Analytic derivation of the Cox�CMerz rule using the MLD ��toy�� model for polydisperse linear polymers

A general constitutive formalism, the ??na?ve?? polydisperse MLD model, has been developed by Mead et al. (Macromolecules 31:7895?C7914, 1998) and Mead (Rheol Acta 46:369?C395, 2007) at both the tube coordinate level and the mathematically simplified ??toy?? level independent of the tube coordinate. The model includes constraint release generated by convection-driven chain retraction (which is equivalent to ??convective constraint release?? (CCR)), reptation, and tube contour length fluctuations. The properties of the mathematically simplified na?ve polydisperse ??toy?? MLD model are explored in linear and nonlinear steady shear flows where we analytically derive the Cox?CMerz rule relating the steady shear viscosity to the modulus of the linear viscoelastic dynamic viscosity. The Cox?CMerz rule relating the linear viscoelastic material properties and the nonlinear material properties is shown to be a direct consequence of convective constraint release. The specific feature of CCR that leads to this result is that the relaxation rate due to convective constraint release is proportional to the shear rate, $\dot{{\gamma }}$ , independent of molecular weight. The viability of this well-known empirical relationship is a direct consequence of a coincidence in the mathematical structure of the linear viscoelastic material properties and convective constraint release. There is no physical analogy or relationship between the molecular relaxation mechanisms operative in linear (diffusive relaxation) and nonlinear (convective relaxation) flow regimes. The polydisperse MLD model predictions of the individual molecular weight component contributions to the flow curve, and interpretations thereof, are effectively identical to those first postulated by Bersted (J Appl Polym Sci 19:2167?C2177, 1975, J Appl Polym Sci 20:2705?C2714, 1976). Following the theoretical developments, a limited experimental study is executed with a commercial polydisperse polystyrene melt. Nearly quantitative agreement between the polydisperse MLD theory and experimental measurements of steady-shear viscosity and dynamic moduli is achieved over a wide range of shear rates.     

Weak�CStrong Uniqueness for the Isentropic Compressible Navier�CStokes System

We prove weak–strong uniqueness results for the isentropic compressible Navier–Stokes system on the torus. In other words, we give conditions on a weak solution, such as the ones built up by Lions (Compressible Models, Oxford Science, Oxford, 1998), so that it is unique. It is of fundamental importance since uniqueness of these solutions is not known in general. We present two different methods, one using relative entropy, the other one using an improved Gronwall inequality due to the author; these two approaches yield complementary results. Known weak–strong uniqueness results are improved and classical uniqueness results for this equation follow naturally.     

On the ��principle of virtual power�� for arbitrary parts of a body

Recently, a “principle of virtual power” has been adopted to model the behavior of materials that involve multiple length scales. In these works, the “principle” is stated for arbitrary parts of a body and this arbitrariness is used, but not to its fullest extent, to draw conclusions concerning the structure of the theory that results. Here, a theorem and an example application are given to illustrate the restrictive nature of the requirement that it hold for arbitrary parts of a body and to draw attention to the full consequences that result from this requirement. Several key results that have been reported in the recent literature are incomplete, and this incompleteness has lead to superficial conclusions.     

Normal stress differences in large-amplitude oscillatory shear flow for the corotational ��ANSR�� model

Using the integral form of a nonlinear corotational model, we derive explicit analytical expressions for the zeroth, second, and fourth harmonics of the second normal stress difference in large-amplitude oscillatory shear (LAOS). This model yields an arbitrary normal stress ratio (ANSR) in any simple shearing deformation, including LAOS. This corotational ANSR model adds one parameter to the corotational Maxwell model, a time constant ?? ₀ controlling the ratio ??₂/??₁ for both the real and imaginary parts of each harmonic of the normal stress difference. The explicit analytical expressions for all harmonics of the alternating shear stress and first normal stress difference responses in LAOS match those obtained previously for the corotational Maxwell model. We evaluate the corotational ANSR model for the case of a single Maxwell relaxation time fluid.     

