Time-resolved spectroscopy for 5s~('4)D_(7/2) state transitions undergoing electron–ion recombination in femtosecond laser-produced copper plasma

In the femtosecond laser-produced Cu-plasma, the transient transition dynamics that the excited state 5s~('4)D_(7/2) via electron–ion recombination transfers to 4p~('4)F_(9/2)~0(465.11 nm, Λ1 line) and 4p~('4)D_(7/2)~0(529.25 nm, Λ_2 line) states are investigated by using the time-resolved spectroscopy. The occupation number and relevant lifetime of the excited state 5s~('4)D_(7/2),the temporal evolutions of spectral intensities for Λ_1 line and Λ_2 line emissions are demonstrated to be in direct proportion to the employed laser intensity, which reveals the transient features of transition dynamics clearly differing from that resulted in the traditional collision excitation. Furthermore, some unique characteristics for Λ_1 and Λ_2 transitions stemming from electron–ion recombination are examined in detail.     

355nm激光曝光SU-8胶的XPS谱和FT-IR谱研究

SU-8光胶因具有良好的光刻性能,并可获得稳定的高深宽比而在微加工领域得到了广泛的应用。众多研究采用不同的光源对其进行了多种光刻研究,本文应用355nm激光对SU-8胶进行曝光,分别采用XPS谱和FT-IR谱分析了SU-8胶与激光相互作用过程中,355nm激光对SU-8胶的作用以及反应前后主要成分含量、分子结构的变化,初步探讨了SU-8胶中激光曝光能量与透入深度的关系。     

基于微通道构型的微流体流动控制研究

微通道不仅仅是作为流体流动的单元, 更是进行流体控制的工具,微通道自身特性和特征用在实现微流体的驱动、进样、混合、分离以及液滴的产生、控制等方面已经表现出了良好的效果.由于微通道中比表面积非常大, 表面效应极大影响流体流动,近年来多数研究集中在应用表面效应来实现微流体驱动与控制,而以利用微通道结构特征实现流体流动控制为目标的研究成果相对较少.为了提高对通道构型作用的认识,主要介绍了基于微通道构型的无可动部件的流体微阀和基于微通道构型微小液滴的产生及流动控制器两个方面的发展情况,表明微通道构型在微流体控制中同样可以发挥重要作用,甚至有望带来微流控技术的突破.      

脉冲激光-铜靶等离子体产生及其演化过程的瞬态光谱研究

应用时间分辨光谱技术, 研究了高能量纳秒脉冲激光作用下铜靶表面等离子体产生及演化的物理过程. 实验中相互作用区固-气-液三相对激光能量的吸收明显地反映于激光反射强度随时间的演化中, 使得靶表面物质形态的改变导致激光反射强度随时间呈双峰分布.同时, 随着激光峰值功率密度的增加, 靶面等离子体(气)-固-液相变发生的时间相应提前.因此, 这些瞬态性质是诊断激光-固体靶相互作用中靶面物质相变时间的有效方法.     

Few-layer graphene film fabricated by femtosecond pulse laser deposition without catalytic layers

The films of few-layer graphene are formed through laser exfoliation of a highly ordered pyrolytic graphite(HOPG), without a catalytic layer for the growth process. The femtosecond(fs) laser exfoliation process is investigated at different laser fluences and substrate temperature. For fs laser exfoliation of HOPG, the few-layer graphene is obtained at 473 K under an optimal laser fluence. The formation of few-layer graphene is explained by removal of intact graphite sheets occurred by an optimal laser fluence ablation. The new insights may facilitate the controllable synthesis of large area few-layer graphene.     

Polarization-dependent ultrafast carrier dynamics in GaAs with anisotropic response

The transient dynamics of anisotropic properties of GaAs was systematically studied by polarization-dependent ultrafast time-resolved transient absorption. Our findings revealed that the anisotropy of reflectivity was enhanced in both pump-induced and probe-induced processes, suggesting an extraordinary resonance absorption of photon-phonon coupling (PPC) with intrinsic anisotropic characteristic in carrier relaxation, regardless of the concrete crystallinity and orientation of GaAs sample. The results, delivering in-depth cognition about the polarization-dependent ultrafast carrier dynamics, also proved the paramount importance of interaction between polarized laser and semiconductor.     

飞秒激光制备黑硅的光谱特性

本文采用飞秒激光在空气中对单晶硅进行扫描处理,在硅表面制备出平行排列并具有微尺度沟槽的黑硅材料。在扫描电子显微镜下,观察到了黑硅的纳米尺度的二级结构。通过黑硅的反射光谱发现,在250~1000nm光谱区域的反射率明显降低,且沟槽越深,反射率越低。同时,对沟槽深度与反射率的关系以及二级纳米结构的形貌进行了讨论。通过黑硅的拉曼光谱发现,飞秒激光处理后的硅片没有发生成分和结构上的变化,黑硅的成分依然是单晶硅。     

Time-Resolved Study of Pseudogap and Superconducting Quasiparticle Dynamics in Ca0.82La0.18Fe1-xNixAs2

We use femtosecond time-resolved optical reflectivity to study the photoexcited quasiparticle(QP) dynamics in the iron-based 112 type superconducting(SC) samples Ca_0.82La_0.18Fe_1-xNi_xAs₂,with x=0 and 0.024.In the parent sample,a fast and a slow relaxation emerge at temperatures below the magnetic-structure(MS) transition T_ms ≈ 50 K and the SC transition T_c≈33 K,respectively.The latter obviously corresponds to an SC QP dy...     

活性炭对乙二醛溶液的脱色研究

乙二醛是一种重要的化工产品和医药中间体,在纺织印染、建材、皮革、医药、农药、国防、涂料、轻工、粘合剂、石油、冶金、环保等方面具有广泛的用途[1,2]。其工业生产方法主要有乙醛硝酸氧化法和乙醇气相氧化法[3~6]。两种方法制得的乙二醛溶液在纯化过程中,溶液颜色加深,不能     

阳离子树脂催化合成古龙酸甲酯的动力学研究

古龙酸甲酯化反应是生产维生素C的一个重要中间过程,目前工业上主要采用古龙酸和甲醇为原料,以浓硫酸作催化剂催化酯化.这一反应存在副反应较多,甲酯的色泽深,质量差,后续反应中需用碱进行中和等缺点,给后续处理带来困难.