening/closing. Under the fully closed forms, all of them display negligible first hyperpolarizability (β) values. When one BOX is opened, which is sketched as C→O, a push–pull π-conjugated segment is formed, having the potential to enhance β and to set the depolarization ratio (DR) to its one-dimensional-like value (DR = 5). This is observed when only one BOX is open, either for the monoBOX species (C→O) or for the diBOX (CC→CO) and triBOX (CCC→CCO) compounds, i.e., when the remaining BOXs stay closed. The next BOX openings have much different effects. For the diBOXs, the second opening (CO→OO) is associated with a decrease of β, and this decrease is tuned by controlling the conformation of the π-linker, i.e., the centrosymmetry of the whole compound because β vanishes in centrosymmetric compounds. For the triBOXs, the second opening gives rise to a Λ-shape compound, with a negligible change of β, but a decrease of the DR whereas, along the third opening, β remains similar and the DR decreases to the typical value of octupolar systems (DR = 1.5).     

Uncertainty quantification in a chemical system using error estimate-based mesh adaption

This paper describes a rigorous a posteriori error analysis for the stochastic solution of non-linear uncertain chemical models. The dual-based a posteriori stochastic error analysis extends the methodology developed in the deterministic finite elements context to stochastic discretization frameworks. It requires the resolution of two additional (dual) problems to yield the local error estimate. The stochastic error estimate can then be used to adapt the stochastic discretization. Different anisotropic refinement strategies are proposed, leading to a cost-efficient tool suitable for multi-dimensional problems of moderate stochastic dimension. The adaptive strategies allow both for refinement and coarsening of the stochastic discretization, as needed to satisfy a prescribed error tolerance. The adaptive strategies were successfully tested on a model for the hydrogen oxidation in supercritical conditions having 8 random parameters. The proposed methodologies are however general enough to be also applicable for a wide class of models such as uncertain fluid flows.     

Growth Rates and Explosions in Sandpiles

We study the abelian sandpile growth model, where n particles are added at the origin on a stable background configuration in ? ^d . Any site with at least 2d particles then topples by sending one particle to each neighbor. We find that with constant background height h≤2d?2, the diameter of the set of sites that topple has order n ^1/d . This was previously known only for h<d. Our proof uses a strong form of the least action principle for sandpiles, and a novel method of background modification. We can extend this diameter bound to certain backgrounds in which an arbitrarily high fraction of sites have height 2d?1. On the other hand, we show that if the background height 2d?2 is augmented by 1 at an arbitrarily small fraction of sites chosen independently at random, then adding finitely many particles creates an explosion (a sandpile that never stabilizes).     

Twistor Actions for Self-Dual Supergravities

We give holomorphic Chern-Simons-like action functionals on supertwistor space for self-dual supergravity theories in four dimensions, dealing with supersymmetries, the cases where different parts of the R-symmetry are gauged, and with or without a cosmological constant. The gauge group is formally the group of holomorphic Poisson transformations of supertwistor space where the form of the Poisson structure determines the amount of R-symmetry gauged and the value of the cosmological constant. We give a formulation in terms of a finite deformation of an integrable -operator on a supertwistor space, i.e., on regions in . For , we also give a formulation that does not require the choice of a background.     

Multiscale laminar flows with turbulentlike properties

By applying fractal electromagnetic force fields on a thin layer of brine, we generate steady quasi-two-dimensional laminar flows with multiscale stagnation point topology. This topology is shown to control the evolution of pair separation (Delta) statistics by imposing a turbulentlike locality based on the sizes and strain rates of hyperbolic stagnation points when the flows are fast enough, in which case Delta(2) approximately t(gamma) is a good approximation with gamma close to 3. Spatially multiscale laminar flows with turbulentlike spectral and stirring properties are a new concept with potential applications in efficient and microfluidic mixing.     

β-Phosphorus Hyperfine Coupling Constant in Nitroxides: Conformational Effects in 6-Membered Ring Nitroxides

Recently, we reported a significant solvent effect on the phosphorus hyperfine coupling constant a _P in β-phosphorylated 6-membered ring nitroxides (?a _P = 24 G in Org. Biomol. Chem. 2015). Thus, it led us to investigate the effect of solvent for several 6-membered ring nitroxides. Although smaller than mentioned above, a change of 5–7 G in a _P with the polarity of solvent was still observed for these nitroxides. As for other β-phosphorylated nitroxides, a _N increases with the polarity/polarizability π* and the Hydrogen Bond Donating α properties of the solvent whereas a _P exhibits the reverse trends. The change of a _P with the solvent depends a lot on a subtle interplay between the destabilizing steric hindrance due to the bulkiness of the substituents and the stabilizing hyperconjugation interactions SOMO → σ*_C–P between the anti-bonding orbitals of the C–P bond and the SOMO.     

Realization of single-mode telluride rib waveguides for mid-IR applications between 10 and 20 μm

The feasibility of all-telluride integrated optics devices based on waveguides presenting a single-mode behavior in the spectral range (10-20 μm) is demonstrated. These waveguides are constituted of a several micrometer thick Te(82)Ge(18) film deposited onto a Te(75)Ge(15)Ga(10) bulk glass substrate by thermal coevaporation and further etched by reactive ion etching under the CHF(3)/O(2)/Ar atmosphere. The obtained structures were proven to behave as channel waveguides with a good single-mode transmission over the whole spectral range. These results allowed validating our technological solution for the fabrication of integrated optics modal filters for spatial interferometry.     

Lossless strip-to-slot waveguide transformer

We present a highly efficient integratable waveguide transformer that is capable of converting Gaussian-like waveguide modes to much more complicated non-Gaussian-like slot-waveguide modes, and vice versa. The structure consists of several pairs of complementary tapers capable of making this mode conversion virtually lossless. The capability of extremely low-loss mode transformation between these two classes of waveguides has been demonstrated by means of single- and double-slot transformers. Our simulation has shown that the total transformation losses are less than 0.01 and 0.02 dB per transformer, respectively, and can be easily achieved, with a total device length of less than 100 microm.