Instability of Streaming Viscoelastic Fluids in the Presence of ��Effective Interfacial Tension�� Through Porous Medium

The ??effective interfacial tension?? effect on the instability of the plane interface between two uniform, superposed, and streaming Rivlin?CEricksen viscoelastic fluids through a porous medium is considered. The case of two uniform streaming Rivlin?CEricksen viscoelastic fluids separated by a horizontal boundary is studied. In the absence of ??effective interfacial tension??, stability/instability of the system as well as perturbations transverse to the direction of streaming are found to be unaffected by the presence of streaming if the perturbations in the direction of streaming are ignored, whereas for perturbations in all other directions, there exists instability for a certain wave number range. ??Effective interfacial tension?? is able to suppress this Kelvin?CHelmholtz instability for small wavelength perturbations, the medium porosity reduces the stability range given in terms of a difference in streaming velocities.     

Extended double Wronskian solutions to?the?Whitham�CBroer�CKaup equations in shallow water

Whitham?CBroer?CKaup (WBK) equations describing the propagation of shallow-water waves, with a variable transformation, are transformed into a generalized Ablowitz?CKaup?CNewell?CSegur system, the bilinear forms of which are obtained via the rational transformations. Employing the matrix extension and symbolic computation, we derive types of solutions of the WBK equations through the selection of different canonical matrices, including solitons, rational solutions, and complexitons. Furthermore, dynamic properties of the solutions are discussed graphically and a novel phenomenon is observed, i.e., the coexistence of the elastic?Cinelastic interactions without disturbing each other.     

Weak in Space, Log in Time Improvement of the Lady?enskaja�CProdi�CSerrin Criteria

In this article we present a Ladyženskaja–Prodi–Serrin Criteria for regularity of solutions for the Navier–Stokes equation in three dimensions which incorporates weak L ^p norms in the space variables and log improvement in the time variable.     

Asymptotic Behavior of Solutions of the Compressible Navier�CStokes Equation Around the Plane Couette Flow

Asymptotic behavior of solutions to the compressible Navier–Stokes equation around the plane Couette flow is investigated. It is shown that the plane Couette flow is asymptotically stable for initial disturbances sufficiently small in some L ² Sobolev space if the Reynolds and Mach numbers are sufficiently small. Furthermore, the disturbances behave in large time in L ² norm as solutions of an n − 1 dimensional linear heat equation with a convective term.     

Experimental research on the rotating detonation in gaseous fuels�Coxygen mixtures

An experimental study on rotating detonation is presented in this paper. The study was focused on the possibility of using rotating detonation in a rocket engine. The research was divided into two parts: the first part was devoted to obtaining the initiation of rotating detonation in fuel–oxygen mixture; the second was aimed at determination of the range of propagation stability as a function of chamber pressure, composition, and geometry. Additionally, thrust and specific impulse were determined in the latter stage. In the paper, only rich mixture is described, because using such a composition in rocket combustion chambers maximizes the specific impulse and thrust. In the experiments, two kinds of geometry were examined: cylindrical and cylindrical-conic, the latter can be simulated by a simple aerospike nozzle. Methane, ethane, and propane were used as fuel. The pressure–time courses in the manifolds and in the chamber are presented. The thrust–time profile and detonation velocity calculated from measured pressure peaks are shown. To confirm the performance of a rocket engine with rotating detonation as a high energy gas generator, a model of a simple engine was designed, built, and tested. In the tests, the model of the engine was connected to the dump tank. This solution enables different environmental conditions from a range of flight from 16 km altitude to sea level to be simulated. The obtained specific impulse for pressure in the chamber of max. 1.2 bar and a small nozzle expansion ratio of about 3.5 was close to 1,500 m/s.     

Logarithmically Improved Regularity Criteria for the Navier�CStokes and MHD Equations

In this paper, logarithmically improved regularity criteria for the Navier–Stokes and the MHD equations are established in terms of both the vorticity field and the pressure.     

Scaling behavior of the elastic properties of non-dilute MWCNT�Cepoxy suspensions

In this paper, the network structure of multiwalled carbon nanotube (MWCNT)?Cepoxy suspensions was investigated under the influence of flow history and temperature using the scaling behavior of the linear viscoelastic properties of the concentrated suspensions above their gel point. It is shown that the suspensions have a self-similar fractal structure with the dimension of about 2.15, characteristic of weakly flocculating suspensions and their elasticity originates from inter- and intra-floc links of nanotubes. From the scaling behavior of the flow-induced storage modulus and the critical strain for the limit of linearity, it is shown that the fractal dimension and so the superstructure of the network did not change significantly under the influence of the flow history due to the initial compact structure of the network before pre-shearing. The time?Ctemperature superposition principle was verified for the CNT suspensions and the shift factor was accounted for by an Arrhenius equation. The reduced storage and loss moduli of the suspensions using the complex modulus of the neat epoxy were shown to increase with temperature revealing more inter-particle interactions as the temperature was raised. However, it was impossible to conclude on the changes of the fractal dimensions with temperature.     

