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1.
A new scheme for controlling photodissociation through preparation of a variationally optimized linear superposition of field free vibrational eigenstates is applied for selective control of IBr and HI dissociation. The dependence of photodissociation on various field parameters and initial conditions is examined to investigate the mechanistic basis of selective control. The parametric equations of motion approach for determining vibrational dynamics as a function of field parameters without having to solve the time dependent Schrödinger equation explicitly for each field parameter separately is outlined and its use to identify field characteristics which will provide the requisite population mix represented by the optimal linear superposition of vibrational states is advocated. 相似文献
2.
A method for the construction of the second constant of motion in fourth order is carried out. Correspondingly the fourth order potential equation is obtained whose solutions directly provide the classical integrable systems. Second constant of motion is obtained for a large class of potentials. Quantum invariants are also obtained with second order quantum corrections of the order O(?2) to the corresponding classical invariants. The phase space diagrams for these cases are drawn using a mathematical computer software package in two dimensions. 相似文献
3.
C.P. Paul P. Ganesh S.K. Mishra P. Bhargava J. Negi A.K. Nath 《Optics & Laser Technology》2007,39(4):800-805
This paper presents an investigation of laser rapid manufacturing (LRM) for Inconel-625 components. LRM is an upcoming rapid manufacturing technology, it is similar to laser cladding at process level with different end applications. In general, laser-cladding technique is used to deposit materials on the substrate either to improve the surface properties or to refurbish the worn out parts, while LRM is capable of near-net shaping the components by layer-by-layer deposition of the material directly from CAD model. In the present study, a high-power continuous wave (CW) CO2 laser system, integrated with a co-axial powder-feeding system and a three-axis workstation were used. The effect of processing parameters during LRM of Inconel-625 was studied and the optimum set of parameters for the maximum deposition rate was established employing Orthogonal L9 array of Taguchi technique. Results indicated that the powder feed rate and the scan speed contributed about 56% and 26%, respectively to the deposition rate, while the influence of laser power was limited to 10% only. Fabricated components were subjected to non-destructive testing (like—ultrasonic testing, dye-penetrant testing), tensile testing, impact testing, metallographic examinations and micro-hardness measurement. The test results revealed defect-free material deposition with improved mechanical strength without sacrificing the ductility. 相似文献
4.
Electric fields of the anions, cations and neutral forms of 2-aminopurine and 6-thioguanine have been mapped. Certain important
features of the maps are similar to those found earlier in the neutral and ionic forms of adenine and guanine. The computed
electric field patterns satisfactorily explain reactive sites and biological activity of the molecules. 相似文献
5.
6.
The occurrence of charge on recoil56Mn produced by the (n,γ) reaction in polycrystalline potassium permanganate has been examined using the ‘charge plate technique’.
From considerations of capture gamma ray decay schemes and internal conversion it appears that, in a condensed medium, the
recoil atom develops charge after losing much of its initial kinetic energy which allows collection on charged electrodes.
Preliminary findings were presented at the International Symposium on Radiochemistry and Radiation Chemistry, RC-41 BARC,
Bombay, Feb. 4–6 (1991). 相似文献
7.
8.
Devdutt Chaturvedi Nisha Mishra Virendra Mishra 《Monatshefte für Chemie / Chemical Monthly》2007,70(6):57-60
A novel Mitsunobu-based protocol was developed for the synthesis of carbamates from the corresponding alcohols using carbon dioxide and amines
in good to excellent yields. This protocol is mild, chemoselective, and efficient compared to other reported methods. 相似文献
9.
Traditional inventory models assume that a buyer places one order with a supplier in each order cycle. A large number of researchers have studied the benefits of dual sourcing such that an order quantity is split and placed simultaneously with two suppliers. We show that many of the benefits of dual sourcing are due to order splitting rather than using two suppliers. We investigate order splitting with one supplier such that the first part of the order is sent out immediately but the second part of the order is released later (scheduled-release). Through extensive computational results, we show that in many situations where dual sourcing or the use of a cheaper supplier would be cost effective, single sourcing with order splitting using scheduled-release orders is better. The paper provides a quantitative rationale to continue with one supplier. We also summarize the qualitative reasons to prefer single sourcing or multiple sourcing. 相似文献
10.
The adsorption of mercury(II) on potassium titanate has been studied in chloride media at different pH values, adsorbate concentrations and temperatures. Effect of different ligands and acid concentrations on the uptake was also investigated. Desoprtion studies were also done to check the reversibility of the process. Interestingly a more or less constant and high value of adsorption has been found at different temperatures, pH values and concentrations and a decrease in the uptake with an increase in the bulk acid concentration was observed. 相似文献