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The manganese(Ⅲ) complex [Mn(acacen){N(CN)2}]n [H2acacen=bis(acetylacetone)ethylenediimine] has been synthesized and the structure has been determined. The complex forms a one-dimensional chain structure via the bidentate bridge ligand μ1,5-[N(CN)2]- linking [Mn(acacen)] moiety. The magnetic property of the compound (75~300 K) shows the existence of an antiferromagnetic exchange interaction among paramagnetic centers along the chain. CCDC: 244940. 相似文献
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The complex {[Mn(H2O)4(3, 3?-azpy)](3, 3?-azpy)3(PF6)2}n (3, 3?-azpy = 3, 3?- azobispyridine) has been synthesized and characterized. The crystal (C40H40F12MnN16O4P2, Mr = 1153.76) belongs to the triclinic system, space group P ī with the following crystallographic parameters: a = 10.761(2), b = 11.040(2), c = 23.365(4) ?, ( = 85.52(1), ( = 82.69(1), ( = 70.44(1)°, V = 2592.5(8) ?3, Dc = 1.478 g/cm3, ((MoK() = 4.16 cm-1, F(000) = 1174, Z = 2, final R = 0.0493 and wR = 0.1158 for the observed reflections (I > 2.00((I)). The X-ray analysis revealed that manganese(Ⅱ) cation coordination environment is a distorted octahedral geometry, and the Mn2+ cation is coordinated by four oxygen atoms of water in the equatorial plane, while the two nitrogen atoms of 3, 3?-azpy occupy the axial positions. The complex forms a one-dimensional chain structure via 3, 3?-azpy bridging ligand. 相似文献
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1INTRODUCTIONThedevelopmentofinorganicsupramoleculararchitecturesisarapidlydevelopedareaofresearchthathasimplicationsfortherationaldesignoffunctionalmaterials[1,2].Aconvenientpathtoobtainapolymericstructureistouseabidentateligand,suchaspyrazine,4,4-bipyridineor4,4?azobispyridinetolinkthemetalions,forminganinfinitestructure[3,4].Theuniquedirectionality,strength,andcomplementarityofnon-covalenthydrogenbondingplayanimportantroleintheconstructionofavarietyofmotifsformolecularself-assemblyandre… 相似文献
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The nickel ( Ⅱ ) complex [Ni(teta) { N(CN)2 } 2] (teta = 5,7,7,12, 1 4, 1 4-hexamehyl- 1,4,8,1 1-tetraazacyclotetradecane) was synthesized and its structure has been determined by singlecrystal X-ray diffraction. Crystal data: C20H36N10Ni, monoclinic, space group P21/c, a = 9.632(2), b = 11.833(2), c = 10.613(2) A, β= 93.46(3)°, V= 1207.4(4) A3, Mr = 475.30, Z= 2, Dc= 1.307 g/cm3,F(000) = 508,μ(MoKα) = 0.831 mm-1, R = 0.0446 and wR = 0.1274 for 2423 observed reflections with I > 2σ(I). The center nickel ion is coordinated by six nitrogen atoms, four from the macrocyclic ligand teta and the other two from two dicyanamides. The dicyanamide is coordinated to the metal atoms as uni-dentate manner via nitrile nitrogen atom. 相似文献
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1 INTRODUCTION Recently the chemistry of transition metal com- plexes containing macrocyclic ligand has become in- creasingly important[1~12]. However, the structurally characterized transition metal complexes containing macrocyclic ligand teta are stil… 相似文献
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