Ce:BaTiO3晶体电光和二倍频系数的拉曼散射测量

从极性晶体晶格振动的理论出发,推导出正交系以上晶系的晶体的拉曼散射效率与晶体电光系数和二倍频系数的关系,测量了Ｃｅ：ＢａＴＩＯ３和ＢａＴｉＯ３晶体各纵、横模的偏振拉曼谱。在此基础上,计算出这两种晶体的电光系数ｒ３３、ｒ５１和二倍频系数ｄ３３、ｄ１５。结果表明：掺微量Ｃｅ元素对ＢａＴｉＯ３晶体电光系数和二倍频系数影响不大。     

三硼酸铯和硼酸铯锂晶体的晶格振动光谱研究

本文对新型非线性光学晶体三硼酸铯（ＣｓＢ３Ｏ５∶ＣＢＯ）和硼酸铯锂（ＣｓＬｉＢ６Ｏ１０∶ＣＬＢＯ）进行了晶格振动光谱研究。首先对两种晶体的基本晶格振动模进行了对称性分类,记录了两种晶体低温下的拉曼光谱和室温下的红外反射光谱,对晶体的晶格振动模进行了认定,将振动模归属于平面六元环（Ｂ３Ｏ６）和四面体（ＢＯ４）。然后比较了ＣＢＯ,ＣＬＢＯ和ＬＢＯ（ＬｉＢ３Ｏ５）三种晶体的晶格振动光谱,讨论了阳离子对振动光谱的影响。另外,还讨论了硼酸盐晶体晶格振动模ＬＯ ＴＯ分裂的大小与晶体非线性光学系数之间的关系。     

NdvGdCOB晶体1331.0nm基频光运转和自倍频红光的观察

ＮｄｖＣａ４ＧｄＯ（ＢＯ３）３（简称ＮｄｖＧｄＣＯＢ）是一种新型自倍频晶体［１］。利用该晶体实现１０６０．０ｎｍ的自倍频绿光输出,因内外均已有报道［２］。我们利用Ｄａｔａｃｈｒｏｍ５０００型染料激光器泵浦该晶体成功地实现了１３３１．０ｎｍ基频光和６６５．５ｎｍ自倍频红光的输出。ＮｄｖＧｄＣＯＢ属单斜双轴晶体,具有明显的偏振吸收特性。生长该晶体所用原料为Ｃａ４Ｎｄ０．０８Ｇｄ０．９２Ｏ（ＢＯ３）３。晶体样品尺寸为３ｍｍ×３ｍｍ×８ｍｍ,通光方向为ｘ（ｘ轴与晶体的ｃ轴的夹角为１２°,ｚ轴与ａ轴的夹…     

Yb:YCOB晶体制备及其光谱与激光二极管抽运激光特性

研究了Ｙｂ：ＹＣＡ４Ｏ（ＢＯ３）（简称Ｙｂ：ＹＣＯＢ）的多晶制备和单晶生长,成功地合成了光学质量优良、掺Ｙｂ原子数分数为２０％的Ｙｂ：ＹＣＯＢ单晶。测量了该晶体的吸收光谱、荧光光谱和荧光寿命。并进行了激光二极管（ＬＤ）为抽运源的激光实验。实现了Ｙｂ：ＹＣＯＢ晶体１０ｍＷ的红外激光输出。观测并记录到自倍频二次谐波。     

KDP晶体三倍频实验和分析

报道了ＫＤＰ晶体中的三倍频产生的实验研究，计算了比较了直接三倍频过程和级联过程对ＫＤＰ晶体三阶有效非线性系数的贡献，并探讨了ＫＤＰ作为非线性晶体材料三阶非线性系数测量基准的可行性。     

新型光学晶体KABO的非线性频率变换特性

简述了新型非线性晶体KABO的光学特性.根据相位匹配角公式、非线性有效系数公式、走离角公式和允许角公式,详细计算了KABO晶体倍频时的相位匹配角、非线性有效系数、倍频时谐波走离角、允许角随波长变化的理论曲线.特别是对LD泵浦掺钕的全固态激光器532 nm输出时,得到了KABO晶体采用I类相位匹配进行四倍频的相位匹配角、非线性有效系数、倍频时谐波走离角、允许角分别为:58.1°、0.254×10^-12m/V、2.8°、1.8233 mrad·mm;并将该晶体与目前可应用于紫外倍频的晶体比较,在考虑走离效应的情况下,研究了四倍频转换效率随KABO晶体长度、基频光光斑半径的变化规律.     

