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Rhodium‐Catalyzed Asymmetric Arylation of β,γ‐Unsaturated α‐Ketoamides for the Construction of Nonracemic γ,γ‐Diarylcarbonyl Compounds 下载免费PDF全文
Dr. Juanjuan Wang Dr. Min Wang Prof. Dr. Peng Cao Liyin Jiang Dr. Guihua Chen Prof. Dr. Jian Liao 《Angewandte Chemie (International ed. in English)》2014,53(26):6673-6677
A highly regio‐ and enantioselective rhodium‐catalyzed 1,4‐addition of arylboronic acids to β,γ‐unsaturated α‐ketoamides using a simple new chiral sulfinylphosphine ligand is described. This transformation provides an attractive approach to construct chiral nonracemic γ,γ‐diarylsubstituted carbonyl compounds, as exemplified in the concise syntheses of sertraline and tetrahydroquinoline‐2‐carboxylamide. 相似文献
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