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1.
2.
Vanessa R. Machado Louis P. Sandjo Giovanni L. Pinheiro Milene H. Moraes Mario Steindel Moacir G. Pizzolatti 《Natural product research》2018,32(3):275-281
The natural product lupeol 1 was isolated from aerial parts of Vernonia scorpioides with satisfactory yield, which made it viable to be used as starting material in semisynthetic approach. Ten lupeol derivatives 2–11 were prepared by classical procedures. Including, five new esters derivatives 7–11, which were obtained by structural modifications in the isopropylidene fragment. All semisynthetic compounds and lupeol 1–11 were confirmed by 1H NMR, 13C NMR and HRMS. Their antiprotozoal activity was evaluated in vitro against L. amazonensis and T. cruzi. Derivative 6 showed the best antitrypanosomal activity (IC50 = 12.48 μg/mL) and the lowest cytotoxic derivative (CC50 = 161.50 μg/mL). The mechanism of action of the most active derivatives (4, 6 and 11) is not dependent from the enzyme trypanothione reductase. 相似文献
3.
Paolo Bertozzini Roberto Conti Roberto Longo 《Communications in Mathematical Physics》1998,193(2):471-492
Let ? be a local conformal net of von Neumann algebras on S
1 and ρ a M?bius covariant representation of ?, possibly with infinite dimension. If ρ has finite index, ρ has automatically
positive energy. If ρ has infinite index, we show the spectrum of the energy always to contain the positive real line, but,
as seen by an example, it may contain negative values. We then consider nets with Haag duality on ℝ, or equivalently sectors
with non-solitonic extension to the dual net; we give a criterion for irreducible sectors to have positive energy, namely
this is the case iff there exists an unbounded M?bius covariant left inverse. As a consequence the class of sectors with positive
energy is stable under composition, conjugation and direct integral decomposition.
Received: 21 April 1997 / Accepted: 23 September 1997 相似文献
4.
Summary We present an approximation method of a space-homogeneous transport equation which we prove is convergent. The method is very promising for numerical computation. Comparison of a numerical computation with an exact solution is given for the Master equation. 相似文献
5.
Giovanni Carini 《Rendiconti del Circolo Matematico di Palermo》1987,36(1):122-138
In this paper, along with the well established lines of the analytical mechanics, we aim to show an autonomous formulation of the fundamental principle of Lagrange-d'Alembert and of the subsequent Hamilton principle in classical mechanics of deformable continua in the sense that the afore—mentioned principles do not turn out to be a reformulation of the well known undefined equations of motion. 相似文献
6.
3-Hydroxy-4-hydroxymethyl pyrrolidin-2-ones, easily prepared from the Baylis–Hillman adduct 1-ethyl-4-methyl-2-hydroxy-3-methylenebutanedioate, are useful intermediates in the synthesis of bioactive compounds. In order to understand the mechanism involved in this reaction, vibrational and Montecarlo molecular mechanics conformational analysis on 1-ethyl-4-methyl-2-hydroxy-3-methylenebutanedioate were carried out, confirming the existence of a low energy intramolecular H-bonded five-member ring. 相似文献
7.
Giuseppe Coppola Andrea Irace Giovanni Breglio Mario Iodice Luigi Zeni Antonello Cutolo Pasqualina M. Sarro 《Optics and Lasers in Engineering》2003,39(3):317-332
In this paper we describe two different kind of optoelectronic devices both based on a three terminals active device and exploit the plasma dispersion effect to achieve the desired working. The first device exploits this effect in order to obtain an optical modulation. The second device is an optoelectronic router based on the mode-mixing principle together with the injection-induced optical phase shift. Both devices are integrated into a Silicon on Silicon optical channel waveguide which can be realized using a standard bipolar process. The possibility of using standard, well-known technology presents several advantages with respect to III–V Optoelectronics. The active three terminal device used is a Bipolar Mode Field Effect Transistor (BMFET). Numerical simulation results are presented on both devices. 相似文献
8.
Sébastien Lemaire Giuliano Giambastiani Barbara Pacini Giovanni Poli 《Journal of organometallic chemistry》2003,687(2):291-300
A new type I palladium-catalyzed pseudo-domino process is developed, in which a single Pd-based catalytic system promotes two mechanistically unrelated, sequential catalytic cycles in chronologically distinct order. Suitable precursors undergo an allylic alkylation and a Heck coupling in sequence, affording polycondensed pyrrolidone derivatives. Depending on the starting precursors, intra/inter or doubly intramolecular processes can be obtained. The allylic alkylation process takes place always very smoothly. On the other hand, the Heck coupling turns out to be rather difficult either when the process is intermolecular, or when an intramolecular process generates polycondensed structures featuring three fused bonds connected to a common carbon atom. In such difficult cases, use of the Herrmann-Beller phosphapalladacycle allowed to catalyze the coupling. This study demonstrates also that allylic alkylations can be catalyzed by the Herrmann-Beller phosphapalladacycle. 相似文献
9.
Giovanni Giachetta Luigi Mangiarotti 《International Journal of Theoretical Physics》1997,36(1):125-141
We consider a metric-affine gravitational framework in which the dynamical fields are the spin structures, the general linear
connections, and the Dirac fermion fields. Using a spin structure and a linear connection on the world manifold, we construct
a principal connection on the spinor bundle. By applying general ideas concerning the conservation laws in the Lagrangian
approach to field theory, we examine the corresponding conserved currents. The main result is that the currents associated
with infinitesimal vertical (internal) transformations of the covariance group are shown to vanish identically. It follows
that to every vector field on the world manifold there corresponds a well-defined current, the stress-energymomentum of the
fields. It turns out that the fermion fields do not contribute at all to the superpotential terms. Actually the expression
we get for the superpotential generalizes the well-known expression obtained by Komar. 相似文献
10.
Giovanni Cupini Marcello Guidorzi Cristina Marcelli 《Journal of Differential Equations》2007,243(2):329-348
Classical one-dimensional, autonomous Lagrange problems are considered. In absence of any smoothness, convexity or coercivity condition on the energy density, we prove a DuBois-Reymond type necessary condition, expressed as a differential inclusion involving the subdifferential of convex analysis. As a consequence, a non-existence result is obtained. 相似文献