122~125Sn中子谱因子的实验研究

多个Sn同位素位于慢速中子俘获（s-）过程路径上,其中子谱因子可用于计算ASn（n,γ） A+1Sn直接辐射俘获的天体物理反应率,并可研究Sn同位素对s-过程核合成的贡献。本工作在中国原子能科学研究院HI-13串列加速器Q3D磁谱仪上,对实验室系下8°~66°范围内的122,124Sn（d,p）和（p,d）单中子转移反应角分布进行了测量。利用DWBA理论计算了转移反应角分布,并提取了122-125Sn的基态以及123,125Sn第一激发态的中子谱因子。其中,122Sn和124Sn的基态中子谱因子是首次从实验上获得。由于本工作成功鉴别开了123,125Sn的基态和第一激发态的效应,因此给出的谱因子比前人的结果更可信。Several Tin isotopes are on the path of slow neutron capture (s-) process, and the direct components of (n, γ) reactions can be derived from their neutron spectroscopic factors. In the present work, the angular distributions of 122,124Sn(p, d) and (d, p) reactions are obtained using the high-precision Q3D magnetic spectrograph in Beijing HI-13 tandem accelerator in China Institute of Atomic Energy. The distorted-wave Born approximation (DWBA) calculations are performed to extract the neutron spectroscopic factors of the ground state of 122-125Sn and the first excited state of 123,125Sn. The neutron spectroscopic factors of the ground state of 122Sn and 124Sn are firstly obtained in this work. As the events of the ground state and first excited state of 123,125Sn can be distinguished clearly by our experiment, the neutron spectroscopic factories of 123,125Sn are more reliable.     

金属核的共振研究Ⅰ金属络合物的111Cd、113Cd、117Sn、119Sn、199Hg NMR谱

以FT-NMR法直接测定了金属络合物MPy₂Cl₂、M(bi-py)Cl₂、M(o-phen)Cl₂(M为Cd、Sn、Hg)的¹¹¹Cd、¹¹³Cd、¹¹⁷Sn、¹¹⁹Sn、¹⁹⁹Hg NMR谱,考察了溶剂、浓度、温度对金属核化学位移的影响,讨论了谱图参数变化规律及一级同位素屏蔽效应。     

Dynamical fluctuations in fragmentation reactions in a Boltzmann–Langevin approach

Based on the isospin-dependent Boltzmann–Langevin model, the dynamical fluctuations in the fragmentation reaction of ¹¹²Sn+¹¹²Sn are investigated. The quadrupole moment and octupole moment with zero magnetic quantum number have large fluctuations in the early time of the collisions. The dynamical fluctuations in momentum space show a strong dependence on the incident energy. The effects of using different fluctuations on the fragment cross sections are also studied in the fragmentation reactions. The results by using Q₂₀ + Q₃₀ fluctuation have a better agreement with the experimental data. Calculations using Q₂₀ + Q₃₀ fluctuation produce more proton-rich and neutron-rich nuclei than those using Q₂₀ fluctuation only. Besides, the difference between the production cross sections of fragments calculated by using Q₂₀ and Q₂₀ + Q₃₀ fluctuations is larger in the vicinity of the projectile. These results present that the dynamical fluctuations may affect the whole dynamical process of fragmentation reactions including the production of fragments, due to the nonlinear nature of the Boltzmann–Langevin equation.     

Mössbauer-effect studies of multilayers and interfaces

The usefulness of Mössbauer spectroscopy for the investigation of magnetic multilayer systems is described. By applying ⁵⁷Fe Mössbauer spectroscopy, the behavior of ultrathin magnetic layers, such as FCC-like Fe films on Cu(0 0 1), is studied. Position-specified (depth-selective) information is available by preparing samples in which monatomic ⁵⁷Fe probe layers are placed at specific vertical positions, e.g. at interfaces or at the surface. As demonstrated for epitaxial chemically ordered Fe₅₀Pt₅₀ alloy films and polycrystalline nanostructured Tb/Fe multilayers, the Fe-spin structure can be determined directly, and a site-selective Fe-specific magnetic hysteresis loop can be traced in very-high-coercivity materials. For the studies of non-magnetic layers, on the other hand, hyperfine field observations by ¹⁹⁷Au and ¹¹⁹Sn probes are worthwhile. Spin polarizations in Au layers penetrating from neighboring ferromagnetic 3D layers are estimated ¹⁹⁷Au from Mössbauer spectra and are also studied by inserted ¹¹⁹Sn probes in Au/3D multilayers. In the Sn spectra for Cr/Sn multilayers, it was found that remarkably large spin polarization is penetrating into Sn layers from a contacting Cr layer, which suggests that Cr atoms in the surface layer have a ferromagnetic alignment.     

