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1.
Rudzevich Y Vysotsky MO Bohmer V Brody MS Rebek Jr J Broda F Thondorf I 《Organic & biomolecular chemistry》2004,2(21):3080-3084
The dimerization of tetratolyl- and tetratosyl-urea derivatives 1 and 2, derived from a tetrapentoxy calix[4]arene in the cone conformation and of the corresponding tetra-urea derivatives 3 and 4, in which the cone conformation is rigidified by the two crown-3 tethers, have been studied. All six possible equimolar mixtures were examined by 1H NMR using CDCl3 and CD2Cl2 as solvents. While no heterodimers are found for the combinations 1/3 and 2/4 in either solvent, all remaining combinations lead to the (exclusive) formation of heterodimers in CD2Cl2. In CDCl3 heterodimers are only observed for the combinations of 3 with 2 or 4. These results are discussed in terms of entropic and enthalpic contributions and compared with MD-simulations in a box of chloroform solvent molecules. 相似文献
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T. Åkesson M.G. Albrow S. Almehed O. Benary H. Bøggild O. Botner H. Brody V. Burkert A. Di Ciaccio D. Cockerill S. Dagan E. Dahl-Jensen I. Dahl-Jensen G. Damgaard W.M. Evans C.W. Fabjan S. Frankel C. Woody 《Nuclear Physics B》1982,209(2):321-335
Calorimeters downstream of the intersection of pα and αα beams in the ISR have been used to study the hadronization of excited nucleons. These data extend and support the conclusions from previous studies of the A-dependence of particle multiplicities in ultrarelativistic p-nucleus collisions, which provided evidence that the proton hadronizes outside the nuclear volume. 相似文献
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Pajewski R Garcia-Medina R Brody SL Leevy WM Schlesinger PH Gokel GW 《Chemical communications (Cambridge, England)》2006,(3):329-331
An Ussing chamber was used to demonstrate that synthetic amphiphilic anion transporters function as chloride transporters in mammalian airway epithelial cells. 相似文献
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R H Brody H G Edwards A M Pollard 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2001,57(6):1325-1338
FT-Raman spectra were collected from fossil resins originating from a variety of geographical locations. The spectral profiles of most of the fossil resins could be related to modern resins containing diterpenoid components with predominantly labdane skeletons. The spectra collected from the fossil resin sample from Borneo differed from other fossil resins and was found to contain triterpenoid components. The differences in the spectral profile of fossil resins containing diterpenoid components are shown to relate to differences in level of maturation rather than geographical origin. FT-Raman spectra of fossil resins cannot be used to distinguish source although the degree of maturation can be used as an indicator to narrow the range of possible geographical origins. 相似文献