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本文报道了不同溶剂对DCNP晶体生长的影响,发现二甲基甲酰胺是一种好溶剂。利用降温法已生长出DCNP透明单晶。 相似文献
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MODELING AND SCALING OF CHIELECTRIC RELAXATION OF NONLINEAR OPTICAL POLYMERS IN FREQUENCY DOMAIN 下载免费PDF全文
chielectric relaxation theory was demonstrated, chielectric relaxation that selectively probes chromophore reorientation in the frequency domain was described by the Havriliak Negami(HN) function, chielectric spectra of several nonlinear optical (NLO) polymers were fitted well by the HN function. To describe the scaling of chromophore reorientation relaxation in frequency domain, two-shape parameters m and n describing the low- and high- frequency wings of the chielectric spectra need to be specified, besides the chielectric characteristic relaxation time τ and the chielectric strength Δχ(2). From the temperature dependences of m and n of NLO polymers, the relations between the chromophore relaxation and the a relaxation of the polymer host have been revealed. 相似文献
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设计、合成了以吡啶阳离子为吸电子基团的二维电荷转移非线性光学生色团分子-双四苯鹏(反式)-4,4'-二{p-[(N-乙基-N-羟乙基)氨基]苯亚乙烯基}-N,N'-(1,2-乙基)-2,2'-联吡啶盐和双四苯硼(反式)-N-己基-咔唑-3,6-二(p-亚乙烯基-N-羟乙基-吡啶盐),利用超瑞利散射技术(HRS)测定了这两种分子的第一超级化率β,在1064nm分别为786x10^-^3^0esu和1770x10^-^3^0esu。双能级模型计算得到的β0的值分别为215x10^-^3^0esu和119x10^-^3^0esu。从分子结构的角度定性地分析了该类分子具有大β值的原因。 相似文献
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