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排序方式: 共有445条查询结果,搜索用时 15 毫秒
1.
João Marcos G. Barbosa Milenna K. Fernandes Rodrigues Lurian C. David Taynara C. e Silva Danielly A. Fortuna Lima Naiara Z. Pereira Emmanuel B. D'Alessandro Anselmo E. de Oliveira Paulo H. Jorge da Cunha Maria Clorinda S. Fioravanti Nelson R. Antoniosi Filho 《Biomedical chromatography : BMC》2020,34(11):e4935
An innovative volatolomic approach employs the detection of biomarkers present in cerumen (earwax) to identify cattle intoxication by Stryphnodendron rotundifolium Mart., Fabaceae (popularly known as barbatimão). S. rotundifolium is a poisonous plant with the toxic compound undefined and widely distributed throughout the Brazilian territory. Cerumen samples from cattle of two local Brazilian breeds (‘Curraleiro Pé-Duro’ and ‘Pantaneiro’) were collected during an experimental intoxication protocol and analyzed using headspace (HS)/GC–MS followed by multivariate analysis (genetic algorithm for a partial least squares, cluster analysis, and classification and regression trees). A total of 106 volatile organic metabolites were identified in the cerumen samples of bovines. The intoxication by S. rotundifolium influenced the cerumen volatolomic profile of the bovines throughout the intoxication protocol. In this way, it was possible to detect biomarkers for cattle intoxication. Among the biomarkers, 2-octyldecanol and 9-tetradecen-1-ol were able to discriminate all samples between intoxicated and nonintoxicated bovines. The cattle intoxication diagnosis by S. rotundifolium was accomplished by applying the cerumen analysis using HS/GC–MS, in an easy, accurate, and noninvasive way. Thus, the proposed bioanalytical chromatography protocol is a useful tool in veterinary applications to determine this kind of intoxication. 相似文献
2.
J. H. de Araújo J. B. M. da Cunha A. Vasquez L. Amaral J. T. Moro F. C. Montenegro S. M. Rezende M. D. Coutinho Filho 《Hyperfine Interactions》1991,67(1-4):507-511
57Fe Mössbauer effect measurements in the diluted Ising antiferromagnet Fe x Zn1?x F2 withx=0.25 andx=0.57 at temperatures between 4.2 and 55 K, are reported. DC suceptibility measurements show a spin-glass (SG) phase at low temperatures forx≤0.31. Our Mössbauer spectra show a phase transition to a SG state with antiferromagnetic order (AFSG) forx=0.25 and only antiferromagnetic order forx=0.57. 相似文献
3.
Vanessa de Freitas Cunha Lins Geraldo Francisco de Andrade Reis Carlos Roberto de Araujo 《Applied Surface Science》2006,253(5):2875-2884
In this work, electrochemical impedance spectroscopy and linear polarization are used in determining porosity of zinc phosphates, and of nickel and manganese modified zinc phosphates on electrogalvanized steel. The porosity of the phosphate layers ranges from 0.1% for the manganese-modified hopeite to 8% for hopeite, using the linear polarization and the electrochemical impedance spectroscopy techniques. The porosity values measured using the two techniques were in agreement. All impedance spectra of coated samples showed two steps, with two capacitive arcs and an inductive looping. 相似文献
4.
A. Paesano Jr. S. C. Zanatta S. N. De Medeiros L. F. CÓtica J. B. M. Da Cunha 《Hyperfine Interactions》2005,161(1-4):211-220
We have investigated the mechanosynthesis of gadolinium and yttrium iron garnets by high-energy ball-milling of α-Fe2O3 and Gd2O3 or α-Fe2O3 and Y2O3, respectively, followed by short thermal annealings conducted at moderate temperatures. The samples were characterized by X-ray diffraction and Mössbauer spectroscopy, in order to determine the influence of the milling time and annealing conditions on the final products. For as-milled samples of each rare-earth system, the results revealed the formation of perovskite phases, in relative amounts that depend on the milling time. The formation of garnet phases was observed in as-annealed samples treated at 1000°C for 2 h or 1100°C for 3 h, i.e., at very modest annealing requirements when compared with ordinary solid-state-reaction processes performed without previous high-energy milling. Also, the occurrence was verified of a milling time for which the relative amount of garnet phases formed by annealing was maximized. This time depends on the rare-earth composing the garnet phase and on the annealing temperature. 相似文献
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6.
