全文获取类型
收费全文 | 69篇 |
免费 | 3篇 |
专业分类
化学 | 35篇 |
力学 | 4篇 |
数学 | 6篇 |
物理学 | 27篇 |
出版年
2023年 | 1篇 |
2021年 | 1篇 |
2019年 | 3篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 2篇 |
2015年 | 2篇 |
2014年 | 4篇 |
2013年 | 2篇 |
2012年 | 2篇 |
2011年 | 4篇 |
2010年 | 2篇 |
2009年 | 2篇 |
2008年 | 3篇 |
2007年 | 5篇 |
2006年 | 6篇 |
2005年 | 5篇 |
2003年 | 1篇 |
2002年 | 2篇 |
2001年 | 1篇 |
2000年 | 6篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1991年 | 1篇 |
1989年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有72条查询结果,搜索用时 15 毫秒
1.
R.G. Abhilash Kumar K. Vinod U. Syamaprasad 《Applied Physics A: Materials Science & Processing》2007,88(2):243-247
MgB2/Fe wires were prepared by electrical self-heating of in situ powder-in-tube wires for the first time at ambient conditions.
Characterization of the wires processed at 750 °C, 800 °C and 850 °C for 15 min by XRD, SEM, ϱ–T, susceptibility and JC measurements shows that the MgB2 formed is of high quality particularly with respect to phase purity and transport JC. The method considerably reduces the overall energy consumption vis-à-vis the production cost, simplifies the complexity
of the fabrication procedure and is promising for manufacture of high-quality MgB2 superconducting wires.
PACS 74.70.Ad; 74.62.Bf; 74.25.Fy; 74.25.Ha; 81.20.Hy 相似文献
2.
3.
Summary A study of the Cd(CN)2 +x X– [Cd(CN)2X
x
]
x–
equilibrium (where X = Cl, Br or CNS) has been carried out at 18° and 38° by measuring the solubility of cadmium cyanide in potassium chloride, bromide and thiocyanate at various concentrations, and at a high ionic strength (6 M) maintained with sodium perchlorate to minimise the effect of activity coefficients. Equilibrium constants forx = 1 and 2 have been calculated and clearly favour the situation wherex = 1. H values for the dissociation of [Cd(CN)2X]– have also been calculated. 相似文献
4.
A facile cycloaddition reaction of 8,8-dicyanoheptafulvene with styrenes leading to the corresponding [8+2] and [4+2] adducts in excellent yields is described. 相似文献
5.
Gayatri Mohanto S. R. Abhilash D. Kabiraj N. Madhavan R. K. Bhowmik 《Journal of Radioanalytical and Nuclear Chemistry》2014,299(2):1129-1131
Targets of isotopically enriched 170Er (erbium) were prepared on 45 μg/cm2 carbon backing using the method of vacuum evaporation. Another layer of carbon with thickness 23 μg/cm2 was deposited on it as a protective cap with the help of an electron gun. Carbon backing, Er and the capping carbon layer were deposited using resistive heating and electron gun deposition without disturbing the vacuum. The thickness of 170Er was measured by X-ray fluorescence analysis as well as with Rutherford backscattering spectrometry and it was found to be 150 μg/cm2. Successful preparation of sandwiched targets was very sensitive to substrate temperature, deposition rate, duration of in situ annealing, cooling rate etc. 相似文献
6.
Gordeev SN Zhukov AA de Groot PA Jansen AG Gagnon R Taillefer L 《Physical review letters》2000,85(21):4594-4597
We report on transport measurements of YBa 2Cu 3O (7-delta) single crystals with different oxygen contents in the geometry B, J ||ab (J perpendicularB). Our data show that the vortices become confined between the Cu-O planes below a well-defined temperature at which the effective size 2xi of the vortex core is approximately equal to the period of the Cu-O layers. This confinement strongly increases the vortex liquid freezing temperature. A new melting line is found separating a vortex liquid and a smectic phase, which shows an oscillatory field dependence reflecting differences between commensurate and incommensurate smectic states. 相似文献
7.
Wijkens P Jastrzebski JT van Der Schaaf PA Kolly R Hafner A van Koten G 《Organic letters》2000,2(11):1621-1624
A general method for the functionalization of Si-Cl terminated carbosilane dendritic molecules via organolithium or organomagnesium reagents is described. Quantitative exchange of the bromine atoms of 4-bromophenyl-functionalized dendrimers affords polylithiated species that are valuable starting materials for further functionalization, e.g., into pyridyl alcohols. The latter were successfully applied as catalyst precursors in a ruthenium-mediated ring-closure metathesis reaction. 相似文献
8.
[reaction: see text] The pyridine-mediated reaction of dimethyl acetylenedicarboxylate and cyclobutene-1,2-diones affords selective access to either hexasubstituted benzene derivatives or cyclopentenedione derivatives depending on the concentration of pyridine. 相似文献
9.
[reaction: see text] Pyridine catalyzes the reaction of 1,2-diaryl diones with dimethyl butynedioate to afford diaroyl maleates. This unprecedented rearrangement involves a unique benzoyl migration and proceeds with complete stereoselectivity. 相似文献
10.
[reaction: see text] Electron-rich arenes condense efficiently with various aldehydes under the influence of AuCl3, thus opening up a practical route to triarylmethanes, which have important applications. The mild conditions employed are especially noteworthy. 相似文献