全文获取类型
收费全文 | 1200篇 |
免费 | 30篇 |
国内免费 | 10篇 |
专业分类
化学 | 790篇 |
晶体学 | 77篇 |
力学 | 15篇 |
数学 | 79篇 |
物理学 | 279篇 |
出版年
2023年 | 13篇 |
2022年 | 23篇 |
2021年 | 16篇 |
2020年 | 13篇 |
2019年 | 33篇 |
2018年 | 33篇 |
2017年 | 34篇 |
2016年 | 34篇 |
2015年 | 40篇 |
2014年 | 55篇 |
2013年 | 102篇 |
2012年 | 64篇 |
2011年 | 93篇 |
2010年 | 46篇 |
2009年 | 49篇 |
2008年 | 77篇 |
2007年 | 47篇 |
2006年 | 46篇 |
2005年 | 28篇 |
2004年 | 30篇 |
2003年 | 27篇 |
2002年 | 36篇 |
2001年 | 18篇 |
2000年 | 17篇 |
1999年 | 13篇 |
1998年 | 6篇 |
1997年 | 9篇 |
1996年 | 15篇 |
1995年 | 10篇 |
1994年 | 10篇 |
1993年 | 12篇 |
1992年 | 17篇 |
1991年 | 15篇 |
1990年 | 14篇 |
1989年 | 6篇 |
1988年 | 7篇 |
1987年 | 8篇 |
1986年 | 10篇 |
1985年 | 13篇 |
1984年 | 21篇 |
1983年 | 18篇 |
1982年 | 9篇 |
1981年 | 7篇 |
1980年 | 5篇 |
1979年 | 4篇 |
1978年 | 8篇 |
1977年 | 4篇 |
1976年 | 7篇 |
1975年 | 4篇 |
1974年 | 6篇 |
排序方式: 共有1240条查询结果,搜索用时 0 毫秒
1.
M. Suresh Babu 《Tetrahedron letters》2004,45(42):7969-7970
Reduction of 2-aryl-oxazolines with NiCl2/NaBH4 followed by hydrolysis gives the corresponding aldehydes in good yields. 相似文献
2.
Summary The paper addresses the problem of the implementation of nonhomogeneous essential Dirichlet type boundary conditions in thep-version of the finite element method.Partially supported by the Office of Naval Research under Grant N-00014-85-K-0169Research partially supported by the Air Force Office of Scientific Research, Air Force Systems Command, USAF, under Grant Number AFOSR 85-0322 相似文献
3.
4.
5.
6.
Treatment of the bis(allylsulfoximine)titanium complexes derived from the beta-methyl-substituted acyclic allylic sulfoximines 13a and 13b with aldehydes gave with high selectivities the corresponding sulfoximine-substituted homoallylic alcohols which were isolated as the silyl ethers 15a-h. Methylation of sulfoximines 15a-h afforded the aminosulfoxonium salts 5a-h which upon treatment with LiN(H)tBu gave in high yields the enantio- and diastereomerically pure silyl-substituted 2,3-dihydrofurans 4a-h. Treatment of the titanium complexes derived from the cyclic allylic sulfoximines 17a, 17b, and ent-17c with p-MeOC(6)H(4)CHO delivered with high selectivities the corresponding sulfoximine-substituted cyclic homoallylic alcohols which were isolated as the silyl ethers 18a, 18b, and ent-18c, respectively. Methylation of sulfoximines 18a, 18b, and ent-18c furnished the aminosulfoxonium salts 8a, 8b, and ent-8c, respectively, whose treatment with LiN(H)t-Bu gave the enantio- and diastereomerically pure fused bicyclic 2,3-dihydrofurans 6a, 6b, and ent-6c, respectively, in good yields. It is proposed that the 1-alkenyl aminosulfoxonium salts 5a-h, 8a, 8b, and ent-8c react with the base under alpha-elimination and formation of the acyclic and cyclic beta-silyloxy alkylidene carbenes 2a-h, 7a, 7b, and ent-7c, respectively, which then undergo a 1,5-O,Si-bond insertion and 1,2-silyl migration. The cyclic aminosulfoxonium salts 8a, 8b, and ent-8c upon treatment with 1,8-diazabicyclo[5.4.0]-7-undecene did not undergo an alpha-elimination but suffered a novel migratory cyclization with formation of the enantio- and diastereomerically pure bicyclic tetrahydrofurans 9a, 9b, and ent-9c, respectively. It is proposed that the 1-alkenyl sulfoxonium salts 8a, 8b, and ent-8c are isomerized to the allylic aminosulfoxonium salts 10a, 10b, and ent-10c, respectively, which then suffer an intramolecular substitution of the (dimethylamino)sulfoxonium group by the silyloxy group followed by a desilylation. The syntheses of the 2,3-dihydrofurans 4a-h, 6a, and 6b and of the tetrahydrofurans 9a and 9b are accompanied by the formation of sulfinamide 16 of >or=98% ee, which can be converted via sulfoxide 28 of >or=98% to the starting sulfoximine 11 of >or=98% ee. 相似文献
7.
Synthesis and binding studies of new bis-calix[4]arenes containing aromatic and heteroaromatic units
A series of new bis-calix[4]arenes containing different aromatic and heteroaromatic moieties have been synthesized. The complexing behavior of these bis-calix[4]arenes have been studied towards different metal ions and it has been found that these bis-calix[4]arenes bind silver ions selectively over other metal ions. The complexation has been studied by liquid-liquid extraction and by NMR and IR spectroscopy. 相似文献
8.
9.
10.