全文获取类型
收费全文 | 198篇 |
免费 | 0篇 |
专业分类
化学 | 195篇 |
物理学 | 3篇 |
出版年
2016年 | 1篇 |
2015年 | 1篇 |
2014年 | 2篇 |
2012年 | 1篇 |
2011年 | 1篇 |
2002年 | 2篇 |
2001年 | 6篇 |
2000年 | 7篇 |
1999年 | 5篇 |
1998年 | 3篇 |
1997年 | 6篇 |
1996年 | 2篇 |
1995年 | 7篇 |
1994年 | 7篇 |
1993年 | 4篇 |
1992年 | 10篇 |
1991年 | 10篇 |
1990年 | 6篇 |
1989年 | 2篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1985年 | 1篇 |
1984年 | 6篇 |
1983年 | 4篇 |
1982年 | 6篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 6篇 |
1975年 | 5篇 |
1974年 | 9篇 |
1973年 | 11篇 |
1972年 | 10篇 |
1971年 | 7篇 |
1970年 | 11篇 |
1969年 | 11篇 |
1968年 | 5篇 |
1967年 | 1篇 |
1966年 | 1篇 |
1965年 | 1篇 |
排序方式: 共有198条查询结果,搜索用时 15 毫秒
1.
V. O. Kur'yanov T. F. Zhelobetskaya A. E. Zemlyakov V. Ya. Chirva 《Chemistry of Natural Compounds》1993,29(1):103-106
The synthesis has been effected of derivatives of MDP having a spacer with an amino or carboxy group. The final stage of the synthesis was the condensation of Boc-L-Ala-D-iGln with 6-aminohexanol (followed by the two-stage replacement of the hydroxy by an azido group) or with benzyl 6-aminohexanoate.Simferopol' State University. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 122–125, January–February, 1993. 相似文献
2.
V. Ya. Chirva P. K. Kintya V. A. Sosnovskii P. E. Krivenchuk N. Ya. Zykova 《Chemistry of Natural Compounds》1970,6(2):213-215
Conclusions The structure of two triterpone glycosides fromSapindus mukorossi Gaertn. has been established. It has been shown that sapindoside A is hederagenin 3-O--L-arabinosyl-(2 1)--L-rhamnopyranoside and sapindoside B is the 3-O--L-arabopyranosyl-(2 1)-O--L-rhamnopyranosyl-(3 1)--D-xylopyranoside. 相似文献
3.
Two furofuranoid lignan glycosides, having the structures of (+)-syringaresinol 4′,4″-di-β-D-glucopyranoside (1) and (+)-syringaresinol 4′-β-D-glucopyranoside (2), and also 2-methylbut-3-en-2-yl β-D-glucopyranoside (3), have been isolated from an extract of the leaves ofNolina microcarpa (fam. Dracaenaceae). 相似文献
4.
G. V. Shevchuk Yu. S. Vollerner A. S. Shashkov M. B. Gorovits V. Ya. Chirva 《Chemistry of Natural Compounds》1991,27(6):706-711
Two new glycosides which have been called nolinofurosides G(I) and H(III), have been isolated from the leaves ofNolina microcarpa. Nolinofuroside G is the sodium salt of 26-β-D-glucofuranosyloxy-(25S)-furost-5,20(22)-diene-1β, 3β-diol 1-sulfate, and nolinofuroside
H is the sodium salt of 1-β-D-fucopyranosyloxy-26-β-D-glucopyranosyloxy-(25S)-furost-5,20(22)-dinen-1β-3β-ol 3-sulfate.
M. V. Frunze Simferopol' State University. Institute of the Chemistry of Plant Substances, Uzbek. Academy of Sciences, Tashkent.
Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 801–806, November–December, 1991. 相似文献
5.
