Portable and Automatic Mössbauer Analysis

A portable Mössbauer spectrometer, developed for extraterrestrial applications, opens up new industrial applications of MBS. But for industrial applications, an available tool for fast data analysis is also required, and it should be easy to handle. The analysis of Mössbauer spectra and their parameters is a barrier for the popularity of this wide-applicable spectroscopic technique in industry. Based on experience, the analysis of a Mössbauer spectrum is time-consuming and requires the dedication of a specialist. However, the analysis of Mössbauer spectra, from the fitting to the identification of the sample phases, can be faster using by genetic algorithms, fuzzy logic and artificial neural networks. Industrial applications are very specific ones and the data analysis can be performed using these algorithms. In combination with an automatic analysis, the Mössbauer spectrometer can be used as a probe instrument which covers the main industrial needs for an on-line monitoring of its products, processes and case studies. Some of these real industrial applications will be discussed.     

As+注入硅的紫外-可见椭圆偏振光谱

本文采用椭圆偏振光谱法研究了剂量为1×10¹⁶—3×10¹²cm^-2的As⁺注入硅,及其在700℃退火后的光学性质。得出:当As⁺注入剂量增大到某一程度后,便呈非晶特性。低于临界剂量的样品,其n-λ,ε₂-λ关系曲线随剂量的增大而往下方移动,呈有规律变化;退火后,在大于4000?波段,n-λ与ε₂-λ曲线基本恢复到单晶硅状态。但在小于4000?的紫外区却未完全恢复,注入剂量越大,偏离单晶硅就越大。并指出,紫外光区是离子注入硅的信息敏感区;用有效质量模型计算出注入剂量与损伤度的关系。计算结果与实验符合得较好。 关键词：     

全球大气重力波联测期间电离层扰动的台阵观测

本文利用武汉电离层观象台的加密频高图和三站Doppler图记录及新近提出的短波扰动反演方法,分析了1985年全球大气重力波联测(WAGS)期间10月18日这天白天的重力波扰动,发现在该日扰动中有两列不同形态的波列分别属于中尺度的内重力波和大尺度的导制重力波。本文还进一步估算了这两列重力波的水平传播参量,深入分析了它们的频谱结构的高度变化特征,发现了重力波功率谱谱峰的分裂和偏移等重要现象。本文结果表明,新的反演方法使电离层无线电汉诊断的简易短波实验系统,也能成为探测和研究重力波一类大尺度电离层动力过程的有效手段。     

Radiochemical solvent extraction method for the determination of Cd and Hg using thionalide as a single reagent

A radiochemical solvent extraction method has been developed for the simultaneous determination of submicrogram amounts of Cd and Hg using^115mCd and²⁰³Hg tracers respectively and thionalide as a single complexing reagent. Hg was determined by 0.05% thionalide in ethyl methyl ketone (EMK) at pH 8.5, masking Cd with 0.1M KCN. From the aqueous phase Cd was demasked using formal-dehyde-acetic acid, pH adjusted to 9.5 and extracted into 0.05% thionalide in chloroform. The method is simple, fast and yields accurate results.     

60keV质子辐照对TiNi记忆合金薄膜马氏体相变的影响

 利用磁控溅射的方法在氧化后的单晶Si基片上制备了TiNi形状记忆合金薄膜，利用示差扫描量热法和原位X射线衍射研究了薄膜的马氏体相变特征。通过60keV质子注入（辐照）薄膜样品研究了H+离子对合金薄膜马氏体相变特征的影响，结果表明氢离子注入后引起了马氏体相变开始Ms和结束点Mf以及逆马氏体相变开始As和结束温度Af的下降，而对R相变开始Rs和结束温度Rf影响不大。掠入射X射线衍射表明H+离子注入后有氢化物形成。H⁺离子注入形成的氢化物是引起相变点的变化的主要因素。     

Synthesis and spectral studies on nickel(II) complexes of amide group-containing ligands

Summary Complexes of nickel(II) with N-(2-carboxyphenyl)benzamide (CPBH), 2-amino-N-(2-carboxyphenyl)benzamide (ACPBH), N-isoxazolyl benzamide (IB), N-anilinobenzamide (AB), N-(2-pyridyl)-3-carboxypropanamide (PCPA) and N-(2-pyridyl)-2-carboxybenzamide (PCBA) have been isolated and characterized by elemental analyses, magnetic susceptibility measurements, thermal studies, i.r. and electronic spectral studies. The electrochemical behaviour of some complexes has also been investigated.     

离子液体中用Heck反应合成2-取代萘烯丙醇化合物

利用Heck反应, 在离子液体、金属钯或镍、碱和膦配体反应体系中, 由卤代萘与烯丙醇反应, 制得了高收率和高选择性的2-取代萘烯丙醇化合物. 该方法原料便宜易得、操作简单、反应体系可循环使用. 并讨论了醋酸镍替代醋酸钯、不同膦配体、溶剂及碱对反应转化率的影响. 通过核磁共振、红外光谱、质谱和元素分析对产物的结构进行了表征.     

Iron(III) complexes of 2-acetylpyridine-4-phenyl-3-thiosemicarbazones: Magnetic,E.s.r. and spectral studies

Summary Iron(III) complexes of 2-acetylpyridine-4-phenyl-3-thiosemicarbazone (LH) with the general formulae FeLX₂ (X = Cl, Br, NO₃ or SCN) and FeLSO₄ have been prepared and characterised by elemental analysis and by magnetic measurements in the polycrystalline state in the 77–298 K range and by electronic, i.r. and e.s.r. spectra. The FeLX₂ species (X = Cl, NCS or NO₃) are square pyramidal of intermediate spin-state (S=3/2) with an⁴ A ₂ ground state. The magnetic behaviour of FeLSO₄ is commensurate with high order effects coupled with antiferromagnetic exchange interactions. FeLBr₂ is a spin-free dimer involving bromine bridging between two FeLBr₂ square pyramids. However, the low-spin species [FeL(DMF)₃]²⁺ exists in dimethylformamide solution.     

Correlation of isomer shift and quadrupole splitting and the sign of EFG

Mössbauer isomer shift // and quadrupole splitting /E_Q/ values in a series of isostructural compounds correlate well to give linear relationship provided the sign of electric field gradient /EFG/ is assigned to the E_Q. The correlation has been used in predicting the sign of EFG for some monosubstituted pentacyanoferrate/II/ complexes. Usefulness of such correlations and its limitations are presented.