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1.
The effect of the replacement of MnO2 by Fe2O3 on the oxidation states of iron in some lithium borosilicate glasses were studied using Mössbauer spectroscopy. DTA and infrared measurements showed the presence of two glassy phases, one of them containing iron and the other manganese. The Mössbauer spectra were measured at room temperature for all the glass samples. The spectra revealed the presence of Fe ions only in ferric state in both tetrahedral and octahedral coordination. Also, it was observed that the ratio between the number of iron ions in both coordination states has not changed with the increase of MnO2 content. 相似文献
2.
Ahmed Abd El-Fattah Mohamad Nageeb Hassan Ahmad Rashad Mona Marei Sherif Kandil 《International Journal of Polymer Analysis and Characterization》2020,25(5):362-373
Abstract An injectable composite hydrogel composed of polyvinyl alcohol (PVA) and bioactive glass (BG) particles were synthesized by a physical crosslinking approach. The morphology, mechanical properties, and viscoelasticity of the PVA/BG composite hydrogel were characterized. Scanning electronic microscopy (SEM) showed uniform and homogeneous distribution of BG particles throughout the composite hydrogel. The incorporation of 2.5?wt% of BG particles in the composite hydrogel formulations, enhanced the static compressive strength and static elastic modulus by 325% and 150%, respectively. The storage molds (G′) was greater than the loss modules (G′′) at all the frequency range studied, which revealed a self-standing elastic composite hydrogel with a smooth injectability. The PVA/BG composite hydrogel was also implanted subcutaneously in the dorsal region of adult male rats. After 4?weeks of implantation, no inflammatory cells were seen within and around the implant, which indicated that the composite hydrogel was biocompatible. The properties of the synthesized injectable PVA/BG composite hydrogel demonstrate its capability toward bone regeneration. 相似文献
3.
Extraction of nitric, perchloric, and hydrochloric acid by N,N-dibutyl diethyl carbamyl phosphonate in carbon tetrachloride was investigated. The data obtained are treated in terms of stepwise neutralization of the acid with the formation of species y · HA and y · 2HA in the organic phase, where y stands for the extractant and HA for the acid. The equilibrium constants, K?1 and K?2 for nitric acid were found to equal 0.24 ± 0.02 and 0.017 ± 0.005, respectively. In case of HClO4 and HCl K?1 were found to equal 0.031 ± 0.003 and 0.0039 ± 0.0005, respectively. A third phase was observed when extraction of HClO4 was performed using acid concentration higher than 3.5 molar. The preference for partition of different acids was discussed on the light of the competition of the proton between the acid anion, water and the basic extractant as well as the degree of the ionization of different acids. 相似文献
4.
E. A. El-Ghany N. Farouk M. T. El-Kolaly 《Journal of Radioanalytical and Nuclear Chemistry》2000,245(2):243-247
Although 125I-hydroxypindolol (125I-HYP) has been an excellent probe of adenoceptor function in certain tissues, but 125I-pindolol (125I-PIN) was found more specific for -adrenoceptor labeling. This study describes a fast and efficient method for radiolabeling of pindolol with iodine-125, where both chloramine-T and iodogen were used as oxidizing agents. The use of iodogen coated glass frit has a great advantage in increasing the radiochemical yield of 125I-pindolol and this was attributed to the increase of the interphaces boundary between the solid and liquid. This technique reduces the quantity of iodogen required to produce high radiochemical yield by its half. The radiochemical yield was determined by TLC system using chloroform: acetic acid: water (15:4:1) as developing solvent and by HPLC using reversed phase RP-18 column and acetonitrile: 0.1M ammonium bicarbonate pH 7.5 (1:1) as a mobile phase at flow rate (1ml/min). The radiochemical yield was found to be 48.6 and 62.9% respectively. 相似文献
5.
The extraction of Co2+ by a mixture of acetylacetone (acac) and pyridine (py) from an aqueous phase of varying ionic strengths has been investigated.
The extraction studies were done at different temperatures in order to determine the effect of changes in the ionic strength
on the free energy ΔG, enthalpy ΔH and entropy ΔS of the synergistic reaction. 相似文献
6.
