Effect of hydrogen on the hyperfine magnetic field in crystalline Zr-Fe alloys

This paper deals with room temperature⁵⁷Fe Mössbauer studies performed on crystalline Zr_1–y Fe _y and Zr_1–y Fe _y H _x (0.05y0.5) alloys. For hydrogenated alloys, the transition from parato ferromagnetic behaviour is observed aty = 0.25, i.e. a considerably lower concentration of iron compared to uncharged alloys. It seems to be not only attributable to ZrFe₂ formation. Apart from ZrFe₂, a relatively intensive and quite different than the ZrFe₂ contribution to theP(B) distribution has been observed for hydrogen charged alloys with only 25 at.% Fe. It is linked to the origin of the additional magnetic component due to hydrogen absorption in which Fe has less than 6 Fe nearest neighbours.     

Hyperfine interaction of111Cd in In-Pd intermetallic compounds

Perturbed - angular correlation (PAC) spectroscopy was applied to study the hyperfine parameters for¹¹¹In probes in In-Pd intermetallic compounds. The PAC spectra measured in In₃Pd, In₃Pd₂ and InPd₂ compounds reflect the number, population and symmetry of nonequivalent indium probe sites predicted by the crystallographic data. The temperature dependence of the observed electric field gradients was measured in the temperature range 80–873 K.     

Temperature dependences of the flow and critical shear stresses of dispersion-hardening alloys

A study was made of the temperature dependences of the flow stress _0.1 (T) and of the critical shear stress _cr(T) of Cu-15% A1-(1–2)% Co, Cu-8% A1-(2–2.8)% Co, and Cu-4% A1–2% Co alloys containing noncoherent intermetallic particles. In the case of single crystals at temperatures 77–673° K there was a good agreement between the theoretically calculated values of the Orowan hardening and those found experimentally, so that the dependence _cr(T) was governed by the temperature dependence of the shear modulus G(T). For polycrystalline samples the usual dependence of the mechanical propertiesties on the grain size was not observed. At temperatures from 77 to 473–573°K the dependence _0.1 (T) was similar to the dependence G(T) and a good agreement was observed between the theoretically calculated dispersion hardening effects with those found experimentally. At temperatures T > 473–573°K the deformation was influenced greatly by grain-boundary glide, which enhanced the dependence _0.1 (T) compared with that expected theoretically.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 85–91, June, 1980.     

XMCD study of the local magnetic and structural properties of microcrystalline NdFeB-based alloys

X-ray Magnetic Circular Dichroism (XMCD) technique was used to investigate local magnetic properties of microcrystalline Nd_10.4Zr_4.0Fe_79.2B_6.4 samples, oriented along either easy or hard magnetization direction. The Nd L _2,3 and Fe K edge XMCD spectra were measured at room temperature under a magnetic field of T. A very strong dependence of XMCD spectra on the sample orientation has been observed at the NdL _2,3-edges, whereas the Fe K-edge XMCD spectra are found to be practically isotropic. This result indicates that magnetic anisotropy of NdFeB-based alloys originates from the Nd sublattice. In addition, element selective magnetization curves have been recorded by measuring the intensity of XMCD signals as a function of an applied magnetic field up to T. To find a correlation between local and macroscopic magnetic properties of studied samples we compared these data with magnetization curves, measured by vibrating sample magnetometer up to T. Results are important for understanding the origin of high-coercivity state in NdFeB-based intermetallic compounds.     

Mössbauer spectroscopy of zirconium alloys

Mössbauer investigations of zirconium alloys were examined. Data about the chemical state of iron atoms in the zirconium alloys of different composition has been provided. Mössbauer spectroscopy revealed that small quantities of iron in binary zirconium alloy are in the solid solution α-Zr (up to 0.02 wt.%). Different iron atoms concentration and thermo-mechanical treatments may lead to formation the intermetallic compounds Zr₃Fe, Zr₂Fe, ZrFe₂. Adding tin atoms does not affect the formation and shape of Mössbauer spectra of these compounds. Adding Cr and Nb atoms makes significant changes in the shape of Mössbauer spectra and leads to the formation of complex intermetallic compounds. Adding Cu and W atoms, the shape of the binary alloys spectra (Zr-Fe) remains unchanged, but a change in the temperature dependence behavior of the spectral parameters occurs and also, changes to the properties of the alloys.     

