Convenient synthesis of alkyl thioacetate from alkyl halide using a polymer-supported sodium thioacetate

Alkyl halides are efficiently converted to their corresponding S-alkyl thioacetates under mild and nonaqueous conditions, using polymer-supported sodium thioacetate as a new polymeric reagent at room temperature in high yields and purity. The spent polymeric reagent can be removed quantitatively by filtration and pure products can be obtained by evaporation of the solvent. The spent polymeric reagent can be regenerated and reused several times without its activity changing appreciably.     

Synthesis of Novel Chiral Ionic Liquid and Its Application in Reduction of Prochiral Ketones to the Corresponding Chiral Alcohols Using NaBH4

A novel chiral ionic liquid (CIL) based on nicotinium salt has been synthesized and used as an efficient asymmetric chiral catalyst for reduction of acetophenone derivatives with NaBH₄ in methanol at room temperature. The optically active alcohols were obtained in low to moderate enantiomeric excess in a short reaction time.     

Aluminum Chloride (Alcl3) Promotes Selective Oxidative Deprotection of Benzylic Trimethylsilyl and Tert- Butyldimethylsilyl Ethers to the Corresponding Carbonyl Compounds with Manganese Dioxide (Mno2)

Various types of trimethylsilyl and tert-butyldimethylsilyl ethers of primary and secondary benzylic alcohols could be selectively converted to their corresponding carbonyl compounds with MnO₂ in the presence of AlCl₃ in good to excellent yields.     

Study of Tangle on the Three Qubit Werner States by Using of Twirl Operation

International Journal of Theoretical Physics - In this paper we study the Tangle of three qubit Werner state using Twirl operation and association scheme. To do this, we introduce the invariants of...     

Simulation of conjugate radiation–forced convection heat transfer in a porous medium using the lattice Boltzmann method

In this paper, a lattice Boltzmann method is employed to simulate the conjugate radiation–forced convection heat transfer in a porous medium. The absorbing, emitting, and scattering phenomena are fully included in the model. The effects of different parameters of a silicon carbide porous medium including porosity, pore size, conduction–radiation ratio, extinction coefficient and kinematic viscosity ratio on the temperature and velocity distributions are investigated. The convergence times of modified and regular LBMs for this problem are 15 s and 94 s, respectively, indicating a considerable reduction in the solution time through using the modified LBM. Further, the thermal plume formed behind the porous cylinder elongates as the porosity and pore size increase. This result reveals that the thermal penetration of the porous cylinder increases with increasing the porosity and pore size. Finally, the mean temperature at the channel output increases by about 22% as the extinction coefficient of fluid increases in the range of 0–0.03.

     

Analysis and design of a dye-doped polymer optical fiber amplifier

A rhodamine-B-doped polymer optical fiber amplifier (RBDPOFA) has been successfully fabricated and tested. In this paper, all parameters affecting the gain of the RBDPOFA are recognized. The time-dependent and time-independent rate equations are solved. By using Runge–Kutta and finite-element methods, different conditions are described and fluctuations of the fiber laser are analyzed. From the time-dependent rate equations, the gain and level-density variations with time can be predicted. These fiber amplifiers have unstable conditions. In experiments, the decay of dye dopants in the high pump power regime has been observed. For example, in a high pump power rhodamine-B is converted from the zwitterion isomer to the colorless lactone isomer [1]. Therefore, for complete coincidence of theoretical and experimental results, this effect must be included in the analysis, which is however beyond the scope of this paper and will be discussed in the near future. PACS 42.60.Da; 42.81.Wg; 31.15.Fx; 33.80.-b; 42.55.WdAn erratum to this article can be found at     

Ultrasound and Sonochemistry for Radical Polymerization: Sound Synthesis

The use of ultrasound as an external stimulus for promoting polymerization reactions has received increasing attention in recent years. In this Review article, the fundamental processes that can lead to either the homolytic cleavage of polymer chains, or the sonolysis of solvent (or other) small molecules, under the application of ultrasound are described. These reactions promote the production of reactive radicals, which can be utilized in chain-growth radical polymerizations under the right conditions. A full historical overview of the development of ultrasound-assisted radical polymerization is provided, with special attention given to the recently described systems that are “controlled” by methods of reversible (radical) deactivation. Perspectives are shared on what challenges still remain in polymer sonochemistry, as well as new areas that are yet to be explored.     

On U(1) Gauge Theory Transfer-Matrix in Fourier Basis*

The properties of the transfer-matrix of U(1) lattice gauge theory in the Fourier basis are explored. Among other statements it is shown: (i) the transfer-matrix is block-diagonal, (ii) all consisting vectors of a block are known based on an arbitrary block vector, (iii) the ground-state belongs to the zero-mode's block. The emergence of maximum-points in matrix-elements as functions of the gauge coupling is clarified. Based on explicit expressions for the matrix-elements we present numerical results as tests of our statements.