Mineral zircon: A novel thermoluminescence geochronometer

Mineral zircon contains trace amounts (typically 10-1000 v ppm) of the f -emitters uranium and thorium, which irradiate this mineral internally. This outstanding feature of zircon turns out to be extremely useful when this mineral is applied as a thermoluminescence (TL) dating medium, because the build-up of the age-dependent luminescence is dominated by the presence of well-defined internal radioactive sources and the contributions to the dose from external radiation sources are two orders of magnitude smaller. The results presented in this paper have led us to the conclusion that for zircon dating it is necessary to carefully select the best and homogeneous zircon grains of the highest optical quality. For successful dating experiments on very young and historically well-defined coastal dune sands, selection of the most stable luminescence component by means of narrow band interference filters is needed. Our results suggest that ultimately optical zircon dating will allow us to determine the age of extremely young samples ( e.g. 12 months!).     

Experimental evidence of high-beta plasma confinement in an axially symmetric gas dynamic trap

In the axially symmetric magnetic mirror device gas dynamic trap (GDT), on-axis transverse beta (ratio of the transverse plasma pressure to magnetic field pressure) exceeding 0.4 in the fast ion turning points has been first achieved. The plasma has been heated by injection of neutral beams, which at the same time produced anisotropic fast ions. Neither enhanced losses of the plasma nor anomalies in the fast ion scattering and slowing down were observed. This observation confirms predicted magnetohydrodynamic stability of plasma in the axially symmetric mirror devices with average min-B, like the GDT is. The measured beta value is rather close to that expected in different versions of the GDT based 14 MeV neutron source for fusion materials testing.     

Observation of weak impact of a stochastic magnetic field on fast-ion confinement

Fast ions are observed to be very well confined in the Madison Symmetric Torus reversed field pinch despite the presence of stochastic magnetic field. The fast-ion energy loss is consistent with the classical slowing down rate, and their confinement time is longer than expected by stochastic estimates. Fast-ion confinement is measured from the decay of d-d neutrons following a short pulse of a 20 keV atomic deuterium beam. Ion confinement agrees with computation of particle trajectories in the stochastic magnetic field, and is understood through consideration of ion guiding center islands.     

Experimental evidence for a reduction in electron thermal diffusion due to trapped particles

New high time resolution measurements of the electron thermal diffusion χ(e) throughout the sawtooth cycle of the Madison Symmetric Torus reversed-field pinch have been made by utilizing the enhanced capabilities of the upgraded multipoint, multipulse Thomson scattering system. These measurements are compared to the χ(e) due to magnetic diffusion predicted by using information from a new high spectral resolution zero-β nonlinear resistive magnetohydrodynamic simulation performed, for the first time, at the Lundquist number of high current Madison Symmetric Torus plasmas (S≈4×10(6)). Agreement between the measured and predicted values is found only if the reduction in thermal diffusion due to trapped particles is taken into account.     

Anisotropic ion heating and tail generation during tearing mode magnetic reconnection in a high-temperature plasma

Complementary measurements of ion energy distributions in a magnetically confined high-temperature plasma show that magnetic reconnection results in both anisotropic ion heating and the generation of suprathermal ions. The anisotropy, observed in the C(+6) impurity ions, is such that the temperature perpendicular to the magnetic field is larger than the temperature parallel to the magnetic field. The suprathermal tail appears in the majority ion distribution and is well described by a power law to energies 10 times the thermal energy. These observations may offer insight into the energization process.     

Ruthenium‐Catalyzed C?C Bond Cleavage in Lignin Model Substrates

Ruthenium–triphos complexes exhibited unprecedented catalytic activity and selectivity in the redox‐neutral C C bond cleavage of the β‐O‐4 lignin linkage of 1,3‐dilignol model compounds. A mechanistic pathway involving a dehydrogenation‐initiated retro‐aldol reaction for the C C bond cleavage was proposed in line with experimental data and DFT calculations.     

Rule extraction from a mutagenicity data set using adaptively grown phylogenetic-like trees

A public bacterial mutagenicity database was classified into 2-D structural families using a set of specific algorithms and clustering techniques that find overlapping classes of compounds based upon chemical substructures. Structure-activity relationships were learned from the biological activity of the compounds within each class and used to identify rules that define substructures potentially responsible for mutagenic activity. In addition, this method of analysis was used to compare the pharmacologically relevant substructure of test compounds with their potential toxic substructures making this a potentially valuable in silico profiling tool for lead selection and optimization.