Mass and Γ3π0/Γγγ decay branching ratio of theη-meson from the p(γ, η)p reaction

Near threshold photoproduction of-mesons from the proton has been measured at the MAMI accelerator with the TAPS spectrometer. The mass of the-meson was deduced from the threshold energy for-photoproduction. The result of m =(547.12 ± 0.06 ± 0.25) MeV supports the low value of the-mass reported from a dp ³He measurement at SATURNE in 1992. The-decay branching ratio ₃0/ was measured to be (0.832±0.005±0.012).This article was processed by the author using the L^AT_EX style filepljour2 from Springer-Verlag.     

The Kinetics of the Cd21Ni5 Intermetallic Growth under High Hydrostatic Pressure

The kinetics of growth of the Cd₂₁Ni₅ intermetallic phase in two-layer Cd-Ni samples has been studied at hydrostatic pressures 0.05–0.9 GPa and at temperatures 200–280°C. Arrhenius equations for both interdiffusion through the growing phase layer and the interfacial reaction have been obtained for different pressures. The activation volumes have been found to be 0.9V₀ for interdiffusion and 1.6V₀ for interfacial reaction, where V_{_0} 1.8 × 10_-29m₃ is the average volume per atom in the Cd₂₁Ni₅ lattice. Atomistic mechanisms of intermetallic growth are discussed.     

Investigation of hyperfine quadrupole interactions in UGe<Subscript>2</Subscript> and UAl<Subscript>2</Subscript> compounds on <Superscript>111</Superscript>Cd probe nuclei by the perturbed angular correlation method

The parameters of nuclear quadrupole hyperfine interaction in intermetallic UGe₂ and UAl₂ compounds have been measured in a temperature range of 100–300 K using the perturbed angular γγ correlation method on ¹¹¹Cd probe nuclei. The results obtained for UGe₂ indicate a pronounced anisotropic character in the distribution of f electrons in agreement with the calculation of the electronic structure of this compound. The hybridization degree between f electrons of U and p electrons of Al in UAl₂ is lower than the hybridization degree between f electrons of U and p electrons of Ge in UGe₂.     

Temperature dependence of drift mobility in the presence of trap-recombination centers

The effect of trap-recombination centers on the temperature dependence of the chargecarrier drift mobility _g in semiconductors is investigated both theoretically and experimentally. The temperature dependence _g(T) becomes steeper than the temperature dependence of the microscopic mobility (T) in the temperature range where E_d=E_t ± 2T (E_d is the demarcation level; E_t is the level at which the centers occur). The dependence _g(T) is measured experimentally in CdS from the temperature dependence of the acoustic current. The experiments agree with the theoretical calculations.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 80–84, December, 1977.     

Measurement of the stopping power of Au and MgF2 for slow muons

The spectral flux densityn(T) of ^– emerging from a Au or MgF₂ moderator has been measured at low energiesT using time-of-flight. Fromn(T) the stopping powerS(T) of Au was determined for 2 keVT22 keV, and of MgF₂ for 2 keVT12 keV. For Au,S(T) is smaller than calculated values obtained from proton atomic data practically in the wholeT range (Barkas effect); at lowT S(T) approaches the calculated values. For MgF₂,S(T) agrees fairly with the calculated values above 5 keV and then drops below these values. We ascribe this dropping to the large energy gap of the MgF₂ insulator.We wish to thank H. Angerer, H. Plendl, G. Schmidt, and C.A. Schug for help with the data taking, J. Homolka for computational help, H. Hagn, and H. Weiss for technical assistance and P. Maier-Komor and R. Scherrer for manufacturing the windows and targets. The hospitality of PSI and financial support by the German Bundesministerium für Forschung und Technologie are acknowledged.     

Neutron diffraction study of crystal structure and antiferromagnetic ordering in the heavy fermion compound CePd2Al3

Nuclear and magnetic structures of an annealed polycrystalline sample of the heavy-fermion compound CePd₂Al₃ prepared by arc-melting were investigated by neutron powder diffraction. The chemical structure corresponds well to the ordered hexagonal PrNi₂Al₃-type structure. The antiferromagnetic structure of CePd₂Al₃ with an ordered magnetic moment _Ce=0.47(2) _B at saturation is remarkably similar to that in the heavy fermion superconductor UPd₂Al₃. The additional incommensurate magnetic structures reported previously both for UPd₂Al₃ and CePd₂Al₃ are not observed in the present sample of CePd₂Al₃. At 1.4 K the magnetoresistivity of CePd₂Al₃ measured up to 14 T indicates only one field-induced phase transition at 3.0 T.     

