Pattern formation in the ferrocyanide-iodate-sulfite reaction: the control of space scale separation

We revisit the conditions for the development of reaction-diffusion patterns in the ferrocyanide-iodate-sulfite bistable and oscillatory reaction. This hydrogen ion autoactivated reaction is the only example known to produce sustained stationary lamellar patterns and a wealth of other spatio-temporal phenomena including self-replication and localized oscillatory domain of spots, due to repulsive front interactions and to a parity-breaking front bifurcation (nonequilibrium Ising-Bloch bifurcation). We show experimentally that the space scale separation necessary for the observation of stationary patterns is mediated by the presence of low mobility weak acid functional groups. The presence of such groups was overlooked in the original observations made with hydrolyzable polyacrylamide gels. This missing information made the original observations difficult to reproduce and frustrated further experimental exploitation of the fantastic potentialities of this system. Using one-side-fed spatial reactors filled with agarose gel, we can reproduce all the previous pattern observations, in particular the stationary labyrinthine patterns, by introducing, above a critical concentration, well controlled amounts of polyacrylate chains in the gel network. We use two different geometries of spatial reactors (annular and disk shapes) to provide complementary information on the actual three-dimensional character of spatial patterns. We also reinvestigate the role of other feed parameters and show that the system exhibits both a domain of spatial bistability and of large-amplitude pH oscillations associated in a typical cross-shape diagram. The experimental method presented here can be adapted to produce patterns in the large number of oscillatory and bistable reactions, since the iodate-sulfite-ferrocynide reaction is a prototype of these systems.     

Effect of multiplicative noise on parametric instabilities

We report a study on the effect of external multiplicative noise on parametric instabilities using two different experimental systems: an electronic RLC circuit, parametrically pumped with a voltage-variable capacitor, and surface waves generated by vertically vibrating a layer of fluid (the Faraday instability). Both systems are forced by the superposition of a sinusoidal and a noisy component. We study the statistical properties of the response of both systems to noisy parametric forcing and compare them with theoretical predictions. When the detuning from parametric resonance is such that the bifurcation in the absence of noise is supercritical, both systems behave in the same way under the influence of noise. We find that the effect of noise is twofold: on one hand, it triggers the instability before its deterministic onset under the form of oscillatory bursts; on the other hand, it inhibits the nonlinearly saturated oscillatory response above the deterministic onset. When the detuning is such that the bifurcation is subcritical, we find that the two systems behave differently. In the case of the electronic oscillator, noise mostly triggers random transitions between the two states of the bistable region that exists in the absence of noise, whereas in the surface wave experiment new states are created by noise and the bistable region is strongly enlarged.     

Stochastic aspects of pattern formation during the catalytic oxidation of CO on Pd(111) surfaces

We present experimental results on rare transitions between two states due to intrinsic noise between two states in a bistable surface reaction, namely the catalytic oxidation of CO on Pd(111) surfaces. The mean time scales involved are typically of order 10⁴ s and the probability distribution shows two peaks over a large part of the bistable regime of this surface reaction. We use measurements of the resulting CO₂ rate as well as photoelectron emission microscopy (PEEM) to characterize these rare transitions. From our dynamic data we can extract probability distributions for the CO₂ rate. We use x-t plots from PEEM measurements to describe the transitions, which are-as we demonstrate-characterized by one wall moving through the field of view in PEEM measurements. The resulting probability distributions for the CO₂ rate are shown to depend strongly on the value, Y, of the CO fraction in the reactant flux inside the bistable regime. We find that the probability distribution is strongly asymmetric indicating that the two basins of attraction are rather different in depth and width. This is also concluded from the PEEM measurements, which show in one case a rather sharp and narrow domain wall going one way, while it is rather wide and diffuse for the motion in the opposite direction. To have two basins of attraction in the bistable regime, which are rather different in nature is reminiscent of other bistable systems such as, for example, optical bistability, although the time scales involved in the present system are entirely different.     

Opinion dynamics as a movement in a bistable potential

In this paper, we investigate the Sznajd model of opinion dynamics with anticonformity on a complete graph. We show that below some threshold value of anticonformal behavior spontaneous reorientations occur between two stable states. Dealing with a complete graph allows us also for an analytical treatment. We provide analytical calculations both for the infinite and finite systems. We show that opinion dynamics can be understood as a movement of a public opinion in a symmetric bistable effective potential. We focus also on the spontaneous transitions between stable states in the case of the finite system and show that a typical waiting time can be observed.     