V. S. Strigunov V. I. Grishkovets A. S. Shashkov V. Ya. Chirva 《Chemistry of Natural Compounds》2001,37(5):462-465
Minor monodesmoside triterpene glycosides St-A, St-B, St-C
1
, St-D
1
, St-C
2
, and St-D
2
were isolated from stem bark ofTetrapanax papyriferumC. Koch (Araliaceae). The structures of oleanolic and echinocystic acid 3-O--L-arabinopyranosides, oleanolic and echinocystic acid 3-O--D-glucopyranosyl-(13)-O--L-arabinopyranosides, and oleanolic and echinocystic acid 3-O--D-galactopyranosyl-(12)-O--L-arabinopyranosides, respectively, were proposed. Glycosides St-C
2
, St-D
1
, and St-D
2
are new triterpene glycosides. The structures of the isolated compounds were established using chemical methods and NMR spectroscopy. 相似文献
6.
Alternative unidirectional methods for synthesizing methyl (methyl α-D-galactopyranosid)uronate and its mono-O-methyl ethers by the oxidation (with CrO3-H2SO4-acetone) of the corresponding methyl O-benzyl-O-methyl-α-D-galactopyranosides having unsubstituted 6-OH groups to the corresponding methyl O-benzyl-O-methyl-α-D-galactouronic acids followed by esterification with CH2N2 and the catalytic hydrogenolysis of the benzyl groups are proposed. 相似文献
7.
V. I. Grishkovets A. E. Kondratenko N. V. Tolkacheva A. S. Shashkov V. Ya. Chirva 《Chemistry of Natural Compounds》1995,30(6):689-692
The leaves of common ivy have yielded 11 triterpene glycosides: the 3-O--L-pyranosides of oleanolic acid (1), of echinocystic acid (2), and of hederagenin; the 3-O-[O--L-rhamnopyranosyl-(12)--L-arabinopyranoside]s of oleanolic acid (4), of echinocystic acid (5), and of hederagenin (6); the O--L-rhamnopyranosyl-(14)-O--D-glucopyranosyl-(16)-O--D-glucopyranosyl ester of hederagenin 3-O--L-pyranoside (7); the O--D-glucopyranosyl-(16)-O--D-glucopyranosyl ester of hederagenin 3-O-[O--L-pyranosyl-(12)--L-arabinopyranoside] (9); and the O--L-rhamnopyranosyl-(14)-O--D-glucopyranosyl-(16)-O--D-glucopyranosyl esters of oleanolic acid, echinocystic acid, and hederagenin 3-O-[O--L-rhamnopyranosyl-(12)--D-glucopyranoside]s (8), (10), and (11), respectively. This is the first time that compounds (1), (2), (5), (7), (9), and (10) have been found in this plant.Simferopol' State University. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 742–746, November–December, 1994. 相似文献
8.
The use of HgI2 as catalyst in the synthesis oftrans-glycosides of N-acetylglucosamine is described. Using this catalyst, -glycosides of N-acetylglucosamine with aglycons of different structures and lyophilicities have been synthesized. The possibility of performing oligosaccharide synthesis has been demonstrated. 相似文献
9.
The synthesis has been achieved of the hexadecyl -glycosides of N-acetylmur-amoyl-L-alanyl-D-glutamic acid and N-acetyl-nor-muramoyl-L-alanyl-D-glutamic acid and of the -octadecylamide of N-acetylmuramoyl-L-alanyl-D-glutamic acid — lipophilic glycopeptides of differing hydrophilic-lipophilic balance.M. V. Frunze Simferopol' State University. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 553–557, July–August, 1991. 相似文献
10.
V. I. Grishkovets V. S. Strigunov A. S. Shashkov V. Ya. Chirva 《Chemistry of Natural Compounds》2001,37(2):167-172
Stem bark ofTetrapanax papyriferumC. Koch., Araliaceae, yielded new triterpene glycosides 28-O--L-rhamnopyranosyl-(14)-O-(6-O-acetyl--D-glucopyranosyl)-(16)-O--D-glucopyranosyl esters of the 3-O-[-D-glucopyranosyl-(13)-[-D-galactopyranosyl-(12)]-O--L-arabinopyranosides of oleanolic and echinocystic acids. The structures of these substances were established using chemical and physicochemical methods 相似文献