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1.
Jacek W. Morzycki Yliana Lpez Jolanta Poszyska Rosa Santillan Leszek Siergiejczyk Andrzej Sobkowiak 《Journal of Electroanalytical Chemistry》2007,610(2):205-210
Electrooxidation of tigogenin acetate afforded two products: 3β-acetoxy-16β-hydroxy-23,24-dinor-5α-cholanoic acid lactone (2) and 20-epitigogenin acetate (3). The structure of the latter compound was confirmed by an X-ray analysis. The tentative mechanism of reaction is proposed. 相似文献
2.
The solubilities of CO2 in 2-methoxyethyl acetate, 1-methoxy-2-propyl acetate, and 3-methoxybutyl acetate were measured by isothermal synthesis method under pressures up to 1.2 MPa and at temperatures ranging from (293.15 to 333.15) K. Henry’s constant was calculated based on experimental data regression. The solubilities of CO2 were found to increase with decreased temperature and increased the methyl group to the molecular structure of the absorbent. Henry’s constant and volumetric solubility of selected absorbents at T = 298.15 K were compared with those of commercial absorbents and common solvents. 3-Methoxybutyl acetate showed the best performance by mole fraction, and 2-methoxyethyl acetate behaved the best by volumetric fraction. Based on Henry’s constant, thermodynamic properties such as Gibbs free energy of solution, enthalpy of solution, and absorption entropy of solution were determined. These properties are very essential for designing an absorption process. 相似文献
3.
Larissa Reis Brandão Inez Valéria Pagotto Yoshida Maria Isabel Felisberti Maria do Carmo Gonçalves 《Cellulose (London, England)》2013,20(6):2791-2802
Composites of cellulose acetate and polysiloxane were prepared using 3-isocyanatepropyltriethoxysilane, as a coupling agent. The structure, the thermal and dynamic-mechanical behaviors, and the morphology of the obtained composites were investigated. The composites showed phase separation which was confirmed by the presence of siloxane micro- and nano-domains dispersed in the cellulose acetate matrix, with good interfacial adhesion between the phases. The results demonstrated that the incorporation of a polysiloxane phase on a cellulose acetate matrix caused a decrease in the glass transition temperature, storage modulus and hardness. The proposed methodology was seen to be convenient for the preparation of cellulose acetate/polysiloxane composites with useful properties. 相似文献
4.
Varvara S. Stafeeva Alexander S. Mitiaev Artem M. Abakumov Alexander A. Tsirlin Artem M. Makarevich Evgeny V. Antipov 《Polyhedron》2007,26(18):5365-5369
Tin(II) acetate was prepared and its crystal structure was solved from X-ray powder diffraction data. Tin(II) acetate adopts a polymeric structure consisting of infinite Sn(CH3COO)2 chains running along the c-axis which are packed into groups of four. The acetate groups bridge the Sn atoms along the chains. The Sn atoms are asymmetrically surrounded by four oxygen atoms with two short Sn–O distances (2.170(6), 2.207(6) Å) and two longer ones (2.293(7), 2.372(8) Å). The coordination environment of the Sn atoms is completed up to a strongly distorted trigonal bipyramid SnO4E by the sterically active lone electron pair E. The coordination environment of the Sn atoms is virtually identical for Sn(CH3COO)2 in the gaseous and solid phase: the two short Sn–O bonds and the lone electron pair are located in the equatorial plane of the trigonal bipyramid and the two longer Sn–O bonds are directed towards the apical vertexes. Localization of the lone electron pair on Sn(II) was confirmed by electron localization function (ELF) analysis. The polymeric nature of the tin(II) acetate crystal structure was confirmed by a MALDI-TOF experiment. 相似文献
5.
New functional copolymers of different composition with triazole and acetate fragments in the macromolecules were synthesized by free radical copolymerization of 1-vinyl-1,2,4-triazole with vinyl acetate. The reactivity of the comonomers was studied and the monomer copolymerization constants were calculated. The structure and composition of the copolymers were determined by elemental analysis, IR and 1H NMR spectroscopy. 相似文献
6.
