共查询到20条相似文献，搜索用时 15 毫秒
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Russian Journal of Organic Chemistry - 相似文献
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《Plasma Chemistry and Plasma Processing》2003,23(3):607-607
Plasma Chemistry and Plasma Processing - 相似文献
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《Russian Journal of Electrochemistry》2004,40(10):1095-1098
Russian Journal of Electrochemistry - 相似文献
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Robert R. Holmes 《Phosphorus, sulfur, and silicon and the related elements》2013,188(7):1523-1535
The coordination tendencies of phosphorus to form a hexacoordinated state from a pentacoordinated state which might assist in describing mechanistic action of phosphoryl transfer enzymes are delineated. The factors discussed include substrate and transition or intermediate state anionicity; hydrogen bonding; packing effects, i.e., van der Waals forces; the ease of formation of hexacoordinate phosphorus from lower coordinate states; and the pseudorotation problem common to nonrigid pentacoordinate phosphorus. In view of the work reported in this account and recent work on enzyme promiscuity and moonlighting activities, it is suggested that donor action should play a role in determining active-site interactions in phosphoryl transfer enzyme mechanisms. 相似文献
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