全文获取类型
收费全文 | 350篇 |
免费 | 15篇 |
国内免费 | 1篇 |
专业分类
化学 | 315篇 |
晶体学 | 1篇 |
力学 | 1篇 |
数学 | 18篇 |
物理学 | 31篇 |
出版年
2023年 | 6篇 |
2022年 | 9篇 |
2021年 | 9篇 |
2020年 | 14篇 |
2019年 | 14篇 |
2018年 | 8篇 |
2017年 | 17篇 |
2016年 | 23篇 |
2015年 | 28篇 |
2014年 | 22篇 |
2013年 | 33篇 |
2012年 | 17篇 |
2011年 | 25篇 |
2010年 | 13篇 |
2009年 | 14篇 |
2008年 | 29篇 |
2007年 | 15篇 |
2006年 | 13篇 |
2005年 | 4篇 |
2004年 | 5篇 |
2003年 | 4篇 |
2002年 | 2篇 |
2001年 | 3篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1994年 | 1篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1982年 | 8篇 |
1981年 | 6篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1956年 | 2篇 |
1955年 | 1篇 |
1929年 | 1篇 |
排序方式: 共有366条查询结果,搜索用时 0 毫秒
1.
Accumulation of five heavy metal ions by five species of wood-rotting basidiomycetes during a 9-day cultivation was studied. Contents of Cd, Cu, Pb, and Zn were measured using ICP-MS; the amount of mercury was determined directly in solid samples using the Advanced Mercury Analyser. A standard operation procedure for the sample preparation and determination of metal content was developed and validated. Presence of Cd, Cu, Hg, and Pb decreased the accumulation of zinc by the fungi. The basidiomycete Pycnoporus cinnabarinus exhibited the highest metal binding capacity of all fungi tested. 相似文献
2.
Glass capillary columns have been prepared without acidic additive in the stationary phase, from which free organic acids elute as sharp and symmetrical peaks. The required surface in the borosilicate glass capillary was generated by a combination of leaching with aqueous HCl and deposition of colloidal silica particles; it can be coated with stationary phases have a broad range of polarity. Aqueous samples containing free organic acids can also be analyzed in such columns in an isothermal mode. 相似文献
3.
Stationary phase containing quinolin-8-ol immobilized on macroporous methacrylate support for the affinity chromatography of porcine pepsin A is described. Optimized chromatographic conditions for separation of porcine pepsin A on this stationary phase were found investigating the influence of pH, concentration, ionic strength and chemical composition of the used mobile phases. The stationary phase shows a good reproducibility of chromatographic analyses (relative standard deviation, +/-2%), a high recovery (ca. 93%) and a satisfactory capacity (13 mg pepsin A/1 mL stationary phase) for porcine pepsin A. The obtained findings confirm the applicability of affinity chromatography on the stationary phase with immobilized quinolin-8-ol to the isolation and determination of porcine pepsin A. 相似文献
4.
Kolárová L Holcapek M Jambor R Dostál L Nádvorník M Růzicka A 《Journal of mass spectrometry : JMS》2004,39(6):621-629
Electrospray ionization (ESI) mass spectrometry was applied to the structural analysis of 23 2,6-[bis(alkyloxy)methyl]phenyltin(IV) derivatives. The mass spectra were measured in both polarity modes and multistage tandem mass spectrometric (MS(n)) measurements were performed on the ion trap analyser for positively charged tin-containing ions. The sum of complementary ions observed in the positive-ion mode (i.e. [M-R(3)](+) ion) and in the negative-ion mode (i.e. [R(3)](-) ion) permits molecular mass determination in spite of the fact that the molecular adducts were often missing even in the first-order mass spectra. The subsequent fragmentation of [M-R(3)](+) ions studied by MS(n) and the correlation of observed fragment ions with the expected structures of synthesized organotin(IV) compounds allowed us to understand the fragmentation behaviour and the mechanism of the ion formation for studied compounds. The typical neutral losses are alkenes, alcohols and aldehydes. The fragmentation pattern of one selected compound was supported by MS(n) measurements of an isotopically labelled analogue to confirm unusual ion-molecule reactions of some fragment ions with water in the ion trap. 相似文献
5.