Anomalous pulse interaction in dissipative media

We review a number of phenomena occurring in one-dimensional excitable media due to modified decay behind propagating pulses. Those phenomena can be grouped in two categories depending on whether the wake of a solitary pulse is oscillatory or not. Oscillatory decay leads to nonannihilative head-on collision of pulses and oscillatory dispersion relation of periodic pulse trains. Stronger wake oscillations can even result in a bistable dispersion relation. Those effects are illustrated with the help of the Oregonator and FitzHugh-Nagumo models for excitable media. For a monotonic wake, we show that it is possible to induce bound states of solitary pulses and anomalous dispersion of periodic pulse trains by introducing nonlocal spatial coupling to the excitable medium.     

Classical dielectric models of fullerenes and estimation of heat radiation

With the aim of describing the cooling of highly excited fullerene molecules by heat radiation, we consider simple classical, dielectric models for calculation of the electromagnetic response and show that the overall distribution of oscillator strength for electronic transitions can be represented fairly well by such a model. The connection to a layer model for graphite is discussed. For thermal emission of radiation from fullerenes, which depends on the oscillator strength at low frequencies only, the classical dielectric model leads to a prediction which should be applicable at high temperatures where the fine structure of the oscillator strength distribution is smeared out. We also estimate the emission from infrared-active vibrations, which dominate at low temperatures but play a minor role at the high temperatures where formation and decay of fullerene molecules take place. Received 22 November 1999 and Received in final form 19 April 2000     

Chemical turbulence and standing waves in a surface reaction model: The influence of global coupling and wave instabilities

Among heterogeneously catalyzed chemical reactions, the CO oxidation on the Pt(110) surface under vacuum conditions offers probably the greatest wealth of spontaneous formation of spatial patterns. Spirals, fronts, and solitary pulses were detected at low surface temperatures (T<500 K), in line with the standard phenomenology of bistable, excitable, and oscillatory reaction-diffusion systems. At high temperatures (T greater, similar 540 K), more surprising features like chemical turbulence and standing waves appeared in the experiments. Herein, we study a realistic reaction-diffusion model of this system, with respect to the latter phenomena. In particular, we deal both with the influence of global coupling through the gas phase on the oscillatory reaction and the possibility of wave instabilities under excitable conditions. Gas-phase coupling is shown to either synchronize the oscillations or to yield turbulence and standing structures. The latter findings are closely related to clustering in networks of coupled oscillators and indicate a dominance of the global gas-phase coupling over local coupling via surface diffusion. In the excitable regime wave instabilities in one and two dimensions have been discovered. In one dimension, pulses become unstable due to a vanishing of the refractory zone. In two dimensions, turbulence can also emerge due to spiral breakup, which results from a violation of the dispersion relation.     

Phase coherent precessional magnetization reversal in microscopic spin valve elements

We evidence multiple coherent precessional magnetization reversal in microscopic spin valves. Stable, reversible, and highly efficient magnetization switching is triggered by transverse field pulses as short as 140 ps with energies down to 15 pJ. At high fields a phase coherent reversal is found revealing periodic transitions from switching to nonswitching under variation of pulse parameters. At the low field limit the existence of a relaxation dominated regime is established allowing switching by pulse amplitudes below the quasistatic switching threshold.     

Control of stochastic resonance in bistable system by using periodic signal

<正>According to the characteristic structure of double wells in bistable systems,this paper analyses stochastic fluctuations in the single potential well and probability transitions between the two potential wells and proposes a method of controlling stochastic resonance by using a periodic signal.Results of theoretical analysis and numerical simulation show that the phenomenon of stochastic resonance happens when the time scales of the periodic signal and the noise-induced probability transitions between the two potential wells achieve stochastic synchronization.By adding a bistable system with a controllable periodic signal,fluctuations in the single potential well can be effectively controlled,thus affecting the probability transitions between the two potential wells.In this way,an effective control can be achieved which allows one to either enhance or realize stochastic resonance.     

Jamming transition and new percolation universality classes in particulate systems with attraction

We numerically study the jamming transition in particulate systems with attraction by investigating their mechanical response at zero temperature (T=0). We find three regimes of mechanical behavior separated by two critical transitions--connectivity and rigidity percolation. The transitions belong to different universality classes than their lattice counterparts, due to force balance constraints. We also find that these transitions are unchanged at low temperatures and resemble gelation transitions in experiments on colloidal and silica gels.     

Collective dynamics of multicellular systems

We have studied the collective behaviour of a one-dimensional ring of cells for conditions when the individual uncoupled cells show stable, bistable and oscillatory dynamics. We show that the global dynamics of this model multicellular system depends on the system size, coupling strength and the intrinsic dynamics of the cells. The intrinsic variability in dynamics of the constituent cells are suppressed to stable dynamics, or modified to intermittency under different conditions. This simple model study reveals that cell–cell communication, system size and intrinsic cellular dynamics can lead to evolution of collective dynamics in structured multicellular biological systems that is significantly different from its constituent single-cell behaviour.     