Rayna Bryaskova Nicolas Willet Philippe Degée Philippe Dubois Robert Jérôme Christophe Detrembleur 《Journal of polymer science. Part A, Polymer chemistry》2007,45(12):2532-2542
The cobalt-mediated radical polymerization of vinyl acetate was extended to copolymerization with 1-alkenes (ethylene or 1-octene). In agreement with the low amount of 1-alkene that could be incorporated into the copolymer, a gradient structure was predictable, but a rather low polydispersity was observed. A poly(vinyl acetate)-b-poly(octene) copolymer was also successfully synthesized, leading to a poly (vinyl alcohol)-b-poly(octene) amphiphilic copolymer upon the methanolysis of the poly (vinyl acetate) block. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2532–2542, 2007 相似文献
7.
With cellulose acetate (CA) as a base material, a novel environmentally friendly carboxylate waterborne cellulose acetate (CWCA) emulsion was synthesized via the method of self-emulsification. Taking advantage of acrylic acid, hydroxyethyl acrylate as a modifier, and isophorone diisocyanate as a bridging agent, the molecular structural design of CWCA dispersion was completed successfully, and the structure was confirmed by Fourier transform infrared spectroscopy (FTIR). In this work, the particle size and distribution of the stable CWCA dispersion with solid content of 22.6% are 115.6 and 0.158 nm, respectively. It was found that the microstructure of emulsion particles is a core-shell structure containing a hydrophilic carboxylate group as the shell and hydrophobic cellulose acetate molecular as the core. In addition, the hydrophobic behavior of CWCA film is presented as a contact angle of 109.9°. Furthermore, CWCA film provided a higher thermal decomposition temperature of 345.42 °C than that of CA film at the largest mass loss rate. 相似文献
8.
A. Kakuta M. Kuramoto M. Ohno H. Kushida A. Tanioka K. Ishikawa 《Journal of polymer science. Part A, Polymer chemistry》1980,18(11):3229-3243
A freeze-dried cellulose acetate membrane fine structure was observed with an ultrathin sectioning electron microscope. The fine structure for the top surface in this membrane could be seen by lead citrate staining ultrathin sectioning. This network structure was observed among pores, which existed in porous substrate. The pore diameter in the top surface was about 50 Å, a value that agrees approximately with the value estimated by gas permeation. 相似文献
9.
A new zinc acetate catalyst which was prepared from modified activated carbon exhibited extreme activity towards the synthesis of vinyl acetate.The activated carbon was modified by nitric acid,vitriol and peroxyacetic acid(PAA).The effect on specific area, structure,pH and surface acidity groups of carriers by modification was discussed.Amount of carbonyl and carboxyl groups in activated carbon was increased by peroxyacetic acid treatment.The productivity of the new catalyst was 14.58%higher than that of... 相似文献
10.
Development of an enantioselective membrane from cellulose acetate propionate/cellulose acetate,for the separation of trans-stilbene oxide 总被引:1,自引:0,他引:1
Lucía Z. Flores-López Jonathan Caloca Eduardo Rogel-Hernández Heriberto Espinoza-Gomez 《Cellulose (London, England)》2014,21(3):1987-1995
This paper reports the characterization of new synthesized chiral polymeric membranes, based on a cellulose acetate propionate polymer. The flux and permselective properties of the membrane were studied using 50 % ethanol solution of (R,S)-trans-stilbene oxide as feed solution. Scanning electron microscopy revealed the asymmetric structure of these membranes. The roughness of the surface was measured by atomic force microscopy. The resolution of over 97 % enantiomeric excess was achieved when the enantioselective membrane was prepared with 18 wt% cellulose acetate and 8 wt% cellulose acetate propionate in the casting solution of dimethyl formamide/N-methyl-2-pyrrolidone/acetone, at 20 °C and 55 % humidity, and a water bath at 10 °C for the gelation of the membrane. The operating pressure and the feed concentration of the trans-stilbene oxide were 275.57, 345.19, and 413.84 kPa and 2.6 mM, respectively. 相似文献
11.