Ordering of atoms in 3d sublattice of the intermetallic quasibinary system Dy(Fe1−xMnx)2

Methods of x-ray analysis and nuclear -resonance (Mössbauer effect) have been used to study the distribution of iron and manganese atoms in the intermetallic quasibinary system Dy(Fe_1–xMn_x)₂, which is isostructural to the Laves phase C15. Ordering of atoms of transition metals has been found in 3d sublattice of intermetallic compounds Dy(Fe_1–xMn_x)₂ with the formation of a triple superstructure having the stoichiometric composition Dy(Fe_0·.25Mn_0·.75)₂.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 55–60, June, 1986.     

Influence of radiation defects on the hyperfine magnetic field at181Ta in (Zr0.9Hf0.1)Fe2

TDPAC measurements for the 133–482 keV -ray cascade in¹⁸¹Ta were performed with¹⁸¹Hf sources in the ferromagnetic Laves intermetallic compound (Zr_0.9Hf_0.1)Fe₂. Two samples, annealed and not annealed after activation of¹⁸¹Hf in a reactor, were investigated. It was shown that in the annealed sample practically all the¹⁸¹Ta daughters occupied regular sites in the cubic Zr(Hf) sublattice and experienced a unique magnetic hyperfine fieldH _h.f.(Ta)=–6.38(14) T. In the unannealed source the regular precession was observed only for 50% of¹⁸¹Ta nuclei, another half of them were located at some unobservable sites due, obviously, to a recoil after the (n, ) reaction. Possible reasons for discrepancies in the results onH _h.f.(Ta) reported in the literature are discussed.     

Temperature scaling of the integrated dynamical susceptibility in YBa2Cu3O6.5(T c =50 K)

The magnetic neutron scattering cross section in a crystal YBa₂Cu₃O_6.5(T _c =50 K) has been measured for energies between 4.5 meV and 15 meV and temperatures between 10 K and 275 K. From these data we extract the generalized susceptibility integrated around the (, ) position These data are combined with those at 8.3 and 33.1 meV from a previous study. It is found thatI(, T) exhibits the simple temperature scaling form found previously in La_2–x Sr _x CuO₄. Specifically, in YBa₂Cu₃O_6.5,I(, T)=I(, 0)2/tan^–1 (/0.9T). Implications of this behavior for the d.c. and infrared conductivity are discussed.     

TheK-Fluorescence Yield of Germanium

TheK-Fluorescence Yield _k of Germanium has been measured using the coincidence method and investigating the decay of⁷⁴As. The branching ratios of this decay had to be measured and all relevant determining values, as detection efficiencies, absorption coefficients etc. The experimental results areP _{K K} = 0.494±0.012 and _K= 0.561±0.015 usingP _K= 0.881±0.003. For the branching ratios of the decay of⁷⁴As we obtainedEC ₂ (1.204) 0.88±0.06%EC ₁ (0.596) 32.8±0.8 % ₁ ⁺ (0.596) 24.7±0.8 %EC _{1 1} ⁺ =1.332±0.046.Additionally the half-lifeT _1/2=(17.76±0.03) d has been measured.     

Understanding the scalar mesonq\bar q nonet

It is shown that one can fit the available data on thea _o(980),f _o(1300) andK _o ^* (1430) mesons as a distorted 0⁺⁺ nonet using very few (5–6) parameters and an improved version of the unitarized quark model. This includes all light two-pseudoscalar thresholds, constraints from Adler zeroes, flavour symmetric couplings, unitarity and physically acceptable analyticity. The parameters include a bare or mass, an over-all coupling constant, a cutoff and a strange quark mass of 100 MeV, which is in accord with expectations from the quark model. It is found that in particular for thea ₀(980) andf ₀(980) the component, in the wave function is large, i.e., for a large fraction of the time the state is transformed into a virtual pair. This component, together with a similar component of for thea ₀(980), and , and components for thef ₀(980), causes the substantial shift to a lower mass than what is naively expected from the component alone. Mass, width and mixing parameters, including sheet and pole positions, of the four resonances are given, with a detailed pedagogical discussion of their meaning.     

