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提出一种合成LaAlO3的新方法,该方法操作简单、成本低、无污染。将化学计量比的反应物La(OH)3/La2O3和Al(OH)3放入反应釜中,于220℃温度下水热活化处理,快速加热至900℃反应即可得到LaAlO3。XRD结果表明,所合成的LaAlO3为三方晶系。PL结果表明,所合成的LaAlO3∶Eu3+的主要发射为Eu3+的5D0→7F1磁偶极跃迁发射和5D0→7F2电偶极跃迁发射,红橙比随着Eu3+离子掺杂量的增加而变大。在VUV-UV激发光谱中,LaAlO3∶Eu3+位于VUV光谱区的基质吸收很弱,而位于~315 nm的O2--Eu3+的电荷迁移跃迁带(CT)则较强。 相似文献
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Fluorescence lifetime measurement in the time domain requires excitation from a well separated single bunch using synchrotron light sources. In the colliding mode of the Beijing Electron Positron Collider Ⅱ (BEPCⅡ), a hybrid filling pattern was realized such that a single bunch was placed in the middle of a large gap between two multi-bunch groups. Detection of fluorescence lifetime, based on the excitation of the light pulse from this designated single-bunch, was established at Beamline 4B8 of the Beijing Synchrotron Radiation Facility (BSRF). The timing signal of the BEPCII was utilized as a trigger to gate this fluorescence event. L-Tryptophan amino acid, a known lifetime standard, was selected to assess the lifetime measurement performance. The measured lifetime was consistent in both colliding and single-bunch mode with the time resolution down to 450 ps. Moreover, both the bunch purity and the fine structure of the hybrid filling pattern were characterized. 相似文献
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基于微流控混合器,采用连续流探测方法,在北京同步辐射装置真空紫外光谱实验站发展了毫秒动态圆二色谱探测方法。石英微流控混合器采用深度离子刻蚀技术加工,通道深度44.5 μm。混合器采用蛇形通道实现溶液的快速混合。通过荧光倒置显微镜,在模拟真实实验条件的高粘度溶液中,观察蛇形通道内溶液混合的荧光图像,进行混合效率测试。500 μL·min-1流量下,目前可实现4.5~270 μs的时间尺度探测。利用微流控混合器进行动态探测,同步辐射紫外光必须聚焦,但由于聚焦透镜波长色散引起的焦点位移,导致圆二色谱发生畸变。通过精确测试不同波长对应焦点的相对位置,然后在圆二色谱扫描中实现波长和焦点位置精确的反馈控制,获得准确的圆二色谱。利用所发展的方法,测试了去折叠状态下的细胞色素c恢复折叠的动态同步辐射圆二色谱,在4.5 μs处折叠恢复54%。这种方法将为生物大分子折叠动力学研究提供新的探测手段。 相似文献
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