《Tetrahedron: Asymmetry》2007,18(4):447-450
Enantioselective deacetylation of α-(±)-botryodiplodin acetate was successfully accomplished by means of lipase PS to afford (+)-botryodiplodin and α-(+)-botryodiplodin acetate with high enantiomeric excesses. Enzyme-mediated transesterification of the acetylated molecule with n-butanol, as well as its hydrolysis in several organic solvents, are also reported. The CD spectra of (+)-botryodiplodin and α-(+)-botryodiplodin acetate are also presented. 相似文献
12.
Funian Zhao Ali Reza Mahdavian Mohammad Bagher Teimouri Eric S. Daniels Andrew Klein Mohamed S. El-Aasser 《Colloid and polymer science》2012,290(13):1247-1255
The preparation of poly(vinyl acetate) with well-controlled structure has received a great deal of interest in recent years because of a large number of developments in living radical polymerization techniques. Among these techniques, the use of reversible addition–fragmentation chain transfer (RAFT)-mediated polymerization has been employed for the controlled polymerization of vinyl acetate due to the high susceptibility of this monomer towards chain transfer reactions. Here, a novel water-soluble N,N-dialkyl dithiocarbamate RAFT agent has been prepared and employed in the emulsion polymerization of vinyl acetate. The kinetic results reveal that the polymerization nucleation mechanism changes from homogeneous to micellar and RAFT-generated radicals can change the kinetic behavior from conventional emulsion polymerization to living radical polymerization. At higher concentrations of the modified RAFT agent, as a result of an aqueous phase reaction between RAFT and sulfate radicals, relatively more hydrophobic radicals are generated, which favors entry and propagation into micelles swollen with monomer. This observation was determined from the investigation of the polymerization rate and measurements of the average particle diameter and the number of particles per liter of the aqueous phase. Molecular weight analysis also demonstrated the participation of the RAFT agent in the polymerization in such a way as to restrict chain transfer reactions. This was determined by examining the evolution of polymer chain length and attaining higher molecular weights, even up to 50?% greater than the samples obtained from the conventional emulsion polymerization of vinyl acetate in the absence of the synthesized modified RAFT agent. 相似文献
13.
Pyrolysis, in combination with gas chromatography and nuclear magnetic resonance techniques, has been used for characterization of poly(vinyl acetate) synthesized by matrix polymerization in the presence of Sephadex gel G-50. The relation was accomplished in an inert medium and initiated by u.v. radiation. For Sephadex/vinyl acetate weight ratios around 3, the polymer has a regular structure, especially with decrease of polymerization temperatures. 相似文献
14.
Martina Štekrová Iva Paterová-Dudková Eliška Vyskočilová-Leitmannová Libor Červený 《Research on Chemical Intermediates》2012,38(8):2075-2084
Perillyl acetate is a fragrance compound that was prepared by the reaction of β-pinenoxide with acetic anhydride and using acetic acid as an acid catalyst. Several selected catalysts were tested (homogenous: phosphoric acid, boric acid, acetic acid, and citric acid; heterogeneous: zeolite USY, SSA, and montmorillonite K-10) and the reaction conditions optimized for this reaction. The yield 78.7 % of perillyl acetate was obtained. Mayol (4-isopropylcyclohexylmethanol), a valuable fragrance compound, was further obtained by a two-step synthesis from perillyl acetate. Firstly, perillyl acetate was saponified to perillyl alcohol. The yield of alcohol was 94.4 %. The last step of the entire preparation was the hydrogenation of perillyl alcohol to Mayol. The yield of the desired product of this reaction was 94.6 %. 相似文献
15.
16.
Copper(II) acetate was calorimetrically titrated with pyridine, 2-, 3- and 4-methylpyridine in absolute ethanol. The enthalpy of reaction and the equilibrium constant were determined for the adduct formation in solution for each ligand. The amines react with copper(II) acetate without breaking the dimeric structure at least in the limit of the concentration ratio|ligand|/|(CH3CO2)4Cu2|<2. 相似文献
17.