在40MeV/u时112Sn+112Sn和124Sn+124Sn中多重碎裂的同位旋效应

利用同位旋相关的量子分子动力学模型,研究了112Sn+112Sn和124Sn+124Sn两个反应系统在入射能量E=40MeV/u时的多重碎裂.计算结果能与实验值定性符合.观察到两个反应系统中,中等质量碎片多重性、中子多重性、荷电粒子多重性与轻荷电粒子多重性之间的关联存在着明显的差别.另外,通过与膨胀蒸发源模型及同位旋相关的渗透模型分析结果的比较,发现这种差别主要是由同位旋相关的反应动力学所造成的.     

Pion-Nucleus Scattering and the Interacting Boson Model

A procedure of combining the medium energy scattering theory in the Eikonal approximation with the interacting boson model is proposed to study the pion-nucleus scattering. The channel coupling effects in the excitation of nuclear collective state with ρ^- and ρ⁺ elastic and inelastic scattering are analyzed. The calculated cross sections for the excitation of 2₁⁺ state of ²¹⁸Sn agree with experimental data quite well.     

探究重离子碰撞中密度和动量依赖的单核子势的影响

从Skyrme有效核子-核子相互作用出发,得到了单核子平均场、介质中的核子-核子散射截面以及核子的初始化密度分布,自洽地用于 Boltzmann-Uehling-Uhlenbeck(BUU) 输运模型中。使用对应不同软硬程度对称能、相反中子-质子有效质量劈裂的六组Skyrme参数(SkI2, Gs, KDE0v1, NRAPR, BSk9和SV-mas08),利用BUU输运模型对$^{124}{\rm{Sn}}$+$^{124}{\rm{Sn}}$和$^{112}{\rm{Sn}}$+$^{112}{\rm{Sn}}$进行了碰撞模拟。结果表明,由中子-质子有效质量劈裂效应引起的自由双中质比差异在较高的核子动能下明显。此外,与NSCL实验数据的比较表明,在用到的六种相互作用之中,KDE0v1相互作用所对应的双中质比结果似乎与实验更为符合。     

化学不稳定性和同位素分布的同位旋效应

采用同位旋相关的量子分子动力学模型,研究了在轰击能量为40MeV/u和100MeV/u时,¹¹²Sn+¹¹²Sn和¹²⁴Sn+¹²⁴Sn反应产物的同位素分布.发现在40MeV/u时,同位素分布与入射体系的同位旋密切相关;而在100MeV/u时,对这两种不同同位旋体系给出几乎相同的同位素分布.这种同位素分布的能量依赖性为研究化学不稳定性及其与力学不稳定性的竞争提供了新途径 关键词： 化学不稳定性 同位旋效应 同位素分布 同位旋相关的量子分子动力学     

缺中子核素101In低位同核异能态的首次观测

在兰州重离子加速器冷却储存环（HIRFL-CSR）上,用初级束流112Sn35+轰击了靶厚约10 mm的Be靶,产生了101In的基态和低位同核异能态。这些实验产生的碎片每25 s经过放射性束流线RIBLL2的筛选后注入到实验环CSRe中,利用飞行时间探测器测量离子在CSRe中的回旋周期。在此次实验中,磁场晃动会导致离子在环内的循环周期发生改变,传统的离子鉴别方法难以完成大部分离子的鉴别。通过发展和运用单次注入离子鉴别这一新的离子鉴别方法,有效地消除了磁场晃动对于离子鉴别的影响,并清楚地将101In基态和低位同核异能态鉴别出来,从而首次在实验中观测到101In的低位同核异能态。实验得到的激发能与理论外推值在112 keV的误差范围内一致,其低位同核异能态的寿命大于200 μs。Isochronous mass spectrometry has been applied to 112Sn projectile fragments at the HIRFL-CSR facility in Lanzhou. To produce short-lived nuclei of interest, we used projectile fragmentation of 112Sn35+ primary beams in a~10 mm thick 9Be production target. The fragments were selected and analyzed by RIBLL2 and injected into the experimental storage ring(CSRe) every 25 s. To measure revolution times of stored ions,we used a Time-Of-Flight detector installed in CSRe. A new particle identification method was developed to distinguish ions on the measured revolution time spectrum for each injection. Based on this method, the shifts of the revolution time due to instable dipole magnet fields can be corrected and the ground and isomeric states of 101In have been well-resolved. The measured excitation energy is consistent with the theoretical value in the error range of 112 keV. The lifetime of the isomeric states of 101In is more than 200 μs.     

