排序方式: 共有62条查询结果,搜索用时 15 毫秒
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The ZnO/MgO solid samples containing the ZnO nanoparticles of controllable size were prepared using colloidal technique. The catalytic performance of the ZnO/MgO samples for the CO oxidation was measured. It was revealed that the rate of the CO oxidation reaction on the ZnO nanoparticles with variable average radius (2.01-2.29 nm) shows nonmonotonic dependence caused by the quantum-confinement effect. 相似文献
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Vasileva L. A. Kuznetsova D. A. Valeeva F. G. Vasilieva E. A. Lukashenko S. S. Gaynanova G. A. Zakharova L. Ya. 《Russian Chemical Bulletin》2021,70(7):1341-1348
Russian Chemical Bulletin - A homologous series of cationic surfactants with a pyrrolidinium head group containing a hydroxyethyl moiety was studied for the solubilization of nonsteroidal... 相似文献
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Aidar T. Gubaidullin Vladimir F. Mironov Gulnara A. Ivkova Igor A. Litvinov Irina V. Konovalova Liliya M. Burnaeva 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1)
Abstract Hexafluoroacetone imine easily interacts with compounds (I, R = OMe, OCH2CF2CHF2, NEt2, Ph) in two directions unlike hexafluoroacttone and gives 1,4,2-oxazaphosphepines (II) (pathway I) or 1,3,2-oxszaphosphepines (III) (pathway 2). The compound (II) (R = NEt2) lightly hydrolyzes to yield the salt (IV). The structure of heterocycles II-IV) has been confirmed by X-ray analysis (see fig. I, II, R = OMe; fig. 2, IV). The detail structural peculiarities of the compounds am discussed. 相似文献
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Jacob Bien Irina Gaynanova Johannes Lederer Christian L. Müller 《Journal of computational and graphical statistics》2018,27(1):23-33
The TREX is a recently introduced method for performing sparse high-dimensional regression. Despite its statistical promise as an alternative to the lasso, square-root lasso, and scaled lasso, the TREX is computationally challenging in that it requires solving a nonconvex optimization problem. This article shows a remarkable result: despite the nonconvexity of the TREX problem, there exists a polynomial-time algorithm that is guaranteed to find the global minimum. This result adds the TREX to a very short list of nonconvex optimization problems that can be globally optimized (principal components analysis being a famous example). After deriving and developing this new approach, we demonstrate that (i) the ability of the preexisting TREX heuristic to reach the global minimum is strongly dependent on the difficulty of the underlying statistical problem, (ii) the new polynomial-time algorithm for TREX permits a novel variable ranking and selection scheme, (iii) this scheme can be incorporated into a rule that controls the false discovery rate (FDR) of included features in the model. To achieve this last aim, we provide an extension of the results of Barber and Candes to establish that the knockoff filter framework can be applied to the TREX. This investigation thus provides both a rare case study of a heuristic for nonconvex optimization and a novel way of exploiting nonconvexity for statistical inference. 相似文献
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Konstantin Chernyshov Dmitry Gen Yuri Shemouratov Kirill Prokhorov Gulnara Nikolaeva Elena Sagitova Pavel Pashinin Anton Kovalchuk Alla Klyamkina Polina Nedorezova Boris Shklyaruk Valery Optov 《Macromolecular Symposia》2010,296(1):505-516
Nascent form of random copolymers of propylene with ethylene, 1-butene, 1-hexene, 1-octene, and 4-methyl-1-pentene was studied by Raman spectroscopy. The most significant spectral alterations with a change in propylene content were observed in two lines at 809 and 841 cm−1. The first line corresponds to vibrations of polypropylene helical chains in the crystalline phase, while the second one is associated with vibrations of polypropylene helical chains having isomeric defects. Raman data confirm that conformational composition and phase state of copolymer macromolecules strongly depend on the comonomer content as well as on the size of the comonomer units. 相似文献
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Ilyas S. Nizamov Gulnara T. Gabdullina Almaz R. Nurmukhametov Ilnar D. Nizamov Rafael A. Cherkasov 《Heteroatom Chemistry》2013,24(6):490-494
The ammonium salt of optically active dithiophosphoric acid obtained by the reaction of tetraphosphorus decasulfide with (1S)‐endo‐(–)‐borneol reacts with benzoyl chloride, methyl chloroacetate and epichlorohydrin to form novel dithiophosphate S‐esters. 相似文献
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Vladimir A. Dyakonov Gulnara N. Kadikova Lilya U. Dzhemileva Guzel F. Gazizullina Milyausha M. Yunusbaeva Usein M. Dzhemilev 《Tetrahedron》2018,74(30):4071-4077
Bicyclo[4.3.1]deca-2,4,8-triene-7,10-diols were synthesized in 76–85% yields by oxidative skeletal isomerization of the substituted bicyclo[4.2.2]deca-2,4,7,9-tetraenes of various structures on treatment with m-chloroperbenzoic acid. The structures of the obtained bicyclic unsaturated diols were reliably proven by modern spectral methods and X-ray diffraction. A high antitumor activity in vitro was found for bicyclo[4.3.1]deca-2,4,8-triene-7,10-diols against the Jurkat, K562, U937 and HL-60 tumor cell lines. 相似文献
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Rimma Sultanova Sophia Borisevich Gulnara Raskil'dina Julianna Borisova Irina Baykova Leonid Spirikhin Sergey Khursan Simon Zlotsky 《中国化学会会志》2020,67(7):1144-1151
Experimental and theoretical aspects of the condensation of glycerol and its homologs (1,2,3- and 1,2,4-butanetriols) with formaldehyde and acetone are studied under conditions of acid catalysis. Calculation of the thermodynamic parameters of the resulting products by the composite method CBS-QB3 shows that the six-membered heterocycles, the products of the interaction of triols with formaldehyde, are thermodynamically more stable than the five-membered acetals, while the reaction of the same triols with acetone is preferable for the formation of the five-membered acetals. This is due to the fact that the regioselectivity of the studied reactions is determined by the structural features and reactivity of the carbocations formed in a condensed medium during the course of the reaction. According to the theoretical data obtained experimentally, during the condensation of glycerol and 1,2,4-butanetriol with formaldehyde in the most stable form of the six-membered cyclic carbocation, intramolecular hydrogen bonding and anomeric stabilization due to the axially oriented hydroxyl group take place. As a result, cation 1b–1 is 1.2–1.6 kJ/mol more stable than its five-membered isomers ( 1a–1 and 1b–2 ). It leads to the predominant formation of 1,3-dioxane ( 3b ). However, upon condensation of butanetriol-1,2,3 with formaldehyde, the intermediate cation 4a–1 turns out to be significantly more stable than the other isomers due to the strong intramolecular hydrogen bond in the six-membered ring with the participation of the hydroxyl group of the substituent and the hydroxyl group of the cationic center, leading to the predominant formation of the dioxolane 6a . 相似文献