Localization of Surface Spectra

We study spectral properties of the discrete Laplacian H on the half-space with random boundary condition ; the V(n) are independent random variables on a probability space and λ is the coupling constant. It is known that if the V(n) have densities, then on the interval [-2(d+1), 2(d+1)] (=σ(H ₀), the spectrum of the Dirichlet Laplacian) the spectrum of H is P-a.s. absolutely continuous for all λ [JL1]. Here we show that if the random potential P satisfies the assumption of Aizenman–Molchanov [AM], then there are constants λ _d and Λ _d such that for |λ|<lambda; _d and |λ|> Λ _d the spectrum of H outside σ(H ₀) is P-a.s. pure point with exponentially decaying eigenfunctions. Received: 3 December 1998 / Accepted: 27 May 1999     

Construction of the Incipient Infinite Cluster for Spread-out Oriented Percolation Above 4 + 1 Dimensions

 We construct the incipient infinite cluster measure (IIC) for sufficiently spread-out oriented percolation on ℤ ^d × ℤ₊, for d +1 > 4+1. We consider two different constructions. For the first construction, we define ℙ ⁿ (E) by taking the probability of the intersection of an event E with the event that the origin is connected to (x,n)  ℤ ^d × ℤ₊, summing this probability over x  ℤ ^d , and normalising the sum to get a probability measure. We let n → ∞ and prove existence of a limiting measure ℙ_∞, the IIC. For the second construction, we condition the connected cluster of the origin in critical oriented percolation to survive to time n, and let n → ∞. Under the assumption that the critical survival probability is asymptotic to a multiple of n ⁻¹, we prove existence of a limiting measure ℚ_∞, with ℚ_∞ = ℙ_∞. In addition, we study the asymptotic behaviour of the size of the level set of the cluster of the origin, and the dimension of the cluster of the origin, under ℙ_∞. Our methods involve minor extensions of the lace expansion methods used in a previous paper to relate critical oriented percolation to super-Brownian motion, for d+1 > 4+1. Received: 13 December 2001 / Accepted: 11 July 2002 Published online: 29 October 2002 RID="*" ID="*" Present address: Department of Mathematics and Computer Science, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands. E-mail: rhofstad@win.tue.nl     

Time Quasi-Periodic Unbounded Perturbations¶of Schrödinger Operators and KAM Methods

We eliminate by KAM methods the time dependence in a class of linear differential equations in ℓ² subject to an unbounded, quasi-periodic forcing. This entails the pure-point nature of the Floquet spectrum of the operator H ₀+εP(ωt) for ε small. Here H ₀ is the one-dimensional Schr?dinger operator p ²+V, V(x)∼|x|^α, α <2 for |x|→∞, the time quasi-periodic perturbation P may grow as |x|^β, β <(α−2)/2, and the frequency vector ω is non resonant. The proof extends to infinite dimensional spaces the result valid for quasiperiodically forced linear differential equations and is based on Kuksin's estimate of solutions of homological equations with non-constant coefficients. Received: 3 October 2000 / Accepted: 20 December 2000     

Approach to Equilibrium in a Microscopic Model of Friction

We consider the time evolution of a disk under the action of a constant force and interacting with a free gas in the mean-field approximation. Letting V₀>0 be the initial velocity of the disk and V_∞>0 its equilibrium velocity, namely the one for which the external field is balanced by the friction force exerted by the background, we show that, if V_∞−V₀ is positive and sufficiently small, then the disk reaches V_∞ with the power law t^−(d+2), d=1,2,3 being the dimension of the physical space. The reason for this behavior is the long tail memory due to recollisions. Any Markovian approximation (or simply neglecting the recollisions) yields an exponential approach to equilibrium.     

Growth of Sobolev Norms in Linear Schrödinger Equations with Quasi-Periodic Potential

In this paper, we consider the following problem. Let iu _t +Δu+V(x,t)u= 0 be a linear Schr?dinger equation ( periodic boundary conditions) where V is a real, bounded, real analytic potential which is periodic in x and quasi periodic in t with diophantine frequency vector λ. Denote S(t) the corresponding flow map. Thus S(t) preserves the L ²-norm and our aim is to study its behaviour on H ^s (T ^D ), s> 0. Our main result is the growth in time is at most logarithmic; thus if φ∈H ^s , then