Study of the Microstructure,Crystallographic Structure and Thermal Stability of Al–Ti–Nb Alloys Produced by Selective Electron Beam Alloying

This paper aims an investigation of the microstructure and crystallographic structure as well as the thermal stability of Al–Ti–Nb formed by selective electron beam surface alloying. The fabrication of the samples has been carried out using circular sweep mode, as two velocities of the sample movement have been chosen: V₁ = 1 cm/s and V₂ = 0.5 cm/s. The studied microstructure and crystallographic structure have been investigated by X-ray diffraction (XRD) and Scanning electron microscopy (SEM) respectively. The thermal behavior of the obtained surface alloys are evaluated by the coefficient of thermal expansion (CTE) which has been evaluated by neutron diffraction measurements at high temperature. The results show that in the earlier stages of formation, the microstructure of the intermetallic phase is mainly in the form of coarse fractions, but at the following moments they dissolve, forming separated alloyed zone and base Al substrate as the alloyed zone consists of fine (Ti,Nb)Al₃ particles dispersed in the Al matrix with small amount of undissolved intermetallic fractions. Formation of preferred crystallographic orientation as a function of the speed of specimen motion has not been observed. The performed neutron diffraction measurements show that the lattice parameters of the obtained intermetallic (Ti,Nb)Al₃ are less upshifted in comparison to pure Al. It has been found that the aluminium lattice is much more unstable at high temperatures than that of the intermetallic phase. The CTE for the intermetallic phase is 8.70 ppm/K for a axis and 7.75 ppm/K for c axis respectively while considering Al it is 12.95 ppm/K.     

On the phase transition of superconducting cuprates in zero and non-zero magnetic fields

We present the results of measurements of the magnetizationM(T) and the specific heatC _p (T) of YBa₂Cu₃O_6.9 and Bi₂Sr₂CaCu₂O₈ in the vicinity of their respective critical temperature and in magnetic fields between 0 and 5 T. From these data we calculate the temperature- and magnetic field derivatives ofM andC _p . Both these measured and calculated quantities are used for testing theoretical predictions concerning the universality class of the transitions and to verify the influence of fluctuations accompanying the transitions.     

Spectroscopic study of potential magneto-optic storage layers

We present an experimental investigation of magneto-optic (MO) thin film materials of interest in optical storage. XPS valence band spectra of ultrahigh vacuum deposited rare earth — Fe₅₀Co₅₀ alloys are correlated to magneto-optic and reflectivity spectra measured ex-situ in the photon energy range 0.5 E _ph 5.5 eV. It is found that 4f ⁿ 4f ^n–15d ¹ optical transitions contribute to room temperature Kerr spectra in Pr-FeCo and Nd-FeCo, but only in the UV spectral region (300 nm). Eu is found to enter Eu-FeCo intermetallic alloys with a 4f ⁷ ground state at –2 eV binding energy. However, no substantial contribution to the Kerr effect from excitations of this electronic state has been observed n either at room temperaturen or at 100 K. We present a general argument that 4f excitations of RE ions in typical intermetallic alloys can never be expected to contribute more than some tenths of a degree to _k in contrast to the well known huge rotations in RE-chalcogenides.For Yb-FeCo we have observed in XPS a mixed valence behavior of Yb showing a discontinuous transition from divalent Yb²⁺ in the pure metal to mixed valent Yb^2.55+ in amorphous Yb-FeCo films. Nofd contributions to the room temperature MO spectra have been detected. Strong optical enhancement effects are presented for metallic bilayer and multilayer structures of the type MO-layer/reflector. The total thickness of an optimized structure corresponds to about two times the penetration depth of light. Enhancement occurs predominantly at photon energies below the plasma frequency of the reflector material and is caused by low values of the optical constantsn andk of the reflector. In storage materials like Tb-FeCo the read-out performance can be improved by about a factor of 2 with a bilayer of 30 nm Tb-FeCo on Cu. Quantitative modelling of the optical and magneto-optic properties of these films is discussed.     

Pressure dependence of the distribution of hyperfine fields in ZrFe2 and Zr(Nb)Fe2

The pressure dependence of the hyperfine fields of⁹¹Zr and⁵⁷Fe, and of⁹³Nb as a dilute impurity, has been measured for ZrFe₂ up to 8 kbar at 4.2 K. The results suggest that Nb, like Zr, carries a magnetic moment anti-parallel to the Fe moment.