核磁共振任意波形发生器的研制

任意波形发生器（又叫函数发生器）作为一种通用的信号源,在物理、电子、计算机等领域有着广泛的应用. 本文提出了一种不依赖PC机总线的、完全独立的、 可用于低场磁共振成像的多用途任意波形发生器（Arbitrary Waveform Generator, AWG）设计方案,围绕着这种方案,研制了80 MHz通用磁共振任意波形发生器. 并提供了实际测试数据和成像实验结果,对研制情况和实验结果进行了总结和讨论.     

MATLAB平台下声卡任意波形发生器的设计

介绍了一种基于MATLAB GUI的虚拟仪器设计方法.系统以手绘波形为信号数据源.通过调用MATLABDAQ工具控制声卡D/A转换器,实现了声卡在音频范围内任意波形信号的输出.     

近满壳偶偶核闯入态的微观描述

对于近满壳的偶偶核,以正常组态、质子对2p-2h激发组态及核子-核子有效相互作用为出发点,本文提出一种研究闯入态性质和组态混合的理论方法.     

偶偶 Ra 同位素的八极形变研究

用反射不对称的相对论平均场理论(RAS-RMF)对偶偶Ra同位素的八极形变进行了系统研究,并与实验数据和有限力程小液滴模型(FRDM)结果进行了比较.结果表明：RAS-RMF理论很好地描述了Ra同位素的基态性质,计算的结合能、双中子分离能和形变与实验数据和FRDM一致.RAS-RMF理论获得的中子、质子密度分布清晰地展现出偶偶Ra同位素由球形逐渐转变为八极形变,到四极形变的过程,与实验观察的八极形变不稳定现象一致.     

偶偶 Ra 同位素的八极形变研究

用反射不对称的相对论平均场理论(RAS-RMF)对偶偶Ra同位素的八极形变进行了系统研究,并与实验数据和有限力程小液滴模型(FRDM)结果进行了比较.结果表明：RAS-RMF理论很好地描述了Ra同位素的基态性质,计算的结合能、双中子分离能和形变与实验数据和FRDM一致.RAS-RMF理论获得的中子、质子密度分布清晰地展现出偶偶Ra同位素由球形逐渐转变为八极形变,到四极形变的过程,与实验观察的八极形变不稳定现象一致. 关键词： 反射不对称平均场(RAS-RMF) 八极形变 偶偶核     

MRI梯度波形发生器研究进展

成像体素空间位置的准确编码对于磁共振成像（MRI）的空间定位至关重要.为了保证空间编码的准确性,获得高性能的梯度磁场是关键.梯度波形发生器是产生梯度磁场的核心部件,本文简要介绍了梯度波形发生器的工作原理和组成部分,总结了近二十年来基于不同设计方案设计的梯度波形发生器的研究进展,详细探讨了梯度波形预加重的实现方法,并对梯度波形发生器未来的研究和发展方向进行了展望.     

基于DSP技术的梯度波形发生器

提出一种用于磁共振成像的数字预加重梯度波形发生器. 它基于PCI总线,特点是采用数字信号处理（DSP）技术,以及高精度、高转换速率、低群延时的数模转换(DA)芯片. 因为所选DSP具有很强的实时运算能力,所以此梯度波形发生器能够包含5个不同时间常数及相应幅度的预加重信号处理单元. 本文给出了详细的设计过程,并给出了实验结果.     

近满壳偶偶核闯入态及组态混合的微观分析

本文应用一种描述近满壳偶偶核的闯入态的微观理论,计算了对应于¹¹⁰Cd组态的低能谱及波函数.系统地考察了各种因素对闯入态形成的影响、产生组态混合的机制及强度.通过与唯象工作的比较,考察了微观s-d哈密顿量.     

相对论平均场框架下偶-偶核奇-偶核计算误差的系统研究

在相对论平均场理