大型壳模型计算中的截断效应对132Sn附近丰中子空穴核能级结构的影响

以双幻核132Sn以及附近的空穴核131Sn,130Sn,131In,130In,130Cd为例,研究了大型壳模型计算中的截断效应对该核区能级结构以及电四极跃迁的影响,其中截断包括了有无中子跨壳激发,以及限制轨道粒子数两种情况。计算结果表明,只有在允许质子跨壳激发的情况下才能给出130In与实验相符的基态能级,而允许两个中子的跨壳激发则会改善132Sn的低激发能级结构。此外中子壳芯激发也会对该核区空穴核的低激发能级有一定的影响,相应低能态之间的电四极跃迁则更加敏感地反映出了空间截断效应的影响。With two different truncations, i.e., neutron core-excitation truncation and orbital particle-number truncation, the research is studied at the truncation effects in shell-model calculations by the hole nuclei of 130Sn, 131Sn, 130In, 130In and 130Cd. We found that the right ground state of 130In needs proton core-excitation in shell model space, and allowing two neutron core-excitations will promote the low-lying states in 132Sn. The neutron core-excitations will also slightly affect the low-lying levels of hole-nuclei close to 132Sn, and the values of BE2 between the corresponded low-lying states reflect more obviously to the neutron core-excitations.     

Excitation of ΔL = 1 resonances in the (p,n) reaction on Zr, Sn, Ce and Pb at Ep = 41 MeV

A broad peak was systematically observed at about 10 MeV above the Gamow-Teller resonance in the ⁹⁰Zr, ¹²⁰Sn, ¹⁴⁰Ce, ²⁰⁸Pb (p,n) reactions at E_p = 41 MeV. The angular distribution shapes of these peaks support the interpretation that they they correspond to ΔL = 1 state. The data are compared with TDA-DWBA calculations.     

Isospin fractionation in nuclear multifragmentation

Isotopic distributions for light particles and intermediate mass fragments have been measured for 112Sn+112Sn, 112Sn+124Sn, 124Sn+112Sn, and 124Sn+124Sn collisions at E/A = 50 MeV. Isotope, isotone, and isobar yield ratios are utilized to estimate the isotopic composition of the gas phase at freeze-out. Analyses within the equilibrium limit imply that the gas phase is enriched in neutrons relative to the liquid phase represented by bound nuclei. These observations suggest that neutron diffusion is commensurate with or more rapid than fragment production.     

三环已基羧酸锡的13C和119Sn NMR研究

测定了33个三环己基脂肪族和芳香族羧酸锡在非配位溶剂(CDCl₃)中的¹³C和¹¹⁹Sn NMR谱。结果表明:化学位移δ(¹¹⁹Sn)值主要由锡原子的配位数决定,结构上微小的变化。都能在δ(¹¹⁹Sn)值上明显地表现出来。讨论了不同类型化合物间NMR参数间的关系。     

全剥离离子94mRu44+的衰变研究

在兰州重离子加速器冷却储存环（HIRFL-CSR）上,用等时性质量谱仪首次研究了百微秒量级全剥离离子94mRu44+的衰变。94mRu44+由初级束流112Sn轰击Be靶产生,经过放射性束流线RIBLL2的筛选后注入到等时性设置的实验环CSRe中,并利用安装在实验环中的飞行时间探测器测量离子在CSRe中的循环周期。94mRu44+退激引起的质量改变会带来其循环周期的变化,由此直接观测到了94mRu44+退激到基态的过程。确定了本次实验中衰变事例探测的灵敏区间,并讨论了衰变发生时刻的测量精度。同时,测量了短寿命核素94mRu44+的质量,其半衰期约为100 μs,这是目前储存环质量谱仪测量的最短寿命核素的质量。The decay of the fully stripped ion 94mRu44+ in the order of one hundred microseconds has been studied for the first time by using the Isochronous Mass Spectrometry (IMS) at the HIRFL-CSR facility in Lanzhou. 94mRu44+ was produced via projectile fragmentation of a 112Sn primary beam bombarding on a 9Be production target. After the in-flight separation with RIBLL2, the ions were injected into the experimental ring (CSRe) and then stored there. The revolution times of the stored ions were measured by a Time-of-Flight (TOF) detector. Due to the mass change of a 94mRu44+ ion caused by its de-excitation to the ground state, hence the revolution time change, the decay process of 94mRu44+ could be directly observed in the CSRe. The sensitive window for detection of the decay events and the measurement precision of the decay time have been determined in this work. At the same time, we measured the mass of short-lived 94mRu44+ with the half-life about one hundred microseconds, which is the shortest among nuclides that have been studied by using storage-ring mass-spectrometry.     

