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1.
We investigate the dependence of the relaxation time of the current flowing in a nematic cell submitted to an external dc voltage on the physical properties of the substrate. We show that previously presented analyses of the same problem are not very useful for practical applications. We compare our theoretical predictions with experimental data, and show that the agreement is rather good. The influence of the adsorption-desorption phenomenon on the relaxation time is also discussed. 相似文献
2.
M.G.?CarvalhoEmail author J.M.R.C.A.?Santos A.A.?Martins M.M.?Figueiredo 《Cellulose (London, England)》2005,12(4):371-383
In this work attention has been focused on the effects of papermaking beating, web forming and sizing operations on the physical/chemical
surface properties of bleached Eucalyptus globulus kraft fibres. Inverse gas chromatography (IGC) was used to determine the dispersive component of surface tension (γsd) as well as the acidic/basic character (according to the Lewis concept) of the solid surfaces (pulp fibres and pulp handsheets).
The results have shown that the main effect of beating is to increase the fibre's Lewis acidic character. Web forming caused
a strong decrease in γsd and significant increments in the adhesion works of both acidic and basic probes, lowering the ratio between the two. Nevertheless,
the surface of handsheets still exhibited a dominant acidic character. The sizing operation did not change the dispersive
component of the surface tension significantly but decreased the difference between the adhesion works of the acidic and basic
probes, rendering the handsheet surface less Lewis acidic and more Lewis basic. Thus, although internal sizing is expected
to strongly influence liquid spreading at the paper surface and liquid penetration of the fibre's network, it is concluded
that beating and web forming lead to important changes in the surface energetic properties of the Eucalyptus globulus kraft fibres. 相似文献
3.
E. Bütkus J. C. Martins U. Berg 《Journal of inclusion phenomena and macrocyclic chemistry》1996,25(1-3):125-128
- and -cyclodextrins were found to form 1:1 inclusion complexes with 2,6- and 2,9-substituted bicyclo[3.3.1]nonanes. The binding constants and the structure of the complexes were estimated from titration studies and 2D ROESY experiments. 相似文献
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Claudio C. Silveira Samuel R. Mendes Guilherme M. Martins 《Tetrahedron letters》2012,53(13):1567-1570
Ce(OTf)3 was successfully employed as catalyst for the activation of the hydroxyl group in the Friedel–Crafts reaction of aromatic compounds with propargylic alcohols in nitromethane. The products were obtained in good to excellent yields. 相似文献
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The rectum of the bee Oxaea flavescens contains six hollow rectal papillae, in contrast to rectal pads found in others Hymenoptera. The rectal epithelium is formed by cubical cells with structural specializations for fluid transport, such as apical plasma membrane invaginations, endocytic vesicles, scalariform junctions, wide extracellular space and double-membrane vesicles. Globular-shaped cells form the rectal papillae with surface plasma membrane invaginations that vary from small depressions to very large sinuses. The cell-cell contact is narrow, exhibiting extensive regions with scalariform junction, while cytoplasmic free ribosome-like material is prominent. These ultrastructural features are discussed in relation to their role in excretion in this bee. 相似文献
10.
Developing exact models of combustion instabilities is not an easy task to carry out and requires a great deal of time prior to obtaining success. The present study proposes a low-order model for pressure oscillations that does not require any knowledge of the systems, any new physical findings nor intricate details regarding its operating condition. This new approach is obtained using a Modified Van der Pol’s equation (MVDP) which is tuned by use of a Dual Extended Kalman Filter (DKEF) as a recursive estimator with perspectives in control by computer. This phenomenological model is used to predict the pressure signal from a variety of different combustors. Input data were taken from experimental cases such as a Rijke tube, a gas turbine and a liquid-fuel aero-engine combustor. Furthermore, a simulation considering high frequency oscillations to show the capability of the new approach is presented. In all cases, the results demonstrated the feasibility of applying the tractable model MVDP and DKEF running together to investigate pressure oscillations in practical cases. 相似文献