Electrodialysis (ED) shows good potential for downstream processing of acetate fermentation broths, to separate acetic acid
while unreacted glucose and other nutrients are partially recycled back to the fermenter. With conventional anion- and cation-exchange
membranes, higher current increased acetate flux, water flux, and energy consumption. Multiple ED stacks connected in series
with unequal initial volumes for a batch process maximized acetate concentration in the concentrating stream to 134g/L calcium-magnesium
acetate (CMA) in the fermentation broth at pH 6.8. Back-transport of acetate from the product into the feed stream and water
transport limit the maximum concentration possible. Cost of ED is about $295/ton acetate for the CMA broth. 相似文献
18.
Infrared data suggest that diphenylantimony acetate has a polymeric structure with bridging acetate groups which is partially broken down in carbon tetrachloride solution and completely destroyed in chloroform. The solid state structure has been determined by X-ray crystallography. The compound is triclinic, space group P, with a 10.61(1), b 13.36(1), c 11.07(1) Å, α 106.9(1), β 116.7(1), γ 93.7(1)° and Z 4. The two independent antimony atoms are linked into polymeric chains by bridging acetate groups and are in pseudo trigonal bipyramidal coordination. The two phenyl groups (mean SbC, 2.155 Å) and the antimony lone pair occupy the equatorial positions while one axial position is occupied by an oxygen of the bonded acetate group (SbO, 2.137 Å).The bridge bonds occupy the second axial position leading to distances of 2.592 and 2.513 Å to Sb(1) and Sb(2). 相似文献
19.
Hernane S. Barud Adalberto M. de Araújo Júnior Daniele B. Santos Rosana M.N. de Assuno Carla S. Meireles Daniel A. Cerqueira Guimes Rodrigues Filho Clvis A. Ribeiro Younes Messaddeq Sidney J.L. Ribeiro 《Thermochimica Acta》2008,471(1-2):61-69
Cellulose acetate (CA) is one of the most important cellulose derivatives and its main applications are its use in membranes, films, fibers, plastics and filters. CAs are produced from cellulose sources such as: cotton, sugar cane bagasse, wood and others. One promissory source of cellulose is bacterial cellulose (BC). In this work, CA was produced from the homogeneous acetylation reaction of bacterial cellulose. Degree of substitution (DS) values can be controlled by the acetylation time. The characterization of CA samples showed the formation of a heterogeneous structure for CA samples submitted to a short acetylation time. A more homogeneous structure was produced for samples prepared with a long acetylation time. This fact changes the thermal behavior of the CA samples. Thermal characterization revealed that samples submitted to longer acetylation times display higher crystallinity and thermal stability than samples submitted to a short acetylation time. The observation of these characteristics is important for the production of cellulose acetate from this alternative source. 相似文献
20.
A DRIFT spectroscopic study of potassium acetate intercalated mechanochemically activated kaolinite 总被引:2,自引:0,他引:2
Frost RL Kristóf J Makó E Horváth E 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2003,59(6):1183-1194
Kaolinite has been mechanochemically activated by dry grinding for periods of time up to 10 h. The kaolinite was then intercalated with potassium acetate and the changes in the structure followed by DRIFT spectroscopy. Intercalation of the kaolinite with potassium acetate is difficult and only the layers, which remain hydrogen bonded, are intercalated. The mechanochemical activation of the kaolinite may be followed by the loss of intensity of the hydroxyl-stretching vibrations. The intensity of the 3695 and 3619 cm(-1) bands reach a minimum after 10 h of grinding. The observation of a band at 3602 cm(-1) is indicative of the intercalation of the kaolinite with potassium acetate. The degree of intercalation decreases with mechanochemical treatment. The effect of exposure of the intercalated mechanochemically activated kaolinite to moist air results in de-intercalation. The effect of the mechanochemical treatment is loss of layer stacking, which prevents the intercalation of the kaolinite. 相似文献