An organizing center for optical bistability and self-pulsing

The problem of self-pulsing in optically bistable systems is discussed within the framework of imperfect bifurcation theory. The joint appearance of a hysteresis cycle in the cw-transmission curve and of transitions to self-pulsing is described as an interaction between steady-state and Hopf bifurcations induced by varying the incident field intensity. The bifurcation equations for the most degenerate case are shown to be determined by a corank-two and codimension-four polynomial normal form. This form can be extracted from analytical and numerical studies on the Maxwell-Bloch equations, and acts as an organizing center for bistable switching and the self-pulsing mechanism. The structurally stable unfolded bifurcation diagrams are analyzed. Besides describing correctly and in a comprehensive way all bifurcations to self-pulsing that have so far been observed, a number of new generic transitions are predicted. These include self-pulsing from the low transmission branch and transitions leading to the formation of islands with self-pulsing behavior.     

Thermal conductance associated with six types of vibration modes in quantum wire modulated with quantum dot

We study the ballistic phonon transport and thermal conductance of six low-lying vibration modes in quantum wire modulated with quantum dot at low temperatures. A comparative analysis is made among the six vibrational modes. The results show that the transmission rates of the six vibrational modes relative to reduced frequency display periodic or quasi-periodic oscillatory behavior. Among the four acoustic modes, the thermal conductance contributed by the torsional mode is the smallest, and the thermal conductances of other acoustic modes have adjacent values. It is also found that the thermal conductance of the optical mode increases from zero monotonously. Moreover, the total thermal conductance in concavity-shaped quantum structure is lower than that in convexity-shaped quantum structure. These thermal conductance values can be adjusted by changing the structural parameters of the quantum dot.     

Noise activated granular dynamics

We study the behavior of two particles moving in a bistable potential, colliding inelastically with each other and driven by a stochastic heat bath. The system has the tendency to clusterize, placing the particles in the same well at low drivings, and to fill all of the available space at high temperatures. We show that the hopping over the potential barrier occurs following the Arrhenius rate, where the heat bath temperature is replaced by the granular temperature. Moreover, within the clusterized "phase" one encounters two different scenarios: For moderate inelasticity, the jumps from one well to the other involve one particle at a time, whereas for strong inelasticity the two particles hop simultaneously.     

Hahn echo and criticality in spin-chain systems

We present a theory to establish a relation between Hahn spin-echo of a spin-1/2 particle and quantum phase transitions in many-body systems. The Hahn echo is calculated and discussed at zero as well as at finite temperatures. On the example of XY model, we show that the critical points of the chain are marked by the extremal values in the Hahn echo, and can influence the Hahn echo in finite temperatures. An explanation for the relation between the echo and criticality is also presented.     

A model of Photoinduced Regular-Dimerized Stack Transitions

We present a model of photoinduced regular-dimerized stack transitions and discuss theoretically the behavior of the organic molecular mixed-stack charge-transfer crystal, Tetrathiafulvalene-Chloranil (TTF-CA). We investigate both the photoinduced structural phase transitions and the thermal phase transition between the regular-stack neutral phase at high temperatures and the dimerized-stack ionic phase at low temperatures. Our model is based on a simple phenomenological insight that the molecules have three stable displacements in the crystal. The cooperative effect is accounted for by introducing harmonic coupling between the molecules. It is the first attempt to include not only the photo-excitation but also the temperature effect on an equal footing.     

Transverse instability of line defects of period-2 spiral waves

Spiral waves that arise in period-2 oscillatory media extended in space generically bear "line defects" along which the local kinetics exhibits a period-1 oscillation. Locally, these defect structures can be viewed as a front separating two period-2 oscillatory domains oscillating 2pi out of phase. Here we show that their shape can become sinusoidal with a transverse instability as in bistable fronts. This instability eventually leads to a line-defect filled spatiotemporal chaotic state having erratic proliferations, annihilations, and regenerations of line defects. The same sequence of phenomena is observed in a model reaction-diffusion system as well as in an experimental system.     

Optical bistability via amplitude and phase control of a microwave field

We investigate the steady-state optical bistability behavior in a three-level Λ-type atomic system closed by a microwave field under the condition that the applied fields are in resonance with corresponding atomic transitions. It is shown that the bistable hysteresis cycles can be controlled by both the amplitude and the phase of the microwave field.