低对称性非线性光学晶体硼酸铋(BIBO)的1064nm三倍频性质

采用高温溶液法成功生长出高光学质量的硼酸铋 (BIBO)晶体 ,尺寸达到 2 4mm× 19mm× 35mm ,质量为4 8g。对BIBO晶体进行了定向 ,并测量了该晶体的主轴折射率。讨论了BIBO晶体的 10 6 4nm三倍频性质 ,包括相位匹配角、有效非线性光学系数deff、容限角、走离角等。结果表明 ,BIBO晶体的最佳三倍频方向为 (137.7°,130°) ,其有效非线性光学系数值达到 3.6 0 pm/V ,属I类相位匹配。就主平面内的相位匹配方向而言 ,(14 6 .4°,90°)具有最大的有效非线性光学系数值 ,为 3.16pm/V。在 10 6 4nm的腔外三倍频实验中 ,(14 6 .4° ,90°)BIBO晶体的转换效率达到 39.5 % ,角度容限半宽为 0 .2 2mrad·cm ,该数值与 0 .175mrad·cm的计算值基本符合。由于(33.6°,90°)BIBO晶体的有效非线性光学系数较小 (0 .31pm/V) ,其三倍频转换效率小于 5 %。     

深紫外无机非线性光学晶体硼铍酸锶及其分子工程学探索方法

阐述了紫外无机非线性光学晶体分子工程学探索方法的基本特点，具体分析深紫外无机非线性光学晶体硼铍酸锶（ＳＢＢＯ）以氟硼铍酸钾（ＫＢＢＦ）为主要参考晶体的分子设计方法，随后根据晶体结构研究、单晶培养、和非线性光学性能测定等实验结果讨论ＳＢＢＯ作为新型深紫外无机晶体的主要优点，即它既具有更短的紫外吸收边（接近１５５ｎｍ）和较大的非线性光学系数（ｄ２２（ＳＢＢＯ）＝０６×ｄ２２（ＢＢＯ）＝１３８ｐｍ／Ｖ），同时晶体无明显层状习性，并肯有良好的化学稳定性和机械性能     

闪光灯泵浦Nd：YCOB自倍频激光器

ＮｄＣａ４ＹＯ（ＢＯ３）３（简称ＮｄＹＣＯＢ）是一种新型的自倍频晶体［１～３］。根据测定的吸收光谱,它有５条较宽的吸收带,因而极适合于用脉冲氙灯进行泵浦。作者利用脉冲氙灯泵浦ＮｄＹＣＯＢ实现了基频光和自倍频光的运转。实验中所用晶体掺杂的摩尔分数为０．...     

使用CNDO/S型近似方法计算NaNO_2晶体的倍频系数

本文使用CNDO/S型近似方法,计算(NO_2)~(-1)的单电子分子轨道,然后按基团理论的通用计算程序计算NaNO_2晶体的倍频系数,计算值和实验值符合得较好,计算结果明确指出:NaNO_2晶体倍频系数各向异性的原因来自基团的共轭π轨道,另外,本文的计算表明,有可能对非线性光学新材料探索提供计算机的预测。 本文还就非线性光学效应的双能级模型作了讨论,并指出了它的局限性。     

在BBO晶体中获得271—281.5nm和频输出

本文用自制的Q-YAG的倍频光泵浦Rh·6G染料,用调谐的染料激光束(562—598nm)与YAG的倍频光束在B-BaB2O4(BBO)晶体中和频,获得的连续可调谐范围是271-281.5nm,和频输出能量大子200μJ,最高转换效率为5%.我们用陈创天等人和K.Kato所给BB0晶体的Sellmetier方程计算了和频调谐曲线,它们之间的相位匹配角大约有一度之差.实验曲线与两条理论曲线都有不同程度的偏差.但是,与K.Kato的理论曲线更为接近.我们还讨论了BBO晶体的长度对输出能量的影响,并解释了产生这种影响的原因。     

晶体球法直接测量KTP晶体第Ⅰ类相位匹配曲线

报道了35ps激光脉冲射入直径为10mm KTP昌体球的第Ⅰ类相位匹配二次谐波产生实验,根据二次谐波产生转换效率直接测量了KTP晶体的第Ⅰ类相位匹配曲线及相应的有效非线性系数,并与6组色散方程给出的理论匹配曲线比较,指出Vanherzele的公式优于其他五组。     

Beam divergence effects on high power optical parametric oscillation

The beam divergence effects of the input pump laser on a high power nanosecond optical parametric oscillator （OPO） have been numerically simulated. The OPO conversion efficiency is affected due to the angular deviation of real laser beams from ideal phase matching conditions. Our theoretical model is based on the decomposition of the Gaussian beam and assumes each component has a single deviation angle and thus a particular wave vector mismatch. We take into account the variable intensity profile in the spatial and temporal domains of the Gaussian beam, the pump depletion effects for large-signal processes as well as the oscillatory effects of the three waves. Two nonlinear crystals β-BaB2O4 （BBO） and LiB305 （LBO） have been investigated in detail. The results indicate that the degree of beam divergence strongly influences the maximum pump intensity, optimum crystal length and OPO conversion efficiency. The impact of beam divergence is much more severe in the case of critical phase-matching for BBO than in the case of non-critical phase-matching for LBO. The results provide a way to choose the optimum parameters for a high power ns OPO such as the nonlinear material, the crystal length and the pump intensity, etc. Good agreement is obtained with our experimental results.     