Spectral Estimates for Periodic Jacobi Matrices

 We obtain bounds for the spectrum and for the total width of the spectral gaps for Jacobi matrices on ℓ²(ℤ) of the form (Hψ) _n =a _n−1 ψ _n−1 +b _nψ _n +a _nψ _n+1 , where a _n=a _n+q and b _n=b _n+q are periodic sequences of real numbers. The results are based on a study of the quasimomentum k(z) corresponding to H. We consider k(z) as a conformal mapping in the complex plane. We obtain the trace identities which connect integrals of the Lyapunov exponent over the gaps with the normalised traces of powers of H. Received: 17 April 2002 / Accepted: 1 October 2002 Published online: 13 January 2003 Communicated by B. Simon     

A Remark on Lp-Boundedness of Wave Operators¶for Two Dimensional Schrödinger Operators

Let H=−Δ+V be a two dimensional Schr?dinger operator with a real potential V(x) satisfying the decay condition , δ > 6. Let H ₀=−Δ. We show that the wave operators are bounded in L ^p (R ²) under the condition that H has no zero resonances or bound states. In this paper the condition , imposed in a previous paper (K. Yajima, Commun. Math. Phys. 208, 125–152 (1999)), is removed. Received: 13 September 2001 / Accepted: 15 October 2001     

Harness Processes and Non-Homogeneous Crystals

We consider the Harmonic crystal, a measure on with Hamiltonian H(x)=∑ _i,j J _i,j (x(i)−x(j))²+h∑ _i (x(i)−d(i))², where x, d are configurations, x(i), d(i)∈ℝ, i,j∈ℤ ^d . The configuration d is given and considered as observations. The ‘couplings’ J _i,j are finite range. We use a version of the harness process to explicitly construct the unique infinite volume measure at finite temperature and to find the unique ground state configuration m corresponding to the Hamiltonian.     

Asymptotic Properties of Solutions to 3-Particle Schrödinger Equations

We construct a generalized Fourier transformation ℱ(λ) associated with the 3-body Schr?dinger operator H=−Δ+Σ ^a V ^a (x ^a ) and characterize all solutions of (H−λ)u= 0 in the Agmon–H?rmander space ℬ^* as the image of ℱ(λ)^*. These stationary solutions admit asymptotic expansions in ℬ^* in terms of spherical waves associated with scattering channels. Received: 20 September 2000 / Accepted: 20 May 2001     

Laser photoacoustic spectroscopy of iodine molecule: Single and two-photon absorption

Photoacoustic spectroscopy of iodine molecule has been studied in gas phase using nitrogen laser-pumped tunable dye laser. The experiment yielded the vibrational spectrum corresponding toX ¹Σ⁺(0 _g ⁺ )→B ³Π(0 _g ⁺ ) transition up to the convergence limit. The photo-acoustic spectrum in the region 17580–18850 cm⁻¹ is presented along with the vibrational analysis. Five of the vibrational bands reported earlier by Venkateswarlu, Kumar and McGlynn have been partially resolved and the structure of one of them has been analyzed and shown to be due to an overlap of (14, 2) and (12, 1) bands. The analysis was based on a comparison with the highly resolved spectrum of Gerstenkorn and Luc. The structure observed in the region 20200–20750 cm⁻¹ which is beyond the convergence limit of the transitionX ¹Σ⁺(0 _g ⁺ )→B ³Π(0 _u ⁺ ) has been analyzed as due to two-photon absorption. Most of the bands could be assigned to two transitions both originating in the ground state and terminating in two different electronic states 1 _g andE(0 _g ⁺ ), atT _e=40821 cm⁻¹ (orT ₀=41355 cm⁻¹) andT _e=41411 cm⁻¹ (orT ₀=41355 cm⁻¹) respectively.     

On the Energy Growth of Some Periodically Driven Quantum Systems with Shrinking Gaps in the Spectrum

We consider quantum Hamiltonians of the form H(t)=H+V(t) where the spectrum of H is semibounded and discrete, and the eigenvalues behave as E _n ∼n ^α , with 0<α<1. In particular, the gaps between successive eigenvalues decay as n ^α−1. V(t) is supposed to be periodic, bounded, continuously differentiable in the strong sense and such that the matrix entries with respect to the spectral decomposition of H obey the estimate ‖V(t) _m,n ‖≤ε|m−n|^−p max {m,n}^−2γ for m≠n, where ε>0, p≥1 and γ=(1−α)/2. We show that the energy diffusion exponent can be arbitrarily small provided p is sufficiently large and ε is small enough. More precisely, for any initial condition Ψ∈Dom(H ^1/2), the diffusion of energy is bounded from above as 〈H〉 _Ψ (t)=O(t ^σ ), where . As an application we consider the Hamiltonian H(t)=|p| ^α +ε v(θ,t) on L ²(S ¹,dθ) which was discussed earlier in the literature by Howland.     

