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<正>Poly(vinylidenefluoride-hexafluoropropylene)(PVDF-HFP) nanofiber membranes with improved hydrophilicity and protein fouling resistance via surface graft copolymerization of hydrophilic monomers were prepared.The surface modification involves atmospheric pressure glow discharge plasma(APGDP) pretreatment followed by graft copolymerization of poly(ethylene glycol) methyl ether methacrylate(PEGMA).The success of the graft modification with PEGMA on the PVDF-HFP fibrous membrane is ascertained by X-ray photoelectron spectroscopy(XPS) and attenuated total reflectance Fourier transform infrared measurements(ATR-FTIR).The hydrophilic property of the nanofiber membranes is assessed by water contact angle measurements.The results show that the PEGMA grafted PVDF-HFP nanofiber membrane has a water contact angle of 0°compared with the pristine value of 132°.The protein adsorption was effectively reduced after PEGMA grafting on the PVDF-HFP nanofiber membrane surface.The PEGMA polymer grafting density on the PVDF-HFP membrane surface is measured by the gravimetric method,and the filtration performance is characterized by the measurement of water flux.The results indicate that the water flux of the grafted PVDF-HFP fibrous membrane increases significantly with the increase of the PEGMA grafting density. 相似文献
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<正>Zein/chitosan composite fibrous membranes were fabricated from aqueous ethanol solutions by electrospinning. Poly(vinyl pyrrolidone)(PVP) was introduced to facilitate the electrospinning process of zein/chitosan composites.The asspun zein/chitosan/PVP composite fibrous membranes were characterized by scanning electron microscopy(SEM) and tensile tests.SEM images indicated that increasing zein and PVP concentrations led to an increase in average diameters of the composite fibers.In order to improve stability in wet stage and mechanical properties,the composite fibrous membranes were crosslinked by hexamethylene diisocyanate(HDI).The crosslinked composite fibrous membranes showed slight morphological change after immersion in water for 24 h.Mechanical tests revealed that tensile strength and elongation at break of the composite fibrous membranes were increased after crosslinking,whereas Young's modulus was decreased. 相似文献
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静电纺丝是通过对聚合物溶液或熔体施加外电场制造纳米纤维的有效方法.电纺过程中,在静电力作用下聚合物射流快速鞭动,形成的纳米纤维无规堆砌,得到无纺布状的无规纳米纤维膜.这种纳米纤维膜具有极大的比表面积,已用于超高效过滤,在刨伤修复、组织工程、水处理等领域有广泛的应用前景.为了进一步拓展纳米纤维在纤维工业、纺织品、微制造等领域的应用,电纺纳米纤维的取向和连续长纱的制备研究受到科学家的重视,文献报道了多种纳米纤维取向方法.本文分析了纳米纤维膜无规堆砌结构的形成机理,总结了纳米纤维取向研究和连续长纱制备研究进展,特别介绍了基于静电作用分析提出的共轭电纺方法,讨论了取向纳米纤维的应用以及纳米纤维未来的研究方向. 相似文献
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A simple method is adopted to grow ZnO nanofibers laterally among the patterned seeds designed in advance on silicon substrate. The preparation of seed lattices is carried out by lithographing the metal zinc film evaporated on the substrate. A layer of aluminum is covered on the zinc layer to prevent the ZnO nanorods vertically growing on the top surface. After oxidation, the patterned ZnO/Al2O3 spots are formed at the sites for the horizontal growth of ZnO nanofibers by the vapor phase transportation (VPT) method using the zinc powders as source material. 相似文献
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本文研究了一系列芘甲酰基标记的苯乙烯—二乙烯苯共聚物的荧光光谱,发现其光谱特征对共聚物中芘甲酰基的含量,溶胀作用以及溶胀溶剂的性质有明显的依赖性.这一结果可以用芘甲酰基在共聚凝胶中形成激基缔合物和激基复合物予以解释. 相似文献
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本文首次通过共聚方法和功能基化方法合成了芘标记苯乙烯/二乙烯苯共聚物,用稳态荧光光谱、裂解色谱、裂解色谱-质谱等方法对芘标记共聚物进行了详细地表征。结果表明,通过控制芘标记单体的投料或功能基化反应时间,可以将一定量的芘基标记到苯乙烯/二乙烯苯共聚物中,其荧光光谱显示了芘基的单体荧光发射和激基缔合物荧光发射;共聚物裂解色谱的甲基芘峰和苯乙烯三聚体峰反映了芘基和交联聚苯乙烯骨架的特征,据此可建立甲基芘 相似文献
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<正>The interpenetrating polymer network(IPN) silicone hydrogels with improved oxygen permeability and mechanical strength were prepared by UV-initiated polymerization of monomers including methacryloxypropyl tris(trimethylsiloxy)silane(TRIS),2-hydroxyethylmethacrylate(HEMA) and N-vinyl pyrrolidone(NVP) in the presence of free radical photoinitiator and cationic photoinitiator.The polymerization mechanism was investigated by the formation of gel network.The structure of IPN hydrogels was characterized by Fourier transform infrared spectroscopy(FTIR), differential scanning calorimetry(DSC) and transmission electron microscopy(TEM).The results showed that the IPN hydrogels exhibited a heterogeneous morphology.The mechanical properties,surface wettability and oxygen permeability were examined by using a tensile tester,a contact angle goniometer and an oxygen transmission tester,respectively.The equilibrium water content of the hydrogels was measured by the gravimetric method.The results revealed that the IPN hydrogels possessed hydrophilic surface and high water content.They exhibited improved oxygen permeability and mechanical strength because of the incorporation of TRIS. 相似文献