Nrusingha C. Pati Subasini Lenka Padma L. Nayak Trijama R. Mohanty 《Journal of polymer science. Part A, Polymer chemistry》1978,16(2):343-351
The aqueous polymerization of acrylonitrile initiated by an acidified bromate–thiourea redox system has been studied under nitrogen atmosphere. The rate of polymerization is independent of thiourea concentration over the range 2–9 × 10?3M and reaches maximum at 9 × 10?3M. The rate varies linearly with [monomer]. The initial rate of polymerization as well as the maximum conversion increases within the range of 4–22.5 × 10?3M KBrO3, but beyond 22.5 × 10?3M the rate of polymerization decreases. The initial rate and the limiting conversion increases with increasing polymerization temperature in the range 30–45°C; and beyond 45°C they decrease. The effect of certain neutral salts, water-soluble solvents, and micelles of cationic, anionic, and nonionic surfactants on the rate of polymerization has been investigated. 相似文献
6.
Graft copolymerization of methyl methacrylate onto wool was investigated in aqueous solution using the potassium peroxy-diphosphate-thiourea redox system as the initiator. The rate of grafting was determined by varying the monomer, peroxydi-phosphate ion, temperature, and solvent. The graft yield increases with increasing peroxydiphosphate ion up to 80 × 10?-4 mol/L, and with further increase of peroxydiphosphate ion the graft yield decreases. The graft yield increases with increasing monomer concentration. The percentage of grafting decreases with increasing thiourea concentration. The rate of grafting increases with an increase of temperature. The effect of acid and water-soluble solvent and certain salts on graft yield has been investigated and a suitable rate expression has been derived. 相似文献
7.
Lenka Blažková Lenka Malinová Václava Benešová Jan Roda Jiří Brožek 《Journal of polymer science. Part A, Polymer chemistry》2017,55(13):2203-2210
A successful preparation of polyamide 4 nanofibers via electrostatic spinning with diameters close to 100 nm is described. Polyamide 4 was prepared by the anionic ring‐opening polymerization of 2‐pyrrolidone and characterized. The effect of the system parameters (i.e., molar mass of the polymer, the solvent system) and the process parameters (i.e., the electrode‐to‐collector distance) during the electrostatic spinning have been studied. The morphology of the polyamide 4 fiber layers is given except molar mass of the polymer and the concentration of its solution primarily by the conformation of polyamide chains due to polyelectrolyte effect which was confirmed by viscosity measurements. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 2203–2210 相似文献
8.
9.
Kinshuk Dasgupta D. Sen T. Mazumdar R. K. Lenka R. Tewari S. Mazumder J. B. Joshi S. Banerjee 《Journal of nanoparticle research》2012,14(3):728
For the first time, bamboo-shaped multiwalled carbon nanotubes, having diameter of the order of 50 nm, have been grown on
carbon black in a fluidized bed in bulk amount. The activation energy for the synthesis of the product was found out to be
around 33 kJ/mol in the temperature range of 700−900 °C. The carbon nanotubes were separated from the carbon black by preferential
oxidation of the later, the temperature of which was determined by thermogravimetry. The transmission electron microscopy
revealed different features of the nanotubes such as “Y” junction, bend, and catalyst filling inside the nanotubes. Small
angle neutron scattering was performed on the nanotubes synthesized at different temperatures. The data were fitted into a
suitable model in order to find out the average diameter, which decreases with increase in synthesis temperature. The Monte
Carlo simulation predicts the same behavior. Based on the above observations, a possible growth mechanism has been predicted.
The oscillation in carbon saturation value inside the catalyst in the fluidized bed has been indicated as the responsible
factor for the bamboo-shaped structure. 相似文献
10.