The electrical properties of semiconductor/metal,semiconductor/liquid,and semiconductor/conducting polymer contacts

Critical comparisons are drawn between the basic electrical properties of semiconductor/metal, semiconductor/liquid, and semiconductor/conducting polymer junctions. A theoretical model is developed to describe the basic current-voltage properties of semiconductor contacts, with emphasis on the contrasts between ideal and observed behavior. Using the concepts from this model, the characteristics of a variety of semiconductor contacts are evaluated. The discussion focuses on the following semiconductors: Si, GaAs, InP, and II-VI compounds based on the Cd-(chalcogenide) materials.     

Reciprocal Ontological Models Show Indeterminism Comparable to Quantum Theory

We show that within the class of ontological models due to Harrigan and Spekkens, those satisfying preparation-measurement reciprocity must allow indeterminism comparable to that in quantum theory. Our result implies that one can design quantum random number generator, for which it is impossible, even in principle, to construct a reciprocal deterministic model.     

Reduction of quantum phase fluctuations in intermediate states

Recently we have shown that the reduction of the Carruthers-Nieto symmetric quantum phase fluctuation parameter (U) with respect to its coherent state value corresponds to an antibunched state, but the converse is not true. Consequently reduction of U is a stronger criterion of nonclassicality than the lowest order antibunching. Here we have studied the possibilities of reduction of U in intermediate states by using the Barnett-Pegg formalism. We have shown that the reduction of phase fluctuation parameter U can be seen in different intermediate states, such as binomial state, generalized binomial state, hypergeometric state, negative binomial state, and photon added coherent state. It is also shown that the depth of nonclassicality can be controlled by various parameters related to intermediate states. Further, we have provided specific examples of antibunched states, for which U is greater than its Poissonian state value.     

Effect of ion beam irradiation on palladium (II) acetyl acetonate dispersed in polymer matrix

Composites, containing different concentrations of palladium (II) acetylacetonate in polymethyl methacrylate (PMMA) matrix were prepared by vigorous mixing. PMMA was prepared by solution polymerization technique. The composites were irradiated with a 120 MeV Ni¹⁰⁺ beam at two different fluences of 1×10¹¹ and 5×10¹² ions/cm² to study ion-induced effects on their dielectric, structural properties and surface morphology. AC electrical properties of these samples were studied in the frequency range 100 Hz to 10 MHz. The dielectric permittivity/loss shows frequency dependent behavior and it obeys the universal law of dielectric (i.e. ?α f ^n?1) for pristine and irradiated samples at high frequency. The crystalline size and crystallinity of the composites were studied by X-ray diffraction analysis. Decrease in peak intensity after irradiation signifies the amorphization which is also responsible for decrease in T _g as obtained by means of differential scanning calorimetry measurement. Fourier transform infrared spectra also support this result. Surface roughness increases upon irradiation as observed from scanning electron microscopy.     

White organic light emitting diodes based on DCM dye sandwiched in 2-methyl-8-hydroxyquinolinolatolithium

Stable white electroluminescence (EL) has been achieved from organic LED, in which an ultrathin 4-(dicyanomethylene)-2-methyl-6-(p-dimethyl-aminostyryl)-4H-pyran (DCM) dye layer has been inserted in between two 2-methyl-8-hydroxyquinolinolatolithium [LiMeq] emitter layer and by optimizing the position of the DCM dye layer from the α-NPD/LiMeq interface. Electroluminescence spectra, current-voltage-luminescence (I-V-L) characteristics of the devices have been studied by changing the position of the dye layer. As the distance of DCM layer from α-NPD/LiMeq interface is increased, the intensity of host emission enhances rapidly. Introduction of thin layer of DCM in emissive layer increases the turn on voltage. The best Commission International de L’ Eclairage (CIE) coordinates i.e. (0.32, 0.33) were obtained with device structure ITO/α-NPD(30 nm) /LiMeq(10 nm)/DCM(1 nm)/LiMeq(25 nm)/BCP(6 nm)/Alq₃(28 nm)/LiF(1 nm)/Al(100 nm). The EL spectrum covers the whole visible spectra range 400-700 nm. The color rendering index (CRI) for our best white light (Device 4) is 47.4. The device shows very good color stability in terms of CIE coordinates with voltages. The maximum luminescence 1240 cd/m⁻² has been achieved at 19 V.     