L.?S.?Roman R.?M.?Q.?Mello F.?Cunha I.?A.?HümmelgenEmail author 《Journal of Solid State Electrochemistry》2004,8(2):118-121
We report the use of sulfonated polyaniline, SPAN, as a positive charge transporting layer in organic electronic devices, demonstrating that it can be used to significantly improve injection into conjugated polymers. The introduction of an intermediate SPAN layer improves device rectification, even when low-work-function anode materials such as tin oxide are used. 相似文献
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8.
The regiochemistry of the previously reported dimer of methyhlphenylcyclopropenone is corrected through analysis of the long-range 1H, 13C correlated (COLOC) 2D nmr spectrum. 相似文献
9.
Pedro A. Fernandes Elsa S. Henriques Vineet Pande Maria. J. Ramos Ana R. R. Maia André A. S. Almeida Bruno F. B. Silva Carla M. S. Ribeiro César F. B. Ribeiro David S. M. Ribeiro Diana A. P. Fonseca Eva M. S. Cunha Filipe R. N. C. Maia Joana A. A. Pereira João P. G. Pacheco Joaquim A. A. D. Ferreira Liliana R. C. Matos Manuel A. B. P. Pinto Maria C. S. Borges Paulo J. C. R. Magalhães Pedro F. R. D. Teixeira Pedro N. B. C. Veloso Ricarte J. F. Ferreira Sandro S. Gomes Tiago F. Barros Tiago S. J. T. Selão Virgínia M. M. C. Fernandes 《Theoretical chemistry accounts》2005,113(4):197-204
We present a series of new inhibitors of the association between nuclear factor kappa B (NF-B) and the corresponding B site in DNA. They were designed using the lead compound 15-deoxy-12,14 -prostaglandin J2 (PGJ2), which is a natural product with demonstrated inhibitory efficiency for this system. First, the binding mode of PGJ2 to NF-B was unraveled by GOLD docking calculation. Subsequently, substitutions were made to PGJ2 to optimize its association with NF-B. Care was taken not to strongly increase the reactivity of the new compounds, and to keep the overall shape, size and hydrophilicity of the lead compound, which should render them a similar bioavailability. Molecular mechanics calculations were performed to decide on the suitability of the substitutions, and to evaluate the energies of association with NF-B. Density functional theory calculations were performed also to study the overall reactivity of the substituted drugs towards NF-B. Important general conclusions were obtained, concerning the improvement of these natural inhibitors; namely, a set of rational methodologies were deduced to improve the association between the PGJ2 derivatives and NF-B, and their efficiency demonstrated by generating a set of substituted complexes, some of them with a very much increased affinity for NF-B, opening new doors to enlarge the therapeutic capabilities of this class of drugs. 相似文献
10.
I. I. L. Cunha 《Journal of Radioanalytical and Nuclear Chemistry》2001,249(1):257-261
Sediment cores were collected at the Cananeia-Iguape Estuary and thelevels of 210Pb, 226Ra and 137Cs were measuredby gamma-ray spectrometry. The total 210Pb levels in sedimentsvaried from 13.5 to 122.5 Bq . kg —1 , for 226Raranged from 2.4 to 28 Bq . kg —1 and for 137Csfrom 0.28 to 6.1 Bq . kg —1 . Sedimentation rates were calculatedfrom the slope of the excess 210Pb profile in the core. The valuesobtained varied from 5 to 10 mm . y—1 , depending on thesediment deposition inputs in the local of sampling. 相似文献