高温度稳定性声表面波信道化滤波器组研制

本文报道了作者研制的频率范围分别为200—350MHZ和350一500MHZ的两种15信道声表面波滤波器组的结果。为了克服现有技术温度稳定性较差的缺点，基片材料采用Yll2°LiTaO3，温度稳定性比现有技术提高3．5—5倍。每个滤波器中的两个叉指换能器一个采用特殊抽样的单指换能器，另一个采用三次谐波工作的分裂指换能器，从而避免了采用基频工作的分裂指换能器所需的0．8μm。工艺。输入匹配网络采用改进的串并联匹配网络，降低了输人匹配网络的插人损耗，补偿了因采用Yll2°LITaO3，单个滤波器插损较大的缺陷，使滤波器组总的插入损耗与现有采用YZ或Y128°LiNbO3的滤波器组相当。     

稠密热等离子体的电子传导不透明度研究

 采用相对论自洽场平均离子势模型，电子简并效应采用Fermi–Dirac分布描述，参数结构因子用来考虑离子结构的影响，电子对离子的散射截面采用分波分析，利用推广的Ziman公式对稠密热等离子体的电子传导不透明度作了大量计算，并将结果与实验值和其它理论值作了比较。     

单链表在离子发动机光学系统粒子模拟中的应用

 目前离子发动机光学系统数值模拟大多采用PIC方法，由于该方法需要跟踪单个粒子的运动，因此需要存储每个粒子的位置信息与运动信息。传统的粒子模拟程序中，保存粒子信息大多采用数组的方式，但是采用这种方式存在弊端，例如对粒子总数变化的自适应不好。基于此开发了一种使用链式存储结构的粒子模拟程序，该程序使用带头节点的单向链表存储粒子信息。使用基于链式存储结构的PIC方法对离子发动机光学系统进行了粒子模拟，验证了链式粒子信息存储方法在粒子模拟中的可用性。模拟表明：（1）在粒子模拟中采用链式存储结构存储粒子信息，无需预先指定最大粒子总数，程序可自适应粒子总数的变化，因此无需进行试算，节省了计算时间；（2）在粒子模拟中采用链式存储结构，由于不存在内存资源的浪费，因而可显著提高程序的存储效率与计算效率。     

油管位置光电检测技术的研究

本文提出了一种测量汽车油管位置的方法。该方法采用平行光投影的光学系统，以高分辨率面阵CCD成像，通过数字信号处理(DSP)系统进行图像采集与处理，处理速度快，可以实现实时处理。在图像处理中，采用合适的边缘检测方法，提高了测量精度。数据处理中采用了最小二乘法拟合曲线，可以精确的拟合出油管像的曲线。与理论曲线相比较，就可以有效地测量油管的位置。     

飞行器大攻角非定常气动特性神经网络建模

大攻角气动特性预测与气动建模是新型飞行器提升飞行性能的重要内容.以轴对称导弹简化模型为研究对象，首先采用计算流体力学方法，对70°大攻角状态的非定常气动特性进行数值模拟，计算方法基于RANS的N-S方程，湍流模型采用SA模型，对流场采用有限体积法离散，无黏项采用Roe通量差分分裂格式，黏性项采用中心差分，时间推进采用LU-SGS格式的双时间步法.飞行器运动模式采用强迫振荡的方式，对5种不同振荡频率进行了非定常数值计算，并记录每一内迭代周期最终的气动力和力矩数值.其次，以CFD预测结果作为气动建模的样本，采用动导数模型、多项式模型等传统方法，进行气动建模，并分析其有效性和精度.最后采用神经网络方法对大攻角非定常气动力进行建模，并和动导数模型、多项式模型进行精度对比.结果表明，基于神经网络的人工智能气动建模方法具有较高的精度和适应性.该方法为飞行器大攻角非定常非线性气动建模，大攻角飞行稳定性分析与控制提供理论参考.      