Performance analysis of an integrated scheme in optical burst switching high-speed networks

A new integrated scheme based on resource-reservation and adaptive network flow routing to alleviate contention in optical burst switching networks is proposed. The objective of the proposed scheme is to reduce the overall burst loss in the network and at the same time to avoid the packet out-of-sequence arrival problem. Simulations are carried out to assess the feasibility of the proposed scheme. Its performance is compared with that of contention resolution schemes based on conventional routing. Through extensive simulations, it is shown that the proposed scheme not only provides significantly better burst loss performance than the basic equal proportion and hop-length based traffic routing algorithms, but also is void of any packet re-orderings.     

Consistency and variations in optical characteristics of four-layer polymeric waveguides

In the present work, four-layer polymeric waveguides have been fabricated and characterized by interchanging the film layer. Using polyvinyl alcohol (PVA) and styrene acrylonitrile (SAN) polymer it has been shown that polymers do not loose their own property in multilayer structure and better efficiency can be achieved in the form of low propagation losses and mode filtration. Due to high contrast of PVA and SAN films, a broad spectrum of refractive index in four-layer structure has been achieved.     

Noble gas halides: The B → X and D → X systems of 136Xe35Cl

The B → X (2870–3100 Å) and D → X (2250–2370 Å) band systems of ¹³⁶Xe³⁵Cl are photographed and vibrationally analyzed. A simultaneous least-squares fit of 41 band-heads in the B-X system and 35 in D-X yields, in part, the following constants (in cm^?1): T_eB = 32 405.8, T_eD = 42 347.9, ω_eB = 194.75, ω_eD = 204.34, ω_eX = 26.22. The ground state dissociation energy ($\text{D}$″_e) is estimated to be 281 ± 10 cm^?1. Potential curves are derived for all three states through Franck-Condon calculations. From these curves the D-state internuclear distance is 0.09 ± .02 Å smaller than the B-state distance.     

Vortex dynamics of a trapezoidal bluff body placed inside a circular pipe

The influence of Reynolds number and blockage ratio on the vortex dynamics of a trapezoidal bluff body placed inside a circular pipe is studied experimentally and numerically. Low aspect ratio, high blockage ratio, curved end conditions (junction of pipe and bluff body), axisymmetric upstream flow with shear and turbulence are some of the intrinsic features of this class of bluff body flows which have been scarcely addressed in the literature. A large range (200:200,000) of Reynolds number (Re_D) is covered in this study, encompassing all the three pipe flow regimes (laminar, transition and turbulent). Four different flow regimes are defined based on the distinct features of Strouhal number (St)–Re_D relation: steady, laminar irregular, transition and turbulent. The wake in the steady regime is stationary with no oscillations in the shear layer. The laminar regime is termed as irregular owing to irregular vortex shedding. The vortex shedding in this regime is observed to be symmetric. The emergence of separation bubble downstream of the bluff body on either side is another interesting feature of this regime, which is further observed to be symmetric. Two pairs of mean streamwise vortices are noticed in the near-wake regime, which are termed as reverse dipole-type wake topology. Beyond the irregular laminar regime, the Strouhal number falls gradually and vortex shedding becomes more periodic. This regime is named transition and occurs close to the Reynolds number at which transition to turbulence takes place in a fully developed pipe. The turbulent regime is characterised by a nearly constant Strouhal number. Typical Karman-type vortex shedding is noticed in this regime. The convection velocity, wake width formation length and irrecoverable pressure loss are quantified to highlight the influence of blockage ratio. These results will be useful to develop basic understanding of vortex dynamics of confined bluff body flow for several practical applications.