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Jung Nam-Suk Kim Min-Ho Kim Hee-Hoon Shin Dong Cheol Kim Gyujin Lee Hee-Seock 《Journal of Radioanalytical and Nuclear Chemistry》2021,330(2):521-528
Journal of Radioanalytical and Nuclear Chemistry - Beam loss monitor using a long optical fiber has been developed and operated for radiation protection in PAL-XFEL, which is an X-ray free electron... 相似文献
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Revisiting Surface Modification of Graphite: Dual‐Layer Coating for High‐Performance Lithium Battery Anode Materials
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Gyujin Song Jaegeon Ryu Seunghee Ko Byoung Man Bang Dr. Sinho Choi Myoungsoo Shin Prof. Sang‐Young Lee Prof. Soojin Park 《化学:亚洲杂志》2016,11(11):1711-1717
Surface modification of electrode active materials has garnered considerable attention as a facile way to meet stringent requirements of advanced lithium‐ion batteries. Here, we demonstrated a new coating strategy based on dual layers comprising antimony‐doped tin oxide (ATO) nanoparticles and carbon. The ATO nanoparticles are synthesized via a hydrothermal method and act as electronically conductive/electrochemically active materials. The as‐synthesized ATO nanoparticles are introduced on natural graphite along with citric acid used as a carbon precursor. After carbonization, the carbon/ATO‐decorated natural graphite (c/ATO‐NG) is produced. In the (carbon/ATO) dual‐layer coating, the ATO nanoparticles coupled with the carbon layer exhibit unprecedented synergistic effects. The resultant c/ATO‐NG anode materials display significant improvements in capacity (530 mA h g?1), cycling retention (capacity retention of 98.1 % after 50 cycles at a rate of C/5), and low electrode swelling (volume expansion of 38 % after 100 cycles) which outperform that of typical graphite materials. Furthermore, a full‐cell consisting of a c/ATO‐NG anode and an LiNi0.5Mn1.5O4 cathode presents excellent cycle retention (capacity retention of >80 % after 100 cycles). We envision that the dual‐layer coating concept proposed herein opens a new route toward high‐performance anode materials for lithium‐ion batteries. 相似文献
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