冲击载荷下非晶态碳材料的动态响应模型研究

 在一维应变冲击加载条件下，采用两个石英压力传感器进行了双值应力历史测量，对非晶态碳材料的动态响应特性进行了分析研究。研究结果表明，非晶态碳材料的冲击响应是简单稳定的，在试验冲击应力范围内为非线性弹性响应，Hugoniot曲线呈上凸的，表明材料内部传播的不是一个冲击波而是一簇压缩波，因此可采用特征线方法来解该冲击波问题，并用Riemann积分法对冲击应力过程进行修正，得到材料更精确的Hugoniot方程。还采用COPS程序对该材料的冲击响应过程进行了数值模拟，数值模拟曲线与试验曲线是很吻合的。表明采用Riemann积分法处理是合理的，此方法可以在VISAR测量中得到应用。     

红外热像仪测试系统的研制与精度验证

目前红外测试能力的建设主要依靠进1：2，设备价格昂贵、供货周期长、维修困难。自主研发的红外测试系统，采用T型离轴折返式平行光管减小杂散红外辐射的影响，采用多帧平均算法减小随机噪声的影响，采用黑体、靶标轮和平行光管的一体化结构设计减小环境温度对平行光管焦距变化的影响，提高了测试精度。红外测试系统软件采用通用化架构和模块化编程技术，扩展性好。该系统与某美国进口的红外测试系统对比，红外热像仪NETD测试结果的偏差小于20％。测试过程和测试配置可自动化，大大提高了批量测试效率。测试系统成本低，性能与国外同类产品相当，性价比高，具有广阔的市场前景。     

C波段新型渡越管模拟研究

 在三腔渡越管的基础上设计了一种工作在C 波段的新型低阻轴向六腔渡越管，其阻抗为15 Ω左右，采用同轴输出。该器件采用大面积发射阴极，无须外加磁场，结构简单紧凑。采用2.5维PIC软件对该器件进行了2维数值模拟，在输入电压为483 kV、电流为32.5 kA的条件下，输出微波平均功率达到3.0 GW，主频为3.75 GHz，微波模式为TEM模。微波功率效率大于19%，比普通低阻抗器件有明显提高。     

X射线法测量的ICF靶丸参数的图像分析

 在ICF靶丸参数测量中，采用接触X射线显微辐射照相法获得靶核的X射线吸收底片图像，将该底片放置于显微镜下并用CCD获得了数字化图像。基于该数字化图像信息，编写了一套完整的计算机算法来计算靶参数。采用辐向平均法标定出靶中心，采用图像强度函数对半径的二阶微分来确定出靶层分界位置，计算精度约为0.2pixels。     

三维流线上风方法

1引言在流场的数值模拟中，为了消除高雷诺数流动中数值的不稳定和非物理振荡，普遍采用能反映流动物理本质的上风方法。在有限元法中，上风法主要有三种表达形式：（1）采用有上风特性的权函数，如SUPG法山；你对流项和扩散项分别离散，对流项直接采用上游点作为积分点，如MonotoneStreamelineUpwind法［‘］及SkewedPositly，CoeficientUpwind法［’］；由用特征法处理非定常的对流扩散方程，使其具有上风特性，采用传统的Galerkin法离散方程，如TaylorGalerkin法＊。ttice及SchniPke门提出的一种流线上风方法能方便地应用于已有的…     

火焰原子吸收法间接测定植物中的硫

根据植物中的硫消化后，消化液中的ＳＯ＾２－４与ＢａＣｒＯ４悬浊液反应释放出ＣｆＯ＾２－４，用火焰原子吸收法间接测定ＳＯ＾２－４。本文研究了影响试样消化液中ＳＯ＾２－４定量测定的各种条件，通过加入一定的量的钙，解决大量共存ＰＯ＾３－４的干扰。与电感耦合等离子体发射光谱法进行了结果对照，基本一致。     

RF-related heating assessment of extracranial neurosurgical implants at 7 T

Purpose

The purpose was to evaluate radiofrequency (RF)-related heating of commonly used extracranial neurosurgical implants in 7-T magnetic resonance imaging (MRI).

