Dynamic surface tension measurements of surfactant solutions using the maximum bubble pressure method – limits of applicability

One of the essential differences in the design of bubble pressure tensiometers consists in the geometry of the measuring capillaries. To reach extremely short adsorption times of milliseconds and below, the so-called deadtime of the capillaries must be of the order of some 10 ms. In particular, for concentrated surfactant solutions, such as micellar solutions, short deadtimes are needed to minimize the initial surfactant load of the generated bubbles. A theoretical model is derived and confirmed by experiments performed for a wide range of experimental conditions, mainly in respect to variations in deadtime and bubble volume.     

Radiothermoluminescence of polycrystalline high-temperature superconducting YBa2Cu3O6.94, EuBa2Cu3O6.9, and SmBa2Cu3O6.9 samples

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, p. 1934, August, 1991.     

Chemically initiated electron-exchange luminescence of Ru(bpy)3Cl2 in catalytic reaction with 1,2-dioxetane

We have investigated chemiluminescence activated by Ru(bpy)₃Cl₂ in the reaction of decomposition of 1,2-dioxetane. Catalysis and activation of chemiluminescence of 1,2-dioxetanes by a ruthenium complex occur according to a mechanism of chemically initiated electron exchange, which leads to effective excitation of Ru(bpy)₃Cl₂ with yield =0.20±0.05.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1316–1321, June, 1991.     

Recovery of 177Lu from Irradiated HfO2 Targets for Nuclear Medicine Purposes

A new method of production of one of the most widely used isotopes in nuclear medicine, ¹⁷⁷Lu, with high chemical purity was developed; this method includes irradiation of the HfO₂ target with bremsstrahlung photons. The irradiated target was dissolved in HF and then diluted and placed onto a column filled with LN resin. Quantitative sorption of ¹⁷⁷Lu could be observed during this process. The column later was rinsed with the mixture of 0.1 M HF and 1 M HNO₃ and then 2 M HNO₃ to remove impurities. Quantitative desorption of ¹⁷⁷Lu was achieved by using 6 M HNO₃. The developed method of ¹⁷⁷Lu production ensures high purification of this isotope from macroquantities of hafnium and zirconium and radioactive impurities of carrier-free yttrium. The content of ^177mLu in ¹⁷⁷Lu in photonuclear production was determined. Due to high chemical and radionuclide purity, ¹⁷⁷Lu obtained by the developed method can be used in nuclear medicine.     

Determination of the carrier concentration in doped <Emphasis Type="Italic">n</Emphasis>-GaAs layers by Raman and light reflection spectroscopies

The carrier concentrations in Si-doped n-GaAs films have been determined by Raman and light reflection spectroscopies. The data obtained are in good agreement with the results of Hall measurements. It is shown that the light reflection and Raman spectroscopies supplement each other in determination of carrier concentrations in the range 10¹⁷?10¹⁹ cm^?3.     

Anomalies in the Fermi surface and band dispersion of quasi-one-dimensional CuO chains in the high-temperature superconductor YBa2Cu4O8

We have investigated the electronic states in quasi-one-dimensional CuO chains by microprobe angle resolved photoemission spectroscopy. We find that the quasiparticle Fermi surface consists of six disconnected segments, consistent with recent theoretical calculations that predict the formation of narrow, elongated Fermi surface pockets for coupled CuO chains. In addition, we find a strong renormalization effect with a significant kink structure in the band dispersion. The properties of this latter effect [energy scale (～40 meV), temperature dependence, and behavior with Zn-doping] are identical to those of the bosonic mode observed in CuO2 planes of high-temperature superconductors, indicating they have a common origin.     

Interaction between the boundary layer and a supersonic flow when part of the wall is rapidly heated

There have been many theoretical studies of aspects of the unsteady interaction of an exterior inviscid flow with a boundary layer [1–9]. The mathematical flow models obtained in these studies by the method of matched asymptotic expansions describe a wide range of phenomena observed experimentally. These include boundary layer separation near the hinge of a flap, the flow in the neighborhood of the trailing edge of an oscillating airfoil [1–2], and the development and propagation of perturbations in a boundary layer excited by an oscillating wall or some other way [3–5]. The present paper studies the interaction of an unsteady boundary layer with a supersonic flow when a small part of the surface of a body in the flow is rapidly heated.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 1, pp. 66–70, January–February, 1984.