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1.
Adam Kiersnowski Jochen S. Gutmann Jacek Pigłowski 《Journal of Polymer Science.Polymer Physics》2007,45(17):2350-2367
ε‐caprolactone was polymerized in the presence of neat montmorillonite or organomontmorillonites to obtain a variety of poly(ε‐caprolactone) (PCL)‐based systems loaded with 10 wt % of the silicates. The materials were thoroughly investigated by different X‐ray scattering techniques to determine factors affecting structure of the systems. For one of the nanocomposites it was found that varying the temperature in the range corresponding to crystallization of PCL causes reversible changes in the interlayer distance of the organoclay. Extensive experimental and literature studies on this phenomenon provided clues indicating that this effect might be a result of two‐dimensional ordering of PCL chains inside the galleries of the silicate. Small angle X‐ray scattering and wide angle X‐ray scattering investigation of filaments oriented above melting point of PCL revealed that polymer lamellae were oriented perpendicularly to particles of unmodified silicate, while in PCL/organoclay systems they were found parallel to clay tactoids. Calorimetric and microscopic studies shown that clay particles are effective nucleating agents. In the nanocomposites, PCL crystallized 20‐fold faster than in the neat polymer. The crystallization rate in nanocomposites was also significantly higher than in microcomposite. Further research provided an insight how the presence of the filler affects crystalline fraction and spherulitic structure of the polymer matrix in the investigated systems. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2350–2367, 2007 相似文献
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We provide a proof of Connes’ formula for a representative of the Hochschild class of the Chern character for (p,∞)-summable spectral triples. Our proof is valid for all semifinite von Neumann algebras, and all integral p?1. We employ the minimum possible hypotheses on the spectral triples. 相似文献
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In this paper a further refinement of Dade's projective conjecture, due to Boltje, is presented. This new statement includes ideas first published by Isaacs and Navarro as well as the recent contractibility version of Alperin's conjecture introduced by Boltje. Leaning heavily on the work of Robinson, weaker forms of the conjecture are proved in the case of p-solvable groups. 相似文献
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Episulfidation of (E)-cyclooctene and (E)-cyclononene was achieved with elemental sulfur by using a catalytic amount of a molybdenum oxo complex. 相似文献
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Some new stabilisers having a chelating polymeric structure were synthesised and characterised, i.e., 8-hydroxyquinoline-formaldehyde chelating resins of Cd, Zn, and Pb. The efficiency of these new stabilisers was studied with respect to PVC. The stabilised PVC samples showed outstanding thermal stability as studied by thermogravimetric techniques, i.e., the percentage of HCl evolved reduced remarkably with increasing polymer decomposition temperature. 相似文献
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The mechanism of degradation of 9-acetoxy-10-arylanthracenes to anthraquinose with the use of HNO3 in AcOH has been reported. This was proved by way of example on 9-acetoxy-10-(4′-acetoxyphenyl )anthracene (1) by means of separation and identification of intermediate products , and . 相似文献
10.
We present solubility and diffusion data for the gases methane and carbon dioxide in the polymer poly(vinylidene fluoride). The polymer was cut from extruded piping intended for use in offshore oil and gas applications. Measurements were carried out using a purpose-built high-pressure microbalance. These properties were determined in the temperature range 80-120 °C and in the pressure range 50-150 bar for methane and 20-40 bar for carbon dioxide. In general, good agreement was obtained for similar measurements reported in the literature. Solubility follows a Henry’s law (linear) dependence with pressure. Diffusion coefficients for each of the gases in the polymer were also measured using the balance. Activation energies for diffusion and heats of solution for the two gases in the polymer were also determined. 相似文献