Materials and methods

Experiments were performed using a 7-T MR system equipped with a transmit/receive RF head coil. Four commonly used titanium neurosurgical implants were studied using a test procedure adapted from the American Society for Testing and Materials Standard F2182-11a. Implants (n = 4) were tested with an MRI turbo spin echo pulse sequence designed to achieve maximum RF exposure [specific absorption rate (SAR) level = 9.9 W/kg], which was further validated by performing calorimetry. Maximum temperature increases near each implant's surface were measured using fiberoptic temperature probes in a gelled-saline-filled phantom that mimicked the conductive properties of soft tissue. Measurement results were compared to literature data for patient safety.

Results

The highest achievable phantom averaged SAR was determined by calorimetry to be 2.0 ± 0.1 W/kg due to the highly conservative SAR estimation model used by this 7-T MR system. The maximum temperature increase at this SAR level was below 1.0 °C for all extracranial neurosurgical implants that underwent testing.

Conclusion

The findings indicated that RF-related heating under the conditions used in this investigation is not a significant safety concern for patients with the particular extracranial neurosurgical implants evaluated in this study.     

原子吸收分光光度法测定石油裂解催化剂中的钠,铁和铜

本文研究了石油裂解催化剂中钠、铁和铜的测定。试样用氢氟酸和高氯酸(或硫酸)溶解后,控制溶液酸度在pH1.5-2.0范围内,分别在5589.0纳米,248.3纳米,324.8纳米波长处对钠、铁和铜进行原子吸收分光光度法测定。其相对标准偏差分别小于5%,4%和2%;回收率分别在96-101%,94-103%和97-104%之间,适合于石油裂解催化剂的分析。     

冷蒸气原子吸收光谱法测定铜精矿中的汞

本文研究了一种用冷蒸气原子吸收光谱测定铜精矿中汞的方法。铜精矿用逆王水或硫酸-高锰酸钾(固)消化后用测汞仪测定其中的汞含量。测定结果的相对标准偏差小于5%;回收率在92-107%之间。     

微波-模板法合成锂离子电池正极材料LiMn2O4机理的光谱学研究

采用微波-PAM模板法合成了具有尖晶石结构的锰酸锂材料,利用动态红外光谱（FTIR）对该方法的反应机理进行了研究。在前驱体的制备和在LiMn2O4晶核形成过程中,由于聚丙烯酰胺与反应母体之间的弱键合作用,使其在晶粒生长过程中对LiMn2O4的团聚规律与缺陷结构起到重要调控作用。     

4种香豆素类化合物的结构和荧光光谱

采用量子化学中密度泛函理论(DFT)的B3LYP方法在6-311G基组下对4种香豆紊类化合物进行了构型优化,经振动分析,未出现虚频率。在此基础上用单激发态组态相互作用(CIS)方法在相同水平下分别计算了4种化合物气相的荧光光谱,所得计算值与实验值基本吻合。     

Sonodynamically induced anti-tumor effect with protoporphyrin IX on hepatoma-22 solid tumor

Objective

The purpose of this study was to evaluate sonodynamically induced anti-tumor effect of protoporphyrin IX (PPIX) in mice bearing hepatoma-22 (H-22) solid tumors, and the possible in vivo cell damage mechanism was also investigated.

Methods

The pharmacokinetics of PPIX was analyzed in plasma, skin, muscle and tumor of H-22 bearing mice. Tumors were irradiated with ultrasound (1.43 MHz, I_SATA 3 W/cm², 3 min) for three times at 8, 12 and 24 h after 5.0 mg/kg PPIX administration, respectively. The anti-tumor effects of sonodynamic therapy (SDT) were estimated by the tumor inhibition ratio (volume and weight). The bio-effects of SDT were evaluated by hematoxylin and eosin (H&E) staining, transmission electron microscope (TEM) observation, lipid peroxidation (LPO) measurement and anti-oxidative enzymes (glutathione peroxidase (GSH-PX), catalase (CAT) and superoxide dismutase (SOD)) assay.

