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Kasat RB Zvinevich Y Hillhouse HW Thomson KT Wang NH Franses EI 《The journal of physical chemistry. B》2006,110(29):14114-14122
The sorbent-solvent interactions for amylose tris(3, 5-dimethylphenylcarbamate) (ADMPC) with five commonly used solvents, hexane, methanol, ethanol, 2-propanol (IPA), and acetonitrile (ACN), are studied using attenuated total reflection infrared spectroscopy (ATR-IR) of thin sorbent films, X-ray diffraction (XRD) of thin films, (13)C cross polarization/magic angle spinning (CP/MAS) and MAS solid state NMR of polymer-coated silica beads (commercially termed "Chiralpak AD"), and DFT modeling. The ADMPC-polymer-coated silica beads are used commercially for analytical and preparative scale separations of chiral enantiomers. The polymer forms helical rods with intra- and inter-rod hydrogen bonds (H-bonds). There are various nm-sized cavities formed between the polymer side-chains and rods. The changes in the H-bonding states of the C=O and NH groups of the polymer upon absorption of each of the five solvents at 25 degrees C are determined with ATR-IR. The IR wavenumbers, the H-bonding interaction energies, and the H-bonding distances of the polymer side-chains with each of the solvent molecules are predicted using the DFT/B3LYP/6-311+g(d,p) level of theory. The changes in the polymer crystallinity upon absorption of each solvent are characterized with XRD. The changes in the polymer crystallinity and the H-bonding states of C=O groups are also probed with (13)C CP/MAS solid-state NMR. The changes in the polymer side-chain mobility are detected using (13)C MAS solid-state NMR. The H-bonding states of the polymer change upon absorption of each polar solvent and usually result in an increase in the polymer crystallinity and the side-chain mobility. The polymer rods are reorganized upon solvent absorption, and the distance between the rods increases with the increase in the solvent molecular size. These results have implications for understanding the role of the solvent in modifying the structure and behavior of the polymer sorbents. 相似文献
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Rahul B. Kasat Chim Y. Chin Kendall T. Thomson Elias I. Franses Nien-Hwa Linda Wang 《Adsorption》2006,12(5-6):405-416
The interactions of amylose tris(3,5-dime- thylphenylcarbamate) (ADMPC, commercially “Chiralpak AD”) with 10 simple solutes—1-propanol,
heptane, heptanol, benzene, propylbenzene, benzyl alcohol, pyridine, tetrahydrofuran, diethylamine, and aniline—are studied
using attenuated total reflection infrared spectroscopy (ATR-IR) of thin polymer films, DFT modeling, and high performance
liquid chromatography (HPLC). ATR-IR is used to determine the changes in the hydrogen bonding states of the C=O and NH groups
of the polymer amide I and II bands upon absorption of each of the solutes at 25∘C. DFT modeling with B3LYP/6-311+g(d,p) level of theory is used to predict the IR wavenumbers, the H-bonding interaction energies,
and the hydrogen bonding distances of the polymer side-chains with certain solute molecules. The capacity factors of these
solutes with ADMPC have been measured at 25∘C in hexane/isopropanol (95/5, v/v) solvent. From IR data and DFT modeling, we conclude that the C=O and NH are key binding
sites of the polymer and interact with the functional groups of various solutes. The capacity factors are understood on the
basis of hydrogen bonding, hydrophobic, and dipole-dipole interactions of the C=O, NH, and phenyl groups of the sorbent with
OH, NH, NH2, O, phenyl, and N functional groups of the solutes. 相似文献
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