Analytic derivation of the Cox�CMerz rule using the MLD ��toy�� model for polydisperse linear polymers

A general constitutive formalism, the ??na?ve?? polydisperse MLD model, has been developed by Mead et al. (Macromolecules 31:7895?C7914, 1998) and Mead (Rheol Acta 46:369?C395, 2007) at both the tube coordinate level and the mathematically simplified ??toy?? level independent of the tube coordinate. The model includes constraint release generated by convection-driven chain retraction (which is equivalent to ??convective constraint release?? (CCR)), reptation, and tube contour length fluctuations. The properties of the mathematically simplified na?ve polydisperse ??toy?? MLD model are explored in linear and nonlinear steady shear flows where we analytically derive the Cox?CMerz rule relating the steady shear viscosity to the modulus of the linear viscoelastic dynamic viscosity. The Cox?CMerz rule relating the linear viscoelastic material properties and the nonlinear material properties is shown to be a direct consequence of convective constraint release. The specific feature of CCR that leads to this result is that the relaxation rate due to convective constraint release is proportional to the shear rate, $\dot{{\gamma }}$ , independent of molecular weight. The viability of this well-known empirical relationship is a direct consequence of a coincidence in the mathematical structure of the linear viscoelastic material properties and convective constraint release. There is no physical analogy or relationship between the molecular relaxation mechanisms operative in linear (diffusive relaxation) and nonlinear (convective relaxation) flow regimes. The polydisperse MLD model predictions of the individual molecular weight component contributions to the flow curve, and interpretations thereof, are effectively identical to those first postulated by Bersted (J Appl Polym Sci 19:2167?C2177, 1975, J Appl Polym Sci 20:2705?C2714, 1976). Following the theoretical developments, a limited experimental study is executed with a commercial polydisperse polystyrene melt. Nearly quantitative agreement between the polydisperse MLD theory and experimental measurements of steady-shear viscosity and dynamic moduli is achieved over a wide range of shear rates.     

On the problem of uniqueness in the theory of a rigid-plastic solid—II

The theory of plastic torsion of prismatic bars with work-hardening is reviewed and developed. Uniqueness and extremum principles proved in Part I (Hill 1956) for a general state of stress are here illustrated in relation to the torsion of a bar of hollow section.     

On the problem of uniqueness in the theory of a rigid-plastic solid—III

In previous papers in this series the question of how to select an actual mode of deformation from the set of virtual modes was answered when geometry changes can be disregarded. In the present paper that restriction is dropped. At the outset this calls for a reappraisal of what constitutes an adequate setting of the boundary-value problem when the future position of the surface is unknown in advance. A sufficient criterion for uniqueness is then established under quite general loading conditions. It is shown how to determine, in any given situation, a critical rate of workhardening above which the mode is certainly unique and below which it probably is not. The conventional tension, compression, and torsion tests are taken as illustrations.     

Instability of Streaming Viscoelastic Fluids in the Presence of ��Effective Interfacial Tension�� Through Porous Medium

The ??effective interfacial tension?? effect on the instability of the plane interface between two uniform, superposed, and streaming Rivlin?CEricksen viscoelastic fluids through a porous medium is considered. The case of two uniform streaming Rivlin?CEricksen viscoelastic fluids separated by a horizontal boundary is studied. In the absence of ??effective interfacial tension??, stability/instability of the system as well as perturbations transverse to the direction of streaming are found to be unaffected by the presence of streaming if the perturbations in the direction of streaming are ignored, whereas for perturbations in all other directions, there exists instability for a certain wave number range. ??Effective interfacial tension?? is able to suppress this Kelvin?CHelmholtz instability for small wavelength perturbations, the medium porosity reduces the stability range given in terms of a difference in streaming velocities.     

Weak in Space, Log in Time Improvement of the Lady?enskaja�CProdi�CSerrin Criteria

In this article we present a Ladyženskaja–Prodi–Serrin Criteria for regularity of solutions for the Navier–Stokes equation in three dimensions which incorporates weak L ^p norms in the space variables and log improvement in the time variable.     

