Oscillating indirect coupling of perpendicular magnetized Co(111)-monolayers through Cu(111)

Oscillating indirect coupling has been observed between perpendicularly magnetized Co(111)-monolayers on Cu(111). through a Cu(111)-interlayer. Contrarily, a weak indication of oscillation only was observed between in-plane magnetized Co(111)-films containing 5 monolayers each. Possible mechanisms for the strongly differing coupling behaviour observed in the Cu/Co(111) system are discussed.     

Superparamagnetism in small Fe clusters on Cu(111)

Fe clusters of 105±2 atoms/cluster were mass selectively deposited onto Cu(111) at cryogenic temperatures. XMCD was used to measure temperature and direction dependent magnetization curves. The clusters are superparamagnetic at the lowest temperature measured (10 K). Their magnetization curves are consistent with magnetic moments of ≈2.5μ_B per atom which are thus enhanced over the bulk values. Within experimental accuracy, the clusters do not present magnetocrystalline anisotropy in the temperature range of 10 K to 60 K.     

Frozen low-spin interface in ultrathin Fe films on Cu(111)

In ultrathin film systems, it is a major challenge to understand how a thickness-driven phase transition proceeds along the cross-sectional direction of the films. We use ultrathin Fe films on Cu(111) as a prototype system to demonstrate how to obtain such information using an in situ scanning tunneling microscope and the surface magneto-optical Kerr effect. The magnetization depth profile of a thickness-driven low-spin to high-spin magnetic phase transition is deduced from the experimental data, which leads us to conclude that a low-spin Fe layer at the Fe/Cu interface stays live upon the phase transition. The magnetically live low-spin phase is believed to be induced by a frozen fcc Fe layer that survives a thickness-driven fcc-->bcc structural transition.     

Magnetic properties of (111) Cu/Fe multilayers

The magnetic properties of (111) Cu/Fe multilayers grown on Cu underlayers of several thickness (2000-500-50 Å) on cleaved mica have been investigated by Mössbauer spectroscopy and SQUID magnetometry. The analysis of experimental results suggests that 2.5 monolayers of ψ-Fe interfaced with Cu evolves partially from paramagnetic to ferromagnetic states as the Cu underlayer thickness is reduced to 50 Å and partially from weak to strong antiferromagnetism.     

"Live" surface ferromagnetism in Fe nanodots/Cu multilayers on Cu(111)

We investigate the crossover behavior from two-dimensional (2D) to three-dimensional in multilayers of magnetic nanodots grown by stacking 2D Fe nanodot assemblies on Cu(111) single crystal substrate with a Cu spacing layer. Using an in situ magneto-optical Kerr effect, we have observed a striking ferromagnetic to spin-glass-like phase transition with an increasing number of Fe dot layers. The topmost layer of the Fe dots survives the phase transition and remains ferromagnetic. This unusual surface ferromagnetism is likely caused by a surface-state-mediated coupling which is stronger than the coupling in bulk layers. This is confirmed by the fact that the critical temperature of the surface ferromagnetism is considerably higher than that of the bulk spin-glass phase in the system.     

Narrow photoemission peak at the Fermi level in Fe/Cu(111)

We have studied electronic states of Fe adatoms deposited on Cu(111) by photoemission spectroscopy and have found a narrow peak at the Fermi level in the Fe 3d spectral function. The Fe 3d spectral function would be consistent with the Anderson impurity model, which has been widely used for the interpretation of bulk Ce and Yb compounds. This result indicates a strong reduction of hybridization between the Fe 3d state and the conduction-band states and an enhancement of effective Coulomb interaction for the Fe 3d electrons in an Fe adatom on Cu(111).     

Interfacial effects in electron transmission through Ag films on Cu(111)

The transmission coefficient for very low energy electrons ($\text{? 10}\text{eV}$) normally incident on thin epitaxial films of Ag on Cu(111) is modulated by reflection of the electronic wavefunction at the interfaces. The observation of such quantum size oscillations in this epitaxial system demonstrates that this effect is truly interfacial in origin.     

局域功函数图像及其在Cu(111)-Au/Pd表面的应用

用扫描隧道显微镜（STM）对Cu(111)-Au和Cu(111)-Pd表面的局域功函数进行了研究.通过 测量隧道电流对针尖样品间距的响应，得到了与STM形貌图一一对应的表面局域功函数图像. 实验发现，Au/Pd覆盖层和Cu衬底间的功函数有明显的不同.Pd薄膜的功函数甚至超过了其体 本征值，且功函数在台阶处变小.用偶极子的形成解释了台阶处功函数的降低.这一工作表明 ，用测量局域功函数的方法容易区分表面上不同的元素，并具有纳米尺度的空间分辨率. 关键词： 扫描隧道显微镜 局域功函数 台阶     

Bromine adsorption on Cu(111)

The dissociative chemisorption of molecular bromine on Cu(111) at 300 K has been studied using ultraviolet photoelectron spectroscopy (UPS), Auger electron spectroscopy (AES), low energy electron diffraction (LEED) and work function change measurements. A (√3 × √3)R30° structure is formed initially at a bromine coverage of 0.33 ML. This then converts to a (9√3 × 9√3)R30° compression structure with a coverage of 0.41 ML. The coincidence distance of the compression structure is determined entirely by the van der Waals diameter of adsorbed bromine. The applicability of using the van der Waals diameters of the three halogens, Cl, Br and I, to predict the saturation compression structures on Cu(111), is discussed.