共查询到17条相似文献,搜索用时 71 毫秒
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采用水热法和电化学沉积法,成功制备了包覆有SnO2纳米颗粒的WO3纳米棒阵列薄膜,退火处理后形成WO3/SnO2异质结复合薄膜。通过改变SnO2的沉积时间得到了复合薄膜的最佳制备条件。采用XRD,FESEM对WO3/SnO2复合薄膜的物相和形貌进行了分析,通过电化学工作站对WO3/SnO2复合薄膜的光电性能进行了研究,结果表明,电沉积时间为120 s时,WO3/SnO2复合薄膜具有最小的阻抗,且在0.6 V的偏压下光电流密度为0.46 mA/cm2,相比于单一WO3纳米棒薄膜,表现出更好的光电化学性能。 相似文献
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采用溶胶-凝胶技术,利用旋转涂膜法制备非晶态二氧化锡薄膜,常温下在含有CO的气氛中光通过薄膜的透射率变大,对CO有较高的灵敏度.对制备过程中出现的实验现象、制备机理及薄膜的结构和特性进行了研究. 相似文献
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采用溶胶凝胶(sol-gel)工艺制备了Sb掺杂SnO2/SiO2复合膜。通过X射线衍射(XRD)、傅立叶变换红外谱(FT-IR)及原子力显微镜(AFM)表征了薄膜样品的物相结构与表面形貌,利用紫外-可见光谱研究了复合薄膜光学特性.利用p-偏振光双面反射法对薄膜的气敏特性进行了测试。实验结果表明,薄膜中的晶粒具有纳米尺寸(~35nm)的大小.比表面积大,孔隙率高;薄膜的透光率高,可见光波段近95%;纳米Sb:SnO2:SiO2复合膜的气敏灵敏度高于纯SnO2薄膜及Sb掺杂的SnO2薄膜。 相似文献
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溶胶-凝胶法制备ZnO薄膜光电导紫外光敏器件 总被引:1,自引:1,他引:0
利用溶胶-凝胶(Sol-Gel)法制备ZnO薄膜获得了响应速度快和灵敏度高的光电导型紫外光敏器件,并改善了器件的稳定性.采用正交试验表格L18[37]安排试验.分析后得到具有最佳响应时间和灵敏度的优化工艺参数为搅拌时间2.0 h,甩膜速率4 000 r/min,甩膜层数3层,退火温度500℃,退火时间2.5 h,预处理温度200℃,叉指间距0.109 mm.测得器件上升时间5 s,下降时间3 s,在0.85 mW/cm2的紫外光强下的灵敏度(光电流与暗电流之比)R/R0为26,稳定性能良好. 相似文献
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The authors report on the fabrication of H2S gas sensors made of SnO2 mixed with ZrO2. Their sensitivities, responses, and selectivities to H2S are presented. A 10-p.p.m. concentration of H2S gas changes the sensor resistivity to a value 300 times lower than that for air around 175°C. The sensors exhibit highly selective detection of H2 S in an atmosphere containing H2S and H2. The mechanism of the reaction between the sensors and H2S are also discussed 相似文献
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In this work, iron-doped SnO2 powders were prepared by two methods: mechanical alloying and mechanochemical alloying with successive thermal treatment. The influence of different milling conditions such as ball to powder weight ratio, milling time, rotation velocity of supporting disc and the type of iron starting reactive and their Fe concentration on the structural and magnetic properties of the products were investigated. A greater incorporation of Fe in the SnO2 structure was observed when the samples were prepared by using mechanochemical alloying and successive thermal treatment. 相似文献
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(Li,Nb)掺杂SnO2压敏材料的电学非线性研究 总被引:4,自引:3,他引:4
研究了掺锂对SnO2压敏电阻器性能的影响.研究发现Li+对Sn4+的取代能明显提高陶瓷的烧结速度和致密度,且能大幅度改善材料的电学非线性性能.掺入x(Li2CO3)为1.0%的陶瓷样品具有最高的密度(P=6.77g/cm3)、最高的介电常数(ε=1851)、最低的视在势垒电场(EB=68.86V/mm)和最高的非线性常数(α=9.9).对比发现,Na+由于具有较大的离子粒半径,其掺杂改性性能相对较差.提出了SnO2@Li2CO3@Nb2O5晶界缺陷势垒模型. 相似文献
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We studied fluorine-doped tin oxide on a glass substrate at 350℃using an ultrasonic spray technique. Tin(Ⅱ) chloride dehydrate,ammonium fluoride dehydrate,ethanol and NaOH were used as the starting material, dopant source,solvent and stabilizer,respectively.The SnO2:F thin films were deposited at 350℃and a pending time of 60 and 90 s.The as-grown films exhibit a hexagonal wurtzite structure and have(101) orientation.The G = 31.82 nm value of the grain size is attained from SnO2:F film grown at 90 s,and the transmittance is greater than 80%in the visible region.The optical gap energy is found to measure 4.05 eV for the film prepared at 90 s, and the increase in the electrical conductivity of the film with the temperature of the sample is up to a maximum value of 265.58(Ω·cm)-1,with the maximum activation energy value of the films being found to measure 22.85 meV,indicating that the films exhibit an n-type semiconducting nature. 相似文献
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A calculation of thermoelectric power in fluorine-doped SnO2 thin films is carried out using the Boltzmann transport theory and including anisotropic effects over material as well as the degeneracy grade of the samples. Curves of thermoelectric power in dependence of the temperature and concentration of F-impurities are reported. Finally, the computed values are compared with those obtained experimentally. 相似文献