Harmonic generation in bismuth triborate (BiB3O6)

We report a study of second- and third-harmonic generation in BiB₃O₆ (BiBO). The effective nonlinearity, phase-matching angle, acceptance bandwidth, and walk-off are calculated and analyzed within the principal planes of the optical indicatrix. In the experiment, the phase-matched harmonic generation is investigated within the xz and yz planes. Also, the temperature dependence of the noncritical phase matching for laser radiation propagating along the z axis is measured for second-harmonic generation (SHG) at crystal temperatures of 25–265^∘C. The corresponding wavelengths of the laser radiation are in the range of 1.16 to 1.34μm. In addition, SHG of 1342-nm radiation of a q-switched Nd:YVO₄ laser system is investigated for noncritical and critical phase matching. The achieved conversion efficiencies are 59% and 20%, respectively. Besides SHG, third-harmonic generation (THG) of 1064-nm, ns laser pulses is investigated. The measured conversion efficiency is as high as 34%. For THG the properties of BiBO are compared with those of BBO and LBO.     

BBO晶体在CPM非稳腔Nd：YAG激光器中的腔内倍频效应

本文报道用BBO晶体作为腔内倍频元件,在带抗共振环的对撞脉冲锁模非稳腔Nd:YAG激光器中实现腔内倍频激光输出,获得倍频能量转换效率为50.4%.理论和实验均证明了该激光器的BBO腔内倍频转换效率高于腔外倍频转换效率.     

飞秒激光在BBO晶体中倍频效率的数值计算

采用分步傅里叶法对飞秒激光在BBO晶体中倍频过程的效率进行了数值计算,分析表明这种方法既避免了其他数学方法的繁琐,又直观地展现了倍频过程的物理本质.针对有关实验条件,计算了脉宽为100fs的激光脉冲通过2mm长、Ⅰ类相位匹配的BBO晶体的倍频效率,计算结果与实验上对同样晶体倍频效率的测量是一致的. 关键词： 飞秒激光 倍频     

Harmonic and sum-frequency generation of pulsed laser radiation in BBO,LBO, and KD*P

The optical properties of the nonlinear crystals lithium borate (LBO), barium borate (BBO) and deuterated potassium phosphate (KD*P) are compared for second and third harmonic generation of Nd:YAG laser radiation. In an experimental investigation the conversion efficiency has been measured as a function of the energy density of 8 ns long laser pulses, generated by a commercial Nd:YAG oscillator-amplifier system. In LBO and BBO the second harmonic generation saturates at an energy density of about 1.5 J cm^–2 at efficiencies of 55–60%. In KD*P comparable efficiencies (40–55%) require energy densities of 2–2.6 J cm^–2. Similar results are obtained for frequency tripling. In LBO and BBO saturated efficiencies of 20–25% are measured at an energy density of about 1.5 J cm^–2. In KD*P efficiencies of 20% are obtained at energy densities exceeding 2 J cm^–2. Besides for doubling and tripling of Nd:YAG laser radiation the phase-matching is calculated for frequency conversion of tunable laser light. The results demonstrate that in LBO and BBO phase-matched sum-frequency mixing of UV and infrared laser light generates tunable radiation at wavelengths as short as the transmission cut-off at 160 nm and 190 nm, respectively.     

Studies on the SFD Properties of NdxGd1-xCa4O(BO3)3 Solid-solution Crystal

NdxGd1-xCa4O(BO3)3 (NdGdCOB) is a new self-frequency-doubling (SFD) solid-solution crystal. The second-harmonic generation (SHG) phase-matching (PM) curves were calculated by using refractive indices. The deff of NdGdCOB crystal along different PM directions were calculated according to the sellmeier equation and dijk data in which the (θ=66.8°, φ=132.6°) PM direction has the highest deff. SFD experiments were carried out with Ti:sapphire CW laser and pulsed dye-laser. A green laser output power up to 225 mW at 530 nm was achieved from a 7×3×3 mm3 crystal sample pumped by 1560 mW CW Ti:sapphire laser. The lasing threshold of SFD was lower than 1.8 mW along the PM direction (66.8°,132.6°). The optical-optical conversion efficiency was 14.4%. The conversion efficiency was 7.7% when 10×3×3 mm3 sample was side-pumped by the pulsed dye-laser tuned to 595.4 nm with 17.5 mJ energy and the lasing threshold is 1.2 mJ.     

Studies on the SFD Properties of Nd_xGd_(1-x)Ca_4O(BO_3)_3 Solid-solution Crystal

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