Dimerization of Acetylene to Monovinylacetylene (MVA) by Bimetallic Zr/Cu Catalyst in Nieuwland Catalytic System

Nieuwland catalyst is a key step in the dimerization of acetylene. Various zirconium metal additives incorporating Nieuwland catalysts were prepared, and their catalytic performances were assessed in acetylene dimerization. Different characterization techniques (i.e., thermogravimetric analysis, temperature-programmed reduction, X-ray diffraction, X-ray photoelectron spectroscopy, hydrogen ion concentration measurement and transmission electron microscopy) were employed in this study. The best catalytic performance was obtained over zirconium-acetylacetonate-incorporated Nieuwland catalysts, with an acetylene conversion of 53.3% and a monovinylacetylene selectivity of 87.4%. Based on these results, the zirconium acetylacetonate additive could reduce the types of transition state complexes, and it could also change the morphology of the catalyst. In addition, the additives could significantly inhibit the occurrence of trimerization products and polymers. Hence, the conversion of acetylene, monovinylacetylene selectivity, and stability of the Nieuwland catalysts were enhanced.     

Optimization of controllability and robustness of complex networks by edge directionality

Recently, controllability of complex networks has attracted enormous attention invarious fields of science and engineering. How to optimize structural controllability hasalso become a significant issue. Previous studies have shown that an appropriatedirectional assignment can improve structural controllability; however, the evolution ofthe structural controllability of complex networks under attacks and cascading has alwaysbeen ignored. To address this problem, this study proposes a new edge orientation method(NEOM) based on residual degree that changes the link direction while conserving topologyand directionality. By comparing the results with those of previous methods in two randomgraph models and several realistic networks, our proposed approach is demonstrated to bean effective and competitive method for improving the structural controllability ofcomplex networks. Moreover, numerical simulations show that our method is near-optimal inoptimizing structural controllability. Strikingly, compared to the original network, ourmethod maintains the structural controllability of the network under attacks andcascading, indicating that the NEOM can also enhance the robustness of controllability ofnetworks. These results alter the view of the nature of controllability in complexnetworks, change the understanding of structural controllability and affect the design ofnetwork models to control such networks.     

Biomimetic Nucleation and Morphology Control of CaCO_3 in PAAm Hydrogels Synthesized from Lyotropic Liquid Crystalline Templates

Hydrogels have been thought to be the material which can provide appealing replacements of biological organisms. Pores of hydrogels synthesized from lyotropic liquid crystalline (LLC) templates were smaller in size and more uniform than those of traditional hydrogels. LLC poly‐acrylamide (PAAm) hydrogels were used as the growth media of CaCO₃. After copolymerized with acrylic acid and 2‐acrylamido‐2‐methylpropanesulfonic acid (AMPS), LLC hydrogels were modified with COOH and SO₃H, respectively. The effect of functional groups on the biomimetic mineralization of CaCO₃ was studied. Most of crystals from traditional hydrogels are rhombohedral and could not form aggregates. Only a few could aggregate and have a particular morphology with irregular orientation of subcrystal. Compared with crystals separated from traditional hydrogels, crystals growing in the LLC hydrogels were much more regulated and could form aggregates with particular morphology and regular orientation, that is, face (104) of rhombohedral subcrystals parallel to the surface of the macrocrystals. Modification of COOH and SO₃H groups made CaCO₃ subcrystal align more tightly. COOH had minor influences on the crystal orientation and small modification to the aggregate morphology. SO₃H groups could change the crystal orientation and morphology effectively. The aggregates are pseudo‐spherical and the face perpendicularity to the face (104) parallels to the surface of the aggregates.     

Combined Sign Coherent Factor and Delay Multiply and Sum Beamformer for Plane Wave Imaging

Plane wave imaging is a relatively new technique in ultrasound imaging. However, in traditional methods, the coherent information of different emissions and different elements are not considered. In fact, the sign coherent factor (SCF) can improve the lateral resolution of the imaging greatly. In addition, the delay multiply and sum (DMAS) beamformer is mainly based on the spatial correlation of background scattering signals, it has higher contrast and resolution, but suffers from energy loss at great depths. In this paper, combining the advantages of SCF and DMAS, the sign coherent factor delay multiply and sum (SCF-DMAS) beamformer for plane wave imaging is proposed. Unlike the traditional plane wave imaging, the proposed SCF-DMAS beamformer is based on the 2-D echo data set, which improves the imaging speed greatly. Finally, we simulated the point targets and the cyst phantom to evaluate the performance of proposed method. Compared with the traditional plane wave imaging, the lateral resolution of SCF-DMAS beamformer improves greatly for the point targets, and for the cyst phantom the contrast ratio (CR) and contrast-to-noise ratio (CNR) increased by 96.97 and by 79.98% respectively without reducing the frame rate.