Entrance Channel Dependence of the Correlation Function of IMFs in 36Ar+112,124Sn at 35MeV/u

The reduced velocity correlation functions of the Intermediate Mass Fragments (IMFs) were measured in the reactions of ³⁶Ar+^112,124Sn at 35MeV/u. The anti-correlation at small reduced velocities is more pronounced in ³⁶Ar+¹²⁴Sn system than that in ³⁶Ar+¹¹²Sn system. The difference of the correlation functions between the two reactions is mainly contributed by the particle pairs with high momenta. A three-body Coulomb repulsive trajectory code (MENEKA) is employed to calculate the emission time scale of IMFs for the both systems. The time scale is 150fm/c in the ³⁶Ar+¹¹²Sn system and 120fm/c in the ³⁶Ar+¹²⁴Sn system, respectively. A calculation based on an Isospin dependence Quantum Molecular Dynamics code (IQMD) reveals that the emission time spectrum of IMFs is shifted slightly leftwards in ³⁶Ar+¹²⁴Sn compared with that in the ³⁶Ar+¹¹²Sn system, indicating a shorter emission time scale. Correspondingly, the central density of the hot nuclei decreases faster in ³⁶Ar+¹²⁴Sn than in ³⁶Ar+¹¹²Sn.     

Effect of entrance-channel asymmetry on the isospin dependence of nucleon emission in heavy ion collisions

Using the isospin- and momentum-dependent hadronic transport model IBUU04, we have in-vestigated the influence of the entrance-channel isospin asymmetry on the sensitivity of the pre-equilibrium neutron/proton ratio to symmetry energy in central heavy-ion collisions induced by high-energy radioactive beams. Our analysis and discussion are based on the dynamical simulations of the three isotopic reaction systems 132Sn+124Sn, 124Sn+112Sn and 112Sn+112Sn which are of the same total proton number but different isospin asymmetry. We find that the kinetic-energy distributions of the pre-equilibrium neutron/proton ratio are quite sensitive to the density-dependence of symmetry energy at incident beam energy E/A = 400 MeV,and the sensitivity increases as the isospin asymmetry of the reaction system increases.     

Isospin diffusion and the nuclear symmetry energy in heavy ion reactions

Using symmetric 112Sn+112Sn, 124Sn+124Sn collisions as references, we probe isospin diffusion in peripheral asymmetric 112Sn+124Sn, 124Sn+112Sn systems at an incident energy of E/A=50 MeV. Isoscaling analyses imply that the quasiprojectile and quasitarget in these collisions do not achieve isospin equilibrium, permitting an assessment of isospin transport rates. We find that comparisons between isospin sensitive experimental and theoretical observables, using suitably chosen scaled ratios, permit investigation of the density dependence of the asymmetry term of the nuclear equation of state.     

2,6-双(三甲基锡)-4,8-双(2-乙基己氧基)苯并[1,2-b∶4,5-b']二噻吩的合成与多核NMR研究

以苯并[1,2-b∶4,5-b´]二噻吩-4,8-二酮为原料合成了一种聚合物太阳能电池材料的单体2,6-双(三甲基锡)-4,8-双(2-乙基己氧基)苯并[1,2-b∶4,5-b´]二噻吩. 通过多核1D和2D NMR技术（包括1D ¹H、¹³C、¹¹⁹Sn、¹¹⁷Sn NMR、DEPT、选择性1D TOCSY及2D¹H-¹H COSY、gHSQC、gHMBC）表征了目标分子结构,完成了 ¹H、¹³C、¹¹⁹Sn 与¹¹⁷Sn NMR化学位移归属,并探讨了该化合物的NMR谱线特征.     

An Isoratio Method and an Isoratio Scaling Phenomenon in Heavy-Ion Collisions

An isoratio method is proposed to study the chemical potential of neutrons (protons) from the yield ratio of isotopes (isotones) differing in neutron-excess (I = N-Z). The measured fragments in the 140 A MeV^40,48 Ca and ^58,64 Ni + ⁹ Be reactions, as well as those in the simulated ^58,64 Ni + ⁹Be reactions by using the antisymmetric molecular dynamics (AMD) model plus the secondary decay model gemini, have been adopted to perform the isoratio analysis. The results of the isoratio method verify that they are similar to that of the well known isoscaling method. The isoratio scaling phenomenon suggested by the isoratio method has also been found in the measured data and the fragments simulated by the AMD + gemini models.