Glass transitions in hydrogen-bonded polymer complexes

Mutual precipitates of poly (N, N-dimethyl acrylamide) and poly (4-hydroxystyrene) were collected from dioxane, methanol, or acetone. The glass transition (T_g) temperatures of the precipitates are higher than the weight-average values. Clear films cast from dimethylformamide solutions have lower T_g values. Complexation also occurred between poly (ethyl oxazoline) and poly (4-hydroxystyrene) in dioxane and between poly (vinyl pyrrolidone) and poly (4-hydroxystyrene) in methanol. Again, the glass transition temperatures of the precipitates are higher than the values for the blend films. The ΔC_p values associated with the glass transitions of the complexes are smaller than those of the blends having the same compositions. Negative excess heat capacities of mixing have been observed for several precipitates.     

SECOND BEST TAXES AND QUOTAS IN NITROGEN REGULATION

This paper investigates second best policies to regulate nitrogen leaching. When the policy maker controls the total nitrogen use, an overall tax is superior to an action equivalent overall quota. When the goal is to regulate the expected level of nitrogen leaching, expected profit of a risk neutral farmer is greater under an overall tax than under an overall quota under a reasonable condition. The welfare ranking of action equivalent taxes and quotas for a risk averse farmer is generally ambiguous. In the numerical analyses, overall taxes turned out to be superior to overall quotas with both targets, despite a very high value of absolute risk aversion, 0.01. These results suggest that an overall tax is probably a superior policy to an overall quota to regulate expected total nitrogen use or expected nitrogen leaching for risk neutral and most of risk averse farmers.     

Extension of multigrid methodology to supersonic/hypersonic 3-D viscous flows

A multigrid acceleration technique developed for solving the three-dimensional Navier–Stokes equations for subsonic/transonic flows has been extended to supersonic/hypersonic flows. An explicit multistage Runge–Kutta type of time-stepping scheme is used as the basic algorithm in conjunction with the multigrid scheme. Solutions have been obtained for a blunt conical frustum at Mach 6 to demonstrate the applicability of the multigrid scheme to high-speed flows. Computations have also been performed for a generic High-Speed Civil Transport configuration designed to cruise at Mach 3. These solutions demonstrate both the efficiency and accuracy of the present scheme for computing high-speed viscous flows over configurations of practical interest.     

The crystal structure of the inorganic surface films formed on Mg and Li intercalation compounds and the electrode performance

A crystallographic approach was applied to elucidate the influence of the nature of the surface films on the electrochemical behavior of Li and Mg intercalation compounds. This paper presents two examples: (1) protection of graphite electrodes by Li₂CO₃ surface films, and (2) the unique electrochemical behavior of Mg-containing Chevrel phases (MgCP) obtained by different synthetic routes. In the former case, the elucidation of the protection mechanism and the explanation of the high performance of such protected electrodes are based on the analysis of possible Li-ion motion in the carbonate crystal structure. In the latter case, a combination of synthesis, electrochemistry and XRD analysis was used to explain an unusual phenomenon: the difference between the excellent electrochemical behavior of the Chevrel phase (CP) based on Cu-leached Cu₂Mo₆S₈ (CuCP), and the poor electrochemical activity of the high-temperature synthesized MgCP, with the same phase composition. It is shown that this phenomenon is caused by MgO formation on the surface of the latter material. The different surface chemistry of the MgCPs obtained by the two different synthetic routes was substantiated by revealing the correlation between the electrochemical activity and the chemical stability of these materials under ambient atmosphere conditions. Dedicated to Prof. Mikhail A. Vorotyntsev on the occasion of his 60th birthday.     