Kandil Samir S. El-Hefnawy Gad B. Bakr Eman A. Abou El-Ezz Amro Z. 《Transition Metal Chemistry》2003,28(2):168-175
A new series of hexacoordinate cobalt(II), nickel(II) and copper(II) complexes of 5-(2-carboxyphenylazo)-2-thiohydantoin HL having formulae [LM(OAc)(H2O)2] · nH2O (M = CoII, CuII and NiII), [LMCl(H2O)2] · nH2O (M = CoII and NiII), [LCuCl(H2O)]2 · 2H2O, [LCu(H2O)3](ClO4) and [LCu(HSO4)(H2O)2] were isolated and characterized by elemental analyses, molar conductivities and magnetic susceptibilities, and by i.r., electronic and e.s.r. spectral measurements, as well as by thermal (t.g. and d.t.g.) analyses. The i.r. spectra indicate that the ligand HL behaves as a monobasic tridentate towards the three divalent metal ions via an azo-N, carboxylate-O and thiohydantoin-O atom. The magnetic moments and electronic spectral data suggest an octahedral geometry for CoII complexes, distorted octahedral geometry for both NiII and CuII complexes with a dimeric structure for [LCuCl(H2O)]2 · 2H2O through bridged chloro ligands. The X-band e.s.r. spectra reveal an axial symmetry for the copper(II) complexes with unsymmetrical Ms = ± 1 signal and G-parameter less than four for the dimeric [LCuCl(H2O)]2 · 2H2O. The thermogravimetry (t.g. and d.t.g.) of some complexes were studied; the order and kinetic parameters of their thermal degradation were determined by applying Coats–Redfern method and discussed. 相似文献
7.
Suzan A. Mina Sohair A. Mohamed Farouk R. Melek Soad M. Abd El-Khalik 《Natural product research》2020,34(9):1292-1296
AbstractIn the present study, evaluation of the antiproliferative activity of Pachypodium lamerei Drake leaves (family Apocyaceae) against human breast cancer cell lines MDA-MB-231 was done for the total methanolic extract, crude alkaloidal mixture and ursolic acid using the MTT colorimetric assay. The methanolic extract showed the strongest antiproliferative activity followed by ursolic acid and crude alkaloidal fraction with an IC50 equal to 6.2, 14.55 and 56.3?µg/ml respectively compared to oleocanthal. It is the first record for the LC/ESI-MS/MS alkaloidal profiling of the leaves of P. lamerei. Seven alkaloids were tentatively identified according to their fragmentation patterns. Four alkaloids were related to the parent indole class and two alkaloids belong to the quinoline class in addition to one steroidal alkaloid with a pregnan nucleus. Phytochemical investigation of the methanolic extract led to the isolation of three triterpenoidal compounds including ursolic acid, 11,12-didehydroursolic acid lactone and ursolic acid lactone. 相似文献
8.
Shoaib Khan Shahid Iqbal Mazloom Shah Wajid Rehman Rafaqat Hussain Liaqat Rasheed Hamad Alrbyawi Ayed A. Dera Mohammed Issa Alahmdi Rami Adel Pashameah Eman Alzahrani Abd-ElAziem Farouk 《Molecules (Basel, Switzerland)》2022,27(20)
A unique series of sulphonamide derivatives was attempted to be synthesized in this study using a new and effective method. All of the synthesized compounds were verified using several spectroscopic methods, including FTIR, 1H-NMR, 13C-NMR, and HREI-MS, and their binding interactions were studied using molecular docking. The enzymes urease and α-glucosidase were evaluated against each derivative (1–15). When compared to their respective standard drug such as acarbose and thiourea, almost all compounds were shown to have excellent activity. Among the screened series, analogs 5 (IC50 = 3.20 ± 0.40 and 2.10 ± 0.10 µM) and 6 (IC50 = 2.50 ± 0.40 and 5.30 ± 0.20 µM), emerged as potent molecules when compared to the standard drugs acarbose (IC50 = 8.24 ± 0.08 µM) and urease (IC50 = 7.80 ± 0.30). Moreover, an anti-microbial study also demonstrated that analogs 5 and 6 were found with minimum inhibitory concentrations (MICs) in the presence of standard drugs streptomycin and terinafine. 相似文献
9.
10.