About the “normal growth” approximation in the dynamical theory of phase transitions

Nonequilibrium phase transitions can often be modeled by a surface of discontinuity propagating into a metastable region. The physical hypothesis of normal growth presumes a linear relation between the velocity of the phase boundary and the degree of metastability. The phenomenological coefficient, which measures the mobility of the phase boundary, can either be taken from experiment or obtained from an appropriate physical model. This linear approximation is equivalent to assuming the surface entropy production (caused by the kinetic dissipation in a transition layer) to be quadratic in a mass flux.In this paper we investigate the possibility of deducing the normal growth approximation from the viscosity-capillarity model which incorporates both strain rates and strain gradients into constitutive functions. Since this model is capable of describing fine structure of a thick advancing phase boundary, one can derive, rather than postulate, a kinetic relation governing the mobility of the phase boundary and check the validity of the normal growth approximation.We show that this approximation is always justified for sufficiently slow phase boundaries and calculate explicitly the mobility coefficient. By using two exact solutions of the structure problem we obtained unrestricted kinetic equations for the cases of piecewise linear and cubic stress-strain relations. As we show, the domain of applicability of the normal growth approximation can be infinitely small when the effective viscosity is close to zero or the internal capillary length scale tends to infinity. This singular behavior is related to the existence of two regimes for the propagation of the phase boundary — dissipation dominated and inertia dominated.     

On the thermodynamics of the Swift–Hohenberg theory

We present the microbalance including the microforces, the first- and second-order microstresses for the Swift–Hohenberg equation concomitantly with their constitutive equations, which are consistent with the free-energy imbalance. We provide an explicit form for the microstress structure for a free-energy functional endowed with second-order spatial derivatives. Additionally, we generalize the Swift–Hohenberg theory via a proper constitutive process. Finally, we present one highly resolved three-dimensional numerical simulation to demonstrate the particular form of the resulting microstresses and their interactions in the evolution of the Swift–Hohenberg equation.     

��-convergence of energies for nematic elastomers in the small strain limit

We study two variational models recently proposed in the literature to describe the mechanical behaviour of nematic elastomers either in the fully nonlinear regime or in the framework of a geometrically linear theory. We show that, in the small strain limit, the energy functional of the first one Γ-converges to the relaxation of the second one, a functional for which an explicit representation formula is available.     

Determining the elastic equilibrium of a cylindrical shell by Vekua’s theory based on the classical elasticity theory and the theory of binary mixtures

Using the approach based on separation of variables, an analytic solution of the class of boundary value problems of the shallow cylindrical shell theory is constructed by Vekua’s method. The cylindrical shell is assumed to be rectangular in the plan. Conditions of a free support or sliding fixation are given on the sides of the rectangle; the load on the shell being arbitrary. The solution of boundary value problems is constructed using both a classical elastic medium and the theory of binary mixtures. Analysis of the constructed solutions is carried out.     

On the ��principle of virtual power�� for arbitrary parts of a body

Recently, a “principle of virtual power” has been adopted to model the behavior of materials that involve multiple length scales. In these works, the “principle” is stated for arbitrary parts of a body and this arbitrariness is used, but not to its fullest extent, to draw conclusions concerning the structure of the theory that results. Here, a theorem and an example application are given to illustrate the restrictive nature of the requirement that it hold for arbitrary parts of a body and to draw attention to the full consequences that result from this requirement. Several key results that have been reported in the recent literature are incomplete, and this incompleteness has lead to superficial conclusions.     

Local wave theory of the collision of elastic bodies. Noncentral impact—Two-dimensional problem in the ideal-fluid approximation

An approach is developed for studying the collision of two bluff elastic bodies. Noncentral impact is examined within the framework of a two-dimensional problem. Nonsteady mixed boundary conditions are formulated with an undefined moving boundary. An infinite system of Volterra integral equations of the second kind is obtained for the case when the shear modulus is equal to zero. Numerical results are presented for the case of two identical spheres. S. P. Timoshenko Institute of Mechanics, National Academy of Sciences of Ukraine, Kiev. Translated from Prikladnaya Mekhanika, Vol. 35, No. 11, pp. 79–89, November, 1999.     

Group foliation of the Lamé equations of the classical dynamical theory of elasticity

We perform the group foliation of the system of Lamé equations of the classical dynamical theory of elasticity for an infinite subgroup contained in a normal divisor of the main group. The resolving system of this foliation includes the following two classical systems of mathematical physics: the system of equations of vortex-free acoustics and the system of Maxwell equations, which allows one to use wider groups to obtain exact solutions of the Lamé equations. We obtain a first-order conformal-invariant system, which describes shear waves in a three-dimensional elastic medium. We also give examples of partially invariant solutions.