Organically modified sols as pseudostationary phases for microchip electrophoresis

We demonstrate that the selectivity of microchip electrophoresis separations is greatly improved by the presence of organically modified silica (Ormosil) sols in the run buffer. A negatively-charged N-(trimethoxysilylpropyl)ethylenediamine triacetic-acid (TETT)-based sol is used for improving the selectivity between nitroaromatic explosives and a methyltrimethoxysilane (MTMOS)-based sol is employed for enhancing the microchip separation of environmental pollutants, aminophenols. These sols are added to the run buffer and act as pseudostationary phases. Their presence in the run buffer changes the apparent mobility of studied solutes, and leads to a higher resolution. The observed mobilities changes reflect the interactions between the Ormosil sols and the solutes. Relevant experimental variables have been characterized and optimized. The diverse chemistry of Ormosil sols should be extremely useful for tailoring the selectivity of a wide range of electrophoresis microchip separations.     

A potent and highly selective sulfotransferase inhibitor

In the present work, we have used a newly developed, fluorescence-based assay to screen a library of >30 000 compounds as potential beta-arylsulfotransferase-IV inhibitors. A total of 11 inhibitors were discovered. Most of the compounds discovered showed low micromolar inhibition, but one of the compounds showed potent inhibition (Ki = 96 nM). The most potent of these inhibitors was tested against a variety of other purine binding enzymes and showed remarkable specificity.     

Randomized broadcast in networks

In this paper we study the rate at which a rumor spreads through an undirected graph. This study has two important applications in distributed computation: in simple, robust and efficient broadcast protocols, and in the maintenance of replicated databases.     

Asynchronous and corrected-asynchronous finite difference solutions of PDEs on MIMD multiprocessors

A major problem in achieving significant speed-up on parallel machines is the overhead involved with synchronizing the concurrent processes. Removing the synchronization constraint has the potential of speeding up the computation, while maintaining greater computation flexibility (e.g. differences in processors speed; differences in the data input to processors). We construct asynchronous (AS) finite difference schemes for the solution of PDEs by removing the synchronization constraint. We analyze the numerical properties of these schemes. Based on the analysis, we develop corrected-asynchronous (CA) finite difference schemes which are specifically constructed for an asynchronous processing. We present asynchronous (AS) and corrected-asynchronous (CA) finite difference schemes for the multi-dimensional heat equation. Although our discussion concentrates on the Euler scheme it should serve only as a sample, as it can be extended to other schemes and other PDEs.These schemes are implemented on the shared-memory multi-userSequent Balance machine. Numerical results for one and two dimensional problems are presented. It is shown experimentally that synchronization penalty can be about 50% of run time: in most cases, the asynchronous scheme runs twice as fast as the parallel synchronous scheme. In general, the efficiency of the parallel schemes increases with processor load, with the time-level, and with the problem dimension. The efficiency of the AS may reach 90% and over, but it provides accurate results only for steady-state values. The CA, on the other hand, is less efficient but provides more accurate results for intermediate (non steady-state) values. The results show the potential of developing asynchronous finite deference schemes for steady-state as well as non steadystate problems.This research was partially supported by a grant from The Basic Research Foundation administrated by The Israel Academy of Sciences and Humanities.A reduced version of the paper was presented at the 4th SIAM Conference on Parallel Processing for Scientific Computing, Dec. 11–13, 1989, Chicago, USA.The work by this author was supported by research grant 337 of the Israeli National Council for Research and Development in the years 1990–1991.This research was supported by the National Aeronautics and Space Administration under NASA Contract No. NASI-18107 while the author was in residence at the Institute for Computer Applications in Sciences and Engineering (ICASE), NASA Langley Research Center, Hampton, VA 23665, USA.     

Topological ergodic decompositions and applications to products of powers of a minimal transformation

For a minimal distal flow (X, T) and a positive integern, let be the largest distal factor of ordern. The existence of a denseG _δ subset ω ofX is shown, such that forx ∈ ω the orbit closure of (x,x,...,x) ∈ X ⁿ⁺¹ under τ =T ×T ² ... ×T ⁿ⁺¹ is π-saturated. In fact, an analogous statement for a general minimal flow is proved in terms of its PI-tower. On the way we get some topological “ergodic” decomposition theorems.