复杂系统的泛系聚类方法

本文利用半等价算子ε_i和相等化算子δ_i研究了复杂系统的聚类问题;阐述了分析运筹复杂系统的δ(1,3)解耦原理、对偶转化原理和大系统分解原理;详细讨论了复杂系统的连通性与解耦性并提供了有关定理.最后,利用泛系聚类方法讨论了复杂系统的层次分析.     

Operation analysis of natural resources and their pan-weighted network models

In this paper, we propose a competition-share 3-category principle, on which we unite the problems of natural resources, energy, population and environment and so on into a mutual scheme, and provide a united model for the comprehensive research on these problems. This makes the idea of operation analysis of natural resources clearer and the relationships between each of their parts more obvious. On the basis of the above discussion, we propose mathematical models for the operation analysis of multi-networks and the solution of the above global comprehensive problems. We discuss, especially, Shengke (growth and restraint) relationships between two networks of natural resources and share-competitors and their analysis models, providing mathematical tools for solving the problems of the resource-population and the resource-economy, etc. Supported by Science Fund of Lanzhou University.     

STUDY ON THE COMPLICATED DYNAMICAL BEHAVIORS OF NONLINEAR ECOSYSTEM (Ⅰ)

This series of papers is prepared to develop systematically the complicated dynamical behaviors of nonlinear ecosystem and its internal mechanism. In this paper, we state briefly the increasing importance of ecology, describe and comment on the situations and reasons why ecology theory is behind practice. Then, we point out a procedure which modern ecology research should obey, and discuss the four basic characteristics of ecosystem in detail: level, opening, nonlinear and far from equilibrium. At last, we discuss systematically equilibrium and nonequilibrium, stable and unstable, environmental stochasticity and dynamical stochasticity, and conclude that there exists a bridge between deterministic behaviors and stochastic behaviors, which will result in a new model for ecological prediction.Supported by Youth Fund of Chinese Academy of Science and Youth Fund of Lanzhou University.     

CCD与CMOS像素传感器γ射线电离辐射响应特性对比研究

为了研究CCD与CMOS像素传感器对γ射线电离辐射的响应差异,对比研究了4类像素传感器的结构特点和辐射响应特性。通过辐射实验,对各传感器在不同辐射水平条件下的光子响应事件分布、平均灰度值以及典型光子响应事件进行研究。研究结果表明：光子响应程度均与辐射剂量率相关;CCD像素传感器的沟道传输方式使每列像元间的辐射响应更容易相互干扰;平均灰度值随剂量率的增大存在明显的梯度,各积分周期内输出信号灰度值围绕均值上下波动,CCD像素传感器输出信号灰度浮动范围较小;CMOS像素传感器各像元对光子的响应更加明显,CCD像素传感器各像元的响应信号易与相邻像元发生串扰;各类像素传感器典型辐射响应事件区域中发生光子响应的像元数量随剂量率的增大而增多,响应事件并非单个光子的行为,而是反映了多个光子在区域内同时沉积能量的过程。本研究为开发像素传感器的γ射线辐射探测技术和应用提供了重要的理论分析和实验数据支撑。     

ICP-MS测定血中镁、铜、铅浓度时的基体效应单一内标校正方法研究

ICP-MS测定模拟全血基体中不同质量段的Mg, Cu, Pb元素,考察基体效应对测定值的影响,分别采用传统内标法和单一内标CAIS方法(common analyte internal standardization)对其进行校正和比较。结果表明CAIS方法适用于不同浓度血液基体中多种元素的同时校正,且效果良好,其相对平均误差仅为3.05%,明显低于传统内标法的12.39%和校正前的23.91%;CAIS方法不受内标元素和被测元素质量数差异、测定强度差异以及电极电位差异的限制;使用全血和血清标准物质对CAIS方法可靠性进行验证,测定值全部落在标准值范围内。     

Copper‐Catalyzed Aerobic Oxidative Reaction of Sulfonyl Hydrazides with Alcohols: An Easy Access to Sulfinates

A Cu‐catalyzed aerobic oxidative reaction between sulfonyl hydrazides and alcohols has been developed. In this reaction, sulfonyl hydrazides act as the sulfinic acid precursors to react with alcohols, resulting in sulfinic esters with up to 72 % yield. This catalytic system tolerates a wide range of sulfonyl hydrazide substrates, and represents a new strategy for the transformation of readily available sulfonyl hydrazides.     

Synthesis of a Novel Phosphorus-Containing Curing Agent and Its Effects on the Flame Retardancy,and Thermal Stability of Epoxy Resins

Russian Journal of Applied Chemistry - A novel curing agent containing phosphorus and carboxyl group compound diphenyl(2,3-dicarboxylpropyl)phosphine oxide (DPDCPPO) was synthesized and used as a...     

高效液相色谱三元梯度分离法测定大气中11种醛酮类化合物的研究

研究选择了以２,４－二硝基苯肼衍生化三元梯度洗脱的高效液相色谱测定大气中１１种醛酮类化合物的最佳色谱分离条件,醛酮类化合物的检出限０．４５到２．０４ｎｇ,各化合物保留时间和相对标准偏差ｓ,≤０．３８％在所测定的含量范围内具有很好的线性关系,每种化合物的相关系数均大于０．９９９;研究了涂敷２,４－二硝基苯肼硅胶吸附采样夹的制作方法,并应用于大气环境中醛酮类化合物的分析。方法简单、快速,１１种醛酮类化     

Antibacterial triterpenoids from the leaves of Ilex hainanensis Merr.

One new triterpenoid (1) and seven known analogues (2–8) were isolated from the leaves of Ilex hainanensis Merr.. Their structures were established by analysis of their MS, 1D and 2D NMR spectroscopic data and comparison with those in the literature. The antibacterial activity of compounds 1–8 were evaluated by determination of minimum inhibitory concentration using twofold microdilution broth method against Streptococcus mutans ATCC 25175 (Gram-positive) and Fusobacterium nucleatum ATCC 10953 (Gram-negative). Compounds 3 and 5 showed significant antibacterial activity against S. mutans in concentration of 9.7 μg/mL, while showed little antibacterial activity against F. nucleatum. On the contrary, the inhibitory activity of compounds 1, 2 and 6 against F. nucleatum were higher than them against S. mutans.