Anderson Localization for Schrödinger Operators on ℤ with Strongly Mixing Potentials

In this paper we show that for a.e. x∈[ 0,2 π) the operators defined on as

A Characteristic Decay Semigroup for the Resonances of Trace Class Perturbations with Analyticity Conditions of Semibounded Hamiltonians

To asymptotic complete scattering systems {M ₊+V,M ₊} on H₊:=L²(R₊,K{\mathcal{H}}_{+}:=L^{2}(\mathbf{R}_{+},{\mathcal{K}}, d λ), where M ₊ is the multiplication operator on H₊{\mathcal{H}}_{+} and V is a trace class operator with analyticity conditions, a decay semigroup is associated such that the spectrum of the generator of this semigroup coincides with the set of all resonances (poles of the analytic continuation of the scattering matrix into the lower half plane across the positive half line), i.e. the decay semigroup yields a “time-dependent” characterization of the resonances. As a counterpart a “spectral characterization” is mentioned which is due to the “eigenvalue-like” properties of resonances.     

The Threshold Effects for the Two-Particle Hamiltonians on Lattices

For a wide class of two-body energy operators h(k) on the d-dimensional lattice ℤ^d, d≥3, k being the two-particle quasi-momentum, we prove that if the following two assumptions (i) and (ii) are satisfied, then for all nontrivial values k, k≠0, the discrete spectrum of h(k) below its threshold is non-empty. The assumptions are: (i) the two-particle Hamiltonian h(0) corresponding to the zero value of the quasi-momentum has either an eigenvalue or a virtual level at the bottom of its essential spectrum and (ii) the one-particle free Hamiltonians in the coordinate representation generate positivity preserving semi-groups.     

The Discrete Spectrum in the Gaps of the Continuous One for Non-Signdefinite Perturbations with a Large Coupling Constant

Given two selfadjoint operators A and V=V ₊ -V _-, we study the motion of the eigenvalues of the operator A(t)=A-tV as t increases. Let α>0 and let λ be a regular point for A. We consider the quantities N ₊(λ,α), N _-(λ,α), N ₀(λ,α) defined as the number of the eigenvalues of the operator A(t) that pass point λ from the right to the left, from the left to the right or change the direction of their motion exactly at point λ, respectively, as t increases from 0 to α>0. An abstract theorem on the asymptotics for these quantities is presented. Applications to Schr?dinger operators and its generalizations are given. Received: 9 April 1997 / Accepted: 26 August 1997     

Adiabatic Times for Markov Chains and Applications

We state and prove a generalized adiabatic theorem for Markov chains and provide examples and applications related to Glauber dynamics of the Ising model over ℤ ^d /nℤ ^d . The theorems derived in this paper describe a type of adiabatic dynamics for l¹(\mathbbRⁿ₊)\ell^{1}(\mathbb{R}^{n}_{+}) norm preserving, time inhomogeneous Markov transformations, while quantum adiabatic theorems deal with ℓ ²(ℂ ⁿ ) norm preserving ones, i.e. gradually changing unitary dynamics in ℂ ⁿ .     

Microhydration of the methylene blue cation in an electrospray ion source

Microhydrated methylene blue cations, MB⁺(H₂O) _n , are produced in an electrospray ion source and their size-distributions are measured as a function of the source temperature. A series of MB⁺(H₂O) _n ions is observed up to n ≃ 60. A striking feature observed in the mass spectra is that the series of hydrated ions starts at n = 4; intensities of n = 1–3 are extremely suppressed. The absence of n = 1–3 ions is well explained by the energetics concerning evaporation processes of water molecules, based on stable structures and the binding energies of MB⁺(H₂O) _n ions calculated by DFT calculations up to n = 5. MB⁺(H₂O) _n ions for n > 4 evaporate a single water molecule sequentially, while MB⁺(H₂O)₄ tends to fragment into MB⁺ and (H₂O)₄ rather than MB⁺(H₂O)₃ and an H₂O molecule. We have observed a clear magic peak at n = 24, which strongly suggests that the MB⁺(H₂O)₂₄ ion is formed by attaching a neutral (H₂O)₂₀ cage onto an MB⁺(H₂O)₄ ion.     

Semiclassical Limit for the Schrödinger Equation¶with a Short Scale Periodic Potential

We consider the dynamics generated by the Schr?dinger operator H=−?Δ+V(x)+W(ɛx), where V is a lattice periodic potential and W an external potential which varies slowly on the scale set by the lattice spacing. We prove that in the limit ɛ→ 0 the time dependent position operator and, more generally, semiclassical observables converge strongly to a limit which is determined by the semiclassical dynamics. Received: 7 February 2000 / Accepted: 7 July 2000