On the Impossibility, in Some Cases, of the Leray�CHopf Condition for Energy Estimates

Current proofs of time independent energy bounds for solutions of the time dependent Navier–Stokes equations, and of bounds for the Dirichlet norms of steady solutions, are dependent upon the construction of an extension of the prescribed boundary values into the domain that satisfies the inequality (1.1) below, for a value of κ less than the kinematic viscosity. It is known from the papers of Leray (J Math Pure Appl 12:1–82, 1993), Hopf (Math Ann 117:764–775, 1941) and Finn (Acta Math 105:197–244, 1961) that such a construction is always possible if the net flux of the boundary values across each individual component of the boundary is zero. On the other hand, the nonexistence of such an extension, for small values of κ, has been shown by Takeshita (Pac J Math 157:151–158, 1993) for any two or three-dimensional annular domain, when the boundary values have a net inflow toward the origin across each component of the boundary. Here, we prove a similar result for boundary values that have a net outflow away from the origin across each component of the boundary. The proof utilizes a class of test functions that can detect and measure deformation. It appears likely that much of our reasoning can be applied to other multiply connected domains.     

A Statistical Representation of the Matrix�CFracture Transfer Function for Porous Media

In this article, the authors present a matrix?Cfracture transfer function where the statistical variation in geometric properties of the matrix blocks is considered. Several particular representations with hypothetical probability density functions (PDFs) for matrix block size distributions are presented, including: (a) the single-value distribution (the limiting case); (b) the uniform distribution; (c) the Gamma distribution; and (d) an approximate representation for arbitrary PDFs. An example using experimental data from the literature, along with the single-block based transfer function developed in this study, is presented demonstrating how the statistical procedure proposed in this text can be applied in practice. It is shown with this example that significant relative errors can be introduced when the statistical variance is ignored. Furthermore, two existing dual-porosity models, the Lim and Aziz model and the Zimmerman et al. model, are also considered using the experimental data. It is shown that considerable relative errors can be introduced with these two models when the effect of statistical variance is not taken into account.     

On the Navier�CStokes equations with rotating effect and prescribed outflow velocity

We consider the equations of Navier–Stokes modeling viscous fluid flow past a moving or rotating obstacle in \mathbb R^d{\mathbb R^d} subject to a prescribed velocity condition at infinity. In contrast to previously known results, where the prescribed velocity vector is assumed to be parallel to the axis of rotation, in this paper we are interested in a general outflow velocity. In order to use L ^p -techniques we introduce a new coordinate system, in which we obtain a non-autonomous partial differential equation with an unbounded drift term. We prove that the linearized problem in \mathbb R^d{\mathbb R^d} is solved by an evolution system on L^p_s(\mathbb R^d){L^p_{\sigma}(\mathbb R^d)} for 1 < p < ∞. For this we use results about time-dependent Ornstein–Uhlenbeck operators. Finally, we prove, for p ≥ d and initial data u₀ ? L^p_s(\mathbb R^d){u_0\in L^p_{\sigma}(\mathbb R^d)}, the existence of a unique mild solution to the full Navier–Stokes system.     

On Anisotropic Regularity Criteria for the Solutions to 3D Navier�CStokes Equations

In this short note we consider the 3D Navier–Stokes equations in the whole space, for an incompressible fluid. We provide sufficient conditions for the regularity of strong solutions in terms of certain components of the velocity gradient. Based on the recent results from Kukavica (J Math Phys 48(6):065203, 2007) we show these conditions as anisotropic regularity criteria which partially interpolate results from Kukavica (J Math Phys 48(6):065203, 2007) and older results of similar type from Penel and Pokorny (Appl Math 49(5):483–493, 2004).     

