Individual (f,tA)‐ and (f,tC)‐Fullerene‐Based Nickel(II) Glycinates: Protected Chiral Amino Acids Directly Linked to a Chiral π‐Electron System

Stereoselective electrosynthesis of the first individual (^f,tA)‐ and (^f,tC)‐1,4‐fullerene derivatives with a non‐inherently chiral functionalization pattern is described, as well as the first example of an optically pure protected primary amino acid directly linked to the fullerene through only the chiral α‐amino‐acid carbon atom. An application of an auxiliary chiral nickel‐Schiff base moiety as derivatizing agent allowed separation of (^f,tA)‐ and (^f,tC)‐1,4‐fullerene derivatives using an achiral stationary phase, a separation which has never been done before.