5th EuChemS Inorganic Chemistry Conference (EICC-5)

Russian Chemical Bulletin -     

The 5th Conference on Carbene Chemistry

On the territory of the former USSR.     

LaNi5类合金的软化学合成

LaNi5类合金是公认的性能优良的常温储氢材料.和其它的稀土过渡金属金属间化合物不同,由于存在不同的扩散机理,用还原-扩散方法很难制备物相纯的LaNi5合金.反应时间、反应温度和所用镍粉的粒径大小都决定着最后LaNi5合金的纯度.......     

Chemistry of bicyclic [1,3,4]thiadiazole 5-5 systems containing ring-junction nitrogen

This review provides a survey of the advances in the methods of formation and chemical reactivity of bicyclic [1,3,4]thiadiazole 5-5 systems containing ring-junction nitrogen over the period from 1989 to the beginning of 2017.     

华东理工大学等编《分析化学》(第5版)评述及几个问题的探讨

探讨了华东理工大学等编《分析化学》(第5版)中波谱分析法、紫外吸收光谱法、气相色谱法、基本单元章节中内容取舍的问题;并对教材中的几个其他问题进行了探讨。     

Chemistry of the 5g Elements: Relativistic Calculations on Hexafluorides

A Periodic System was proposed for the elements 1–172 by Pyykkö on the basis of atomic and ionic calculations. In it, the elements 121–138 were nominally assigned to a 5g row. We now perform molecular, relativistic four‐component DFT calculations and find that the hexafluorides of the elements 125–129 indeed enjoy occupied 5g states.     

Quantum Chemistry Study of Microstructure of Molecular Sieve of APO-5 Type

Four-membered and six-membered rings were chosen as substructure units to simulate molecular sieve of APO-5 type. The stability of various orderings of AlO4 and PO4 tetrahedra in micros tracture of the APO-5 type was studied by using CNDO/2 method.By means of analysing energies of systems, frontier orbitals, charges and bond orders in detail, Loewenstein's empirical rule is explained theoretically.     

综合有机化学实验:5-甲基-3-异噁唑甲酰胺的合成

利用丙酮和草酸二乙酯为原料,通过Claisen酯缩合、肟化环合与氨水氨解,合成磺胺甲基异噁唑的关键中间体——5-甲基-3-异噁唑甲酰胺。通过红外光谱、核磁共振、熔点测定等方法验证其结构。本实验综合运用有机合成、产物分离和结构鉴定中的多种操作单元,并训练红外光谱、核磁共振等常用仪器分析技术,适合学生进行综合有机化学实验。