Modified Young��s moduli of nano-materials taking into account the scale effects and vacancies

In this paper, the modified Young??s moduli in both directions are obtained for the two-dimensional single crystal body with a square lattice by using the continuum approach of continuum mechanics and taking into account only the interaction of neighboring atoms. Separately, an expression is obtained taking into account the linear defects such as vacancies. The values of effective Young??s moduli compared with the same values for an infinite crystal lattice. Analyses show that the influences of scale effects and vacancies on the Young??s moduli are considerable. In addition, it is shown that the effective Young??s moduli have three components: the macroscopic value; factors determining the scale effect; factors determining the vacancy. The last component is analogous to the parameter of the damage of the theory of fracture.     

The Decay Rate and Higher Approximation of Mild Solutions to the Navier�CStokes Equations

In this paper, we consider v(t) = u(t) − e ^tΔ u ₀, where u(t) is the mild solution of the Navier–Stokes equations with the initial data u₀ ? L²(\mathbb Rⁿ)?Lⁿ(\mathbb Rⁿ){u_0\in L^2({\mathbb R}^n)\cap L^n({\mathbb R}^n)} . We shall show that the L ² norm of D ^β v(t) decays like t^{-\frac |b|-1 2-\frac n4}{t^{-\frac {|\beta|-1} {2}-\frac n4}} for |β| ≥ 0. Moreover, we will find the asymptotic profile u ₁(t) such that the L ² norm of D ^β (v(t) − u ₁(t)) decays faster for 3 ≤ n ≤ 5 and |β| ≥ 0. Besides, higher-order asymptotics of v(t) are deduced under some assumptions.     

The monotonicity and critical periods of periodic waves?of?the �� 6 field model

In this paper, we study the relationship between period and energy of periodic traveling wave solutions for the ?? ⁶ field model. The various topological phase portraits with periodic annulus are given by using standard phase portrait analytical technique. Some analytic behaviors (convexity, monotonicity and number of critical periods) of the period functions associated with periodic waves are investigated. We prove that the period function has exactly one critical period under certain conditions. Moreover, the numerical simulation is made. The results show that our theoretical analysis agrees with the numerical simulation.     

Extension of the Darcy�CForchheimer Law for Shear-Thinning Fluids and Validation via Pore-Scale Flow Simulations

Flow of non-Newtonian fluids through porous media at high Reynolds numbers is often encountered in chemical, pharmaceutical and food, as well as petroleum and groundwater engineering, and in many other industrial applications. Under the majority of operating conditions typically explored, the dependence of pressure drops on flow rate is non-linear and the development of models capable of describing accurately this dependence, in conjunction with non-trivial rheological behaviors, is of paramount importance. In this work, pore-scale single-phase flow simulations conducted on synthetic two-dimensional porous media are performed via computational fluid dynamics for both Newtonian and non-Newtonian fluids and the results are used for the extension and validation of the Darcy?CForchheimer law, herein proposed for shear-thinning fluid models of Cross, Ellis and Carreau. The inertial parameter ?? is demonstrated to be independent of the viscous properties of the fluids. The results of flow simulations show the superposition of two contributions to pressure drops: one, strictly related to the non-Newtonian properties of the fluid, dominates at low Reynolds numbers, while a quadratic one, arising at higher Reynolds numbers, is dependent on the porous medium properties. The use of pore-scale flow simulations on limited portions of the porous medium is here proposed for the determination of the macroscale-averaged parameters (permeability K, inertial coefficient ?? and shift factor ??), which are required for the estimation of pressure drops via the extended Darcy?CForchheimer law. The method can be applied for those fluids which would lead to critical conditions (high pressures for low permeability media and/or high flow rates) in laboratory tests.     

Bifurcation analysis in a delayed Lokta�CVolterra predator�Cprey model with two delays

In this paper, a class of delayed Lokta?CVolterra predator?Cprey model with two delays is considered. By analyzing the associated characteristic transcendental equation, its linear stability is investigated and Hopf bifurcation is demonstrated. Some explicit formulae for determining the stability and the direction of the Hopf bifurcation periodic solutions bifurcating from Hopf bifurcations are obtained by using normal form theory and center manifold theory. Some numerical simulations for supporting the theoretical results are also provided. Finally, main conclusions are given.