Results

A significant anti-tumor effect was obtained by PPIX-mediated sonodynamic therapy (PPIX-SDT). At the fifteenth day after PPIX-SDT, the tumor growth and tumor weight inhibition ratios were 53.84% and 45.86%, respectively. In addition, the structure of tumor tissues and the anti-oxidative enzymes were obviously destroyed after SDT treatment.

Conclusions

A biochemical mechanism was involved in PPIX-SDT in vivo, and the free radicals produced by the synergistic treatment destroying the anti-oxidative system of tumor cells in vivo may play an important role in this action. Also, the thermal effect could not be excluded in inducing damage of cellular structures, like membrane disruption and chromatin condensation under current evaluation in this paper.     

BaMoO4 powders processed in domestic microwave-hydrothermal: Synthesis, characterization and photoluminescence at room temperature

In this paper, BaMoO₄ powders were prepared by the coprecipitation method and processed in a domestic microwave-hydrothermal. The obtained powders were characterized by X-ray diffraction (XRD), Fourier transform Raman (FT-Raman) spectroscopy, ultraviolet-visible (UV-vis) absorption spectroscopy and photoluminescence (PL) measurements. The morphology of these powders were investigated by scanning electron microscopy (SEM). SEM micrographs showed that the BaMoO₄ powders present a polydisperse particle size distribution. XRD and FT-Raman analyses revealed that the BaMoO₄ powders are free of secondary phases and crystallize in a tetragonal structure. UV-vis was employed to determine the optical band gap of this material. PL measurements at room temperature exhibited a maximum emission around 542 nm (green emission) when excited with 488 nm wavelength. This PL behavior was attributed to the existence of intrinsic distortions into the [MoO₄] tetrahedron groups in the lattice.     

General approach for fabricating nanoparticle arrays via patterned block copolymer nanoreactors

A general approach to fabricate nanoparticle arrays of different kinds of materials is demonstrated in this paper. It was found that the center-to-center distance of the nanoparticles or the nanoclusters can be controlled using patterned block copolymer nanoreactors by adding polystyrene (PS) homopolymer to poly(styrene-b-4-vinylpyridine) (PS-b-P4VP) diblock copolymer thin film. The number of the nanoparticles formed in the P4VP nanodomains can also be adjusted by addition of polystyrene (PS) homopolymer to poly(styrene-b-4-vinylpyridine) (PS-b-P4VP) diblock copolymer. In fabrication of Au nanoparticle arrays, HAuCl₄ precursor was directly loaded into P4VP nanodomains of the diblock copolymer thin film by using a methanol solvent, which is a good solvent for P4VP but non-solvent for PS. The Au nanoparticle arrays were then obtained by reducing HAuCl₄ with sodium citrate dihydrate, and then in situ transferred to silicon substrate by a two-step calcination method. ZnO and Fe _x O _y nanoparticle arrays were also synthesized by this approach with thermal decomposition and double decomposition reactions, respectively. Additionally, the advantage of using two-step calcination method over the air plasma method was discussed.     

Characteristics of the temperature-tunable Nd:YAG/YVO4 Raman laser

We demonstrate a tunable crystalline Raman laser by varying the temperature of Raman crystal. Nd:YAG and YVO(4) crystals were selected as the laser and Raman gain media, respectively. The center wavelength of this Nd:YAG/YVO(4) Raman laser was tuned over a 0.49 nm range from 1175.76 to 1175.27 nm when the temperature of the Raman crystal was adjusted from 5 °C to 150 °C. The characteristics of this Raman laser including tunability, output power, and beam quality factors (M(2)) dependent on temperature were also studied in this paper.