共查询到20条相似文献,搜索用时 15 毫秒
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Tavorite‐structured oxyphosphates, fluorophosphates, oxysulfates, and fluorosulfates are evaluated for use as cathode materials in lithium ion batteries and activation energies for lithium diffusion through LiVO(PO4), LiV(PO4)F, and LiFe(SO4)F are calculated. 相似文献
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ChemInform Abstract: Stability of B12(CN)122‐: Implications for Lithium and Magnesium Ion Batteries.
DFT calculations are used to calculate the binding energies of the second electron of the closo‐borane B12H122‐ and B12(CN)122‐. 相似文献
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Yuanchun Ji Prof. Carsten Streb Prof. Yu‐Fei Song 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(51):18799-18804
An organo‐functionalized polyoxometalate (POM)–pyrene hybrid (Py‐Anderson) has been used for noncovalent functionalization of carbon nanotubes (CNTs) to give a Py‐Anderson‐CNT nanocomposite through π–π interactions. The as‐synthesized nanocomposite was used as the anode material for lithium‐ion batteries, and shows higher discharge capacities and better rate capacity and cycling stability than the individual components. When the current density was 0.5 mA cm?2, the nanocomposite exhibited an initial discharge capacity of 1898.5 mA h g?1 and a high discharge capacity of 665.3 mA h g?1 for up to 100 cycles. AC impedance spectroscopy provides insight into the electrochemical properties and the charge‐transfer mechanism of the Py‐Anderson‐CNTs electrode. 相似文献
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《化学:亚洲杂志》2017,12(1):116-121
Antimony/porous biomass carbon nanocomposites have been prepared by a chemical reduction method and applied as anodes for sodium‐ion batteries. The porous biomass carbon derived from a black fungus had a large Brunauer–Emmett–Teller (BET) surface area of 2233 m2 g−1 in which antimony nanoparticles were uniformly distributed in the porous carbon. The as‐prepared antimony/porous biomass carbon nanocomposites exhibited a high reversible sodium storage capacity of 567 mA h g−1 at a current density of 100 mA g−1, extended cycling stability, and good rate capability. 相似文献
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Daozhong Hu Lai Chen Jun Tian Yuefeng Su Ning Li Gang Chen Yulu Hu Yueshan Dou Shi Chen Feng Wu 《中国化学》2021,39(1):165-173
Lithium plating on graphite anode is triggered by harsh conditions of fast charge and low temperature, which significantly accelerates SOH (state of health) degradation and may cause safety issues of lithium ion batteries (LIBs). This paper has reviewed recent research progress of lithium plating on graphite anode. Firstly, we summarize the forming mechanisms of Li plating with corresponding influence factors, the detecting methods and hazard of Li plating. Then, approaches to suppress Li plating are discussed, including anode surface modification, electrolyte composition optimization and development of optimal charge strategies. Finally, we conclude and propose the remaining challenges and prospects in terms of mechanism research, detecting approaches, and suppressing methods of Li plating. This review highlights the development of Li plating research and plays a guiding rule of further study on Li plating in LIBs. 相似文献