排序方式: 共有78条查询结果,搜索用时 15 毫秒
1.
CV Tomy D Pal SS Banerjee S Ramakrishnan AK Grover S Bhattacharya MJ Higgins G Balakrishnan McK Paul 《Pramana》2002,58(5-6):925-935
The weakly pinned single crystals of the hexagonal 2H-NbSe2 compound have emerged as prototypes for determining and characterizing the phase boundaries of the possible order-disorder
transformations in the vortex matter. We present here a status report based on the ac and dc magnetization measurements of
the peak effect phenomenon in three crystals of 2H-NbSe2, in which the critical current densities vary over two orders of magnitude. We sketch the generic vortex phase diagram of
a weakly pinned superconductor, which also utilizes theoretical proposals. We also establish the connection between the metastability
effects and pinning. 相似文献
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Alberti G Brunet E Dionigi C Juanes O de La Mata MJ Rodríguez-Ubis JC Vivani R 《Angewandte Chemie (International ed. in English)》1999,38(22):3351-3353
The hydrophilic oxygen atoms of polyethylenoxide chains inserted as pillars in gamma-zirconium phosphate form hydrogen bonds with the acid groups of the host. As a result the pillars are almost perpendicular to the gamma layers. Upon changing the pH level of the supernatant solution the hydrogen bonds are broken and the pillars become almost perpendicular to the layers (shown schematically). Thus there is a reversible enlargement-shortening of the interlayer space. 相似文献
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Garavelli M Ruggeri F Ogliaro F Bearpark MJ Bernardi F Olivucci M Robb MA 《Journal of computational chemistry》2003,24(11):1357-1363
MMVB is a QM/MM hybrid method, consisting of a molecular mechanics force field coupled to a valence bond Heisenberg Hamiltonian parametrized from ab initio CASSCF calculations on several prototype molecules. The Heisenberg Hamiltonian matrix elements Q(ij) and K(ij), whose expressions are partitioned here into a primary contribution and second-order correction terms, are calculated analytically in MMVB. When the original MMVB force field fails to produce potential energy surfaces accurate enough for dynamics calculations, we show that significant improvements can be made by refitting the second-order correction terms for the particular molecule(s) being studied. This "local" reparametrization is based on values of K(ij) extracted (using effective Hamiltonian techniques) from CASSCF calculations on the same molecule(s). The method is demonstrated for the photoisomerization of s-cis butadiene, and we explain how the correction terms that enabled a successful MMVB dynamics study [Garavelli, M.; Bernardi, F.; Olivucci, M.; Bearpark, M. J.; Klein, S.; Robb, M. A. J Phys Chem A 2001, 105, 11496] were refitted. 相似文献
6.
Izmaylov AF Mendive-Tapia D Bearpark MJ Robb MA Tully JC Frisch MJ 《The Journal of chemical physics》2011,135(23):234106
We consider photoinduced electronic transitions through conical intersections in large molecules. Starting from the linear vibronic model Hamiltonian and treating linear diabatic couplings within the second order cumulant expansion, we have developed a simple analytical expression for the time evolution of electronic populations at finite temperature. The derived expression can be seen as a nonequilibrium generalization of the Fermi golden rule due to a nonequilibrium character of the initial photoinduced nuclear distribution. All parameters in our model are obtained from electronic structure calculations followed by a diabatization procedure. The results of our model are found to agree well with those of quantum dynamics for a test set of systems: fulvene molecule, 2,6-bis(methylene) adamantyl cation, and its dimethyl derivative. 相似文献
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Prince PD Bearpark MJ McGrady GS Steed JW 《Dalton transactions (Cambridge, England : 2003)》2008,(2):271-282
A range of hydridosilicate anions has been prepared and characterised by spectroscopic, structural and computational methods. The general approach involved reaction of KH with a neutral silane precursor in the presence of [18]crown-6. In this manner, [K([18]crown-6)]+ salts of [Ph3SiH2](-) (1), [Ph3SiF2](-) (9), and [(p-FC6H4)3SiHF](-)/[(p-FC6H4)3SiH2](-) (12) were stabilised and characterized by NMR spectroscopy and X-ray diffraction. In each case, the anion adopts a trigonal bipyramidal (TBP) geometry with three equatorial phenyl groups eclipsing the axial Si-H/Si-F bonds. The Si-H[dot dot dot]K distances, along with DFT calculations on 1, indicate an electrostatic interaction that does not dictate the geometry adopted by the anion. A [H2SiOiPr3](-) salt (7) has also been crystallised in the same way; X-ray diffraction shows in this case a distorted TBP array with axial hydride ligands, and both Si-H[...]K and Si-O[...]K interactions. 1H NMR exchange experiments show 1 to undergo facile hydride exchange with Ph3SiH. Compound 1 acts as a good hydride transfer reagent to a variety of substrates, but its high reactivity often results in redistribution and other side reactions. 相似文献
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Lasorne B Bearpark MJ Robb MA Worth GA 《The journal of physical chemistry. A》2008,112(50):13017-13027
In this work, we investigate general mechanistic principles that control reaction selectivity following S(1)/S(0) internal conversion in benzene. A systematic relationship is drawn between the varying topology of an extended seam of conical intersection and the balance between two competitive radiationless decay channels: photophysical (benzene reactant regeneration) and photochemical (prefulvene product formation). This is supported by a model quantum dynamics study, using a direct dynamics approach based on variational multiconfiguration Gaussian wavepackets, where initial excitation of specific vibrational modes is designed to generate dynamical pathways that reach selected targets regions of the seam. High-energy regions of the seam are found to be sloped and in favor of the photophysical channel, while lower-energy regions are peaked and give access to the photochemical channel. This changeover could in principle be exploited to define targets for optimal control, by exciting different combinations of specific vibronic levels in S(1), accessing different regions of the seam, and giving different products. 相似文献
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Sicilia F Blancafort L Bearpark MJ Robb MA 《The journal of physical chemistry. A》2007,111(11):2182-2192
In this paper, we present a practical approach for the characterization of critical points on conical intersection seams as either local minima or saddle points using second-derivative technology. The utility of this methodology is illustrated by the analysis of seven S0/S1 (2Ag/1Ag) conical intersection points involved in the photochemistry of butadiene. The characterization of critical points on the crossing seam requires second derivatives computed in curvilinear coordinates. Using such coordinates, we can represent the branching space and the intersection space to second order. Although these curvilinear coordinates are conceptually important, they also give rise to two additional practical applications. First, such coordinates yield information on the nature of vibrational modes that are stimulated following radiationless decay at a crossing point. Second, the second-order force field is directly comparable to experimental spectroscopic data for Jahn-Teller systems. We will illustrate the latter idea for the cyclopentadienyl radical. 相似文献