“Alpha decays” of <Stack><Subscript>Λ</Subscript><Superscript>10</Superscript></Stack>Be and <Stack><Subscript>Λ</Subscript><Superscript>10</Superscript></Stack>B hypernuclei: Phenomenological analysis and role of nuclear structure

Hypernuclei are used to study the baryon-baryon weak interaction and associated effective weak Hamiltonian. We will show how the proper choice of hypernucleus can be used to pick out components of the effective weak Hamiltonian. It is well known that removing one nucleon from ⁹Be or ⁹B results in ⁸Be* with a subsequent αα decay. Through this unique process, it would be possible to identify final states of the residual nucleus. So, due to these specific properties of the core nuclei ⁹Be and ⁹B, it may be possible to measure the branching fractions Γ _ααi ^n(p) for the exclusive decays of the _Λ ¹⁰ Be ( _Λ ¹⁰ B) hypernuclei.     

Resonant parameters of <Superscript>5</Superscript>He and <Superscript>5</Superscript>Li states and nucleon-α scattering

A new method of analysis of resonant parameters in the framework of the J-matrix inverse scattering formalism is proposed. The method is applied to analysis of Nα scattering in various partial waves. The obtained 1/2^? and 3/2^? resonance energies and widths in ⁵He and ⁵Li nuclei are in good agreement with the results of other approaches. The eigenenergies entering the J-matrix phase shift parameterization are shown to correlate well with the respective results of no-core shell model calculations, in particular, in the case of non-resonant s-wave scattering.     

O<Subscript>2</Subscript> photodesorption from AuO<Stack><Subscript>2</Subscript><Superscript>−</Superscript></Stack> and Au<Subscript>2</Subscript>O<Stack><Subscript>2</Subscript><Superscript>−</Superscript></Stack>

Using time-resolved photoelectron spectroscopy, the decay channels of AuO₂⁻ and Au₂O₂⁻ following photoexcitation with 3.1-eV photons have been studied. For AuO₂⁻, a state with a rather long lifetime of 30 ps has been identified. Its decay path could not be determined but photodesorption can be excluded. For Au₂O₂⁻, the spectra indicate O₂ desorption after 3.1-eV photoexcitation on a time scale of 1 ps. While comparing these results on Au _n O₂⁻ with analogous data on Ag _n O₂⁻ clusters, a discernible pattern emerges: for dissociatively bound O₂(AuO₂⁻, Ag₃O₂⁻), there are long-living excited states which do not decay by oxygen desorption, while for molecular chemisorption (Au₂O₂⁻, Ag₂O₂⁻, Ag₄O₂⁻, Ag₈O₂⁻), the 3.1-eV photoexcitation triggers fast O₂ desorption with a high quantum yield.     

Synthesis and electrochemical performance of amorphous nickel hydroxide codoped with Fe<Superscript>3+</Superscript> and CO<Stack><Subscript>3</Subscript><Superscript>2−</Superscript></Stack>

Amorphous nickel hydroxide codoped with Fe³⁺ and CO₃²⁻ was synthesized by micro-emulsion precipitation method combined with rapid freezing technique. The microstructure and composition of the sample were characterized by X-ray diffraction and IR analysis. The electrochemical performance of the sample was analyzed by cyclic voltammetry, electrochemical impedance spectroscopy, and charge–discharge tests. The results showed that the Fe³⁺ and CO₃²⁻ codoping enhances the amorphous feature of the prepared nickel hydroxide. Moreover, the Fe³⁺ and CO₃²⁻ codoping could increase the specific capacity and improve the electrochemical reversibility of the amorphous nickel hydroxide electrode.     

<Emphasis Type="Italic">J</Emphasis><Superscript>π</Superscript>0<Superscript>−</Superscript> levels in <Superscript>156</Superscript>Gd and <Superscript>158</Superscript>Gd

The 0^? states in the ¹⁵⁶Gd nucleus at E = 1952.38 keV and in the ¹⁵⁸Gd nucleus at E = 2269.16 keV are established on the basis of an analysis of available data on even-even deformed nuclei. From data on the deexcitation of the levels and on the probability of their population by beta transitions, it is found that these states have a two-particle proton structure. A comparison of our data with information about the 0^? levels in the ¹⁷⁰Yb and ¹⁷⁶Hf nuclei makes it possible to conclude that J^π0^? two-particle states exist at an excitation energy of about 2 MeV and higher.     

A Simple and Neutral Receptor Acting as a Sensitive and Switch-on Fluorescent Chemosensor for H<Subscript>2</Subscript>PO<Stack><Subscript>4</Subscript><Superscript>−</Superscript></Stack>

A novel artificial anion chemosensor 1 based on 2, 2′-di (4-nitrophenylurea-β-N-yl) -1, 1′-binaphthyl is designed and synthesized for sensing anions including halide ions and oxoanions. The fluorescent emission of the binaphthyl of receptor 1, forming the hydrogen bonding with anions as the sensing mechanism, is monitored in DMSO for detecting anions. In brief, while most of the anion chemosensors are switch-off fluorescent chemosensor, or non-fluorescent sensor, receptor 1 exhibits obviously the switch-on emission during the complexation with H₂PO₄⁻.     

<Superscript>10</Superscript>B–<Superscript>11</Superscript>B isotope substitution and superconductivity in ZrB<Subscript>12</Subscript>

The specific heat of the ZrB₁₂ compound in the normal and superconducting states (T _C ≈ 6 K) has been studied in the 1.9–7 K temperature range for high-quality single crystals with different relative contents of boron isotopes. For Zr¹⁰B₁₂, Zr^natB₁₂, and Zr¹¹B₁₂ dodecaborides, the electron density of states and the electronphonon coupling constant, λ_e-ph ∼ 0.4, are found. The dependence of the thermodynamic and upper critical fields, as well as of the Ginzburg-Landau parameter (κ = 0.8–1.14) on temperature and isotope composition is determined. The results suggest the existence of the magnetic field induced phase transition at T* = 4–5 K, which is not related to the transition from type-I to type-II superconductivity. The possibilities of the existence of two-gap superconductivity and a structural phase transition at T* in zirconium dodecaboride are discussed.     

Photoproduction of π<Superscript>0</Superscript>π<Superscript>+</Superscript> pairs on proton and deuteron

The reaction of π⁰π⁺ photoproduction on free and quasi-free protons with γ-ray energies from 0.5 to 1.5 GeV has been studied. Its cross section was measured in the range θ _π ⁰ ≥ 20°. The distributions of π⁰π⁺, π⁰n, and π⁺n invariant masses were analyzed. The experiment was performed using the Compton back-scattered γ-ray beam at the GRAAL facility (Grenoble, France), applying liquid deuterium and hydrogen targets and a large-aperture (almost 4π) detector. Particular attention was paid to analysis of systematic errors related to the neutron detection efficiency.     

Conserved vector current and decays τ<Superscript>−</Superscript> → η(η′)π<Superscript>−</Superscript>π<Superscript>0</Superscript>ν<Subscript>τ</Subscript>

We use experimental data on e ⁺ e ^? → (η′)π⁺π^? and conservation of vector current to estimate the branching fractions of τ^? decay to η(η′)π^?π⁰ν_τ. The obtained values are compared to the experimental results.     

Inversion of the <Emphasis Type="Italic">K</Emphasis><Superscript>π</Superscript>=1<Superscript>−</Superscript> states in <Superscript>156</Superscript>Gd and <Superscript>170</Superscript>Yb

For the ¹⁵⁶Gd and ¹⁷⁰Yb nuclei, where the inversion of levels in the K^π=1^? bands is observed, the energies of rotational levels are calculated on the basis of the Coriolis interaction model for the states of two bands whose quantum numbers are K^π=1^?. New 0^? levels are introduced in ¹⁷⁰Yb, and the structure of ¹⁷⁰Er is refined. The interaction parameters calculated for six nuclei are considered within the structure predicted by the quasiparticle-phonon model.     

Perturbative analysis of the 2νββ decays of <Superscript>100</Superscript>Mo and <Superscript>116</Superscript>Cd

We have performed a theoretical analysis of the ground-state-to-ground-state transitions in ¹⁰⁰Mo and ¹¹⁶Cd, based on the quasiparticle random-phase approximation and on a straightforward perturbative scheme. The results show that the single-state dominance found in the realistic calculations of the nuclear matrix elements, which is consistent with data, can be viewed as a result of the interference between few two-quasiparticle configurations. Received: 12 August 2002 / Accepted: 23 October 2002 / Published online: 18 February 2003 RID="a" ID="a"e-mail: civitarese@fisica.unlp.edu.ar Communicated by V.V. Anisovich     

Long <Emphasis FontCategory="NonProportional">K</Emphasis><Superscript>π</Superscript> = 0<Superscript>+</Superscript> and 4<Superscript>−</Superscript> bands in deformed nuclei

Experimental data on some long bands in N=88–98 deformed nuclei are analyzed on the basis of a method systematizing the energies of levels and inertial parameters and a method employing the analogy between neighboring. Beta bands built on low-lying 0 ₂ ⁺ levels are identified in N=90 isotones, including the ¹⁵⁸Er, ¹⁶⁰Yb, and ¹⁶²Hf nuclei. Some of intermediate members of these bands have not been found yet. The systematic properties of 4^? bands are presented, and the dynamics of the inertial parameters of these bands in N=88–98 isotones is revealed. The bands are identified in ¹⁵⁸Yb, ¹⁵⁶Dy, ¹⁵⁶Er, ¹⁶²Yb, and ¹⁶⁶Hf.     

A comparative study of singlet-oxygen generation by С<Subscript>60</Subscript> and С<Subscript>70</Subscript> fullerenes

The results of comparative investigations of singlet-oxygen generation by С₆₀ and С₇₀ fullerenes in tetrachloromethane solutions, aqueous suspensions, and solid-phase powders of fullerenes optically excited by cw diode arrays with different wavelengths and by pulsed xenon lamps with a band filter are presented. The measurements were performed by recording singlet-oxygen phosphorescence at the O²(¹Δ_g)–O₂(³Σ_g) transition (λ = 1270 nm).     

Prompt <Emphasis Type="Italic">γ</Emphasis> rays in <Superscript>77</Superscript>Ge and <Superscript>75</Superscript>Ge after thermal neutron capture

The reactions ⁷⁴Ge(n, γ) and ⁷⁶Ge(n, γ) have been measured with cold neutrons generated by the research reactor FRM II near Munich, Germany. The γ rays have been detected by two Compton-suppressed HPGe systems in single and coincidence mode. The number of identified prompt transitions and levels in ⁷⁷Ge was increased significantly and the decay scheme could be reconstructed for the first time. The decay scheme was also reconstructed for 68 prompt transitions in ⁷⁵Ge. Previously reported inconsistencies of the γ-ray intensities in the ⁷⁷Ge β decay could be resolved. In particular, the region around 2039 keV was investigated carefully, since the background to the neutrinoless double-beta decay of ⁷⁶Ge must be understood well for the upcoming Gerda and Majorana experiments.     

Cold and ultracold collisions of MgH (<Superscript>2</Superscript>Σ<Superscript>+</Superscript>) with helium

The cross sections for rotational, fine-structure and projection-change transitions in collision of MgH (²Σ⁺) molecule with ³He and ⁴He atoms were computed at cold and ultracold temperatures using the ab initio potential energy surface. The significant suppression feature and resonance pattern caused by spin-rotation interaction were found and discussed. The collisions exhibit a strong isotope effect in the ultracold regime. The rotational relaxations of the fine-structure excited energy levels tendentiously preserve the F index. The ratio of the cross sections for elastic and spin-flipping collision with ³He partner is always greater than seven orders of magnitude for the energy range 10^-6−1cm^-1 and suggests the MgH molecule is a good candidate for ³He buffer gas cooling.     

Shape coexistence and <Emphasis Type="Italic">α</Emphasis>-decay chains of <Superscript>293</Superscript>Lv

Two recently observed ²⁹³Lv (Z = 116) α-decay chains [Eur. Phys. J. A 48, 62 (2012)] are investigated in the framework of covariant density functional theory with PC-PK1, where the pairing correlations are treated by the Bardeen-Cooper-Schrieffer method with a density-independent zerorange force. From the calculated potential energy curves, it is found that two minima always occur, with one having an almost spherical shape and the other exhibiting a large deformed prolate shape. Originating from the ground state and the shape-isomeric state of ²⁹³Lv, the two observed α-decay chains are constructed and the calculated Q _α values are found to be in good agreement with the data.     

Synthesis,structure, and optical and photocatalytic properties of quasi-one-dimensional ZnO doped with Со<Subscript>3</Subscript>O<Subscript>4</Subscript> and carbon

One-dimensional nanocomposites Zn_1–x Co _x O_1–y С _у :nCo₃O₄ and solid solutions Zn_1–x Co _x O_1–y С _у , which are promising photocatalysts for the oxidation of toxic organic compounds in visible light, are obtained via the thermolysis of Zn_1–x Co _x (HCOO)(OCH₂CH₂O)_1/2 (0.1 ≤ x ≤ 0.5) precursor in a controlled gaseous atmosphere.     

Potential energy of <Superscript>∞</Superscript>H<Stack><Subscript>2</Subscript><Superscript>-</Superscript></Stack>(<Superscript>2</Superscript>∑<Stack><Subscript>u</Subscript><Superscript>+</Superscript></Stack> in the bound-state region

An accurate calculation of the lowest negative electronic state of H ₂ ^- (fixed nuclei) is reported using the CCSD(T) method and doubly augmented cc-pv5z basis set. Comparison has been made with the reference data by Senekowitsch et al. [Chem. Phys. Lett. 111 (1984) 211]. Owing to larger size of the basisset and inclusion of triple excitations, no vertical shift in this work is necessary to reproduce the asymptotics of H + H ^-. In addition, the effect of basis-set truncation is estimated, based on the complete-basis-set extrapolation method. The contribution of correlated electron-proton motion to the electron-energy curve for H₂ ^– dynamics is pointed out.Dedicated to Prof. Jií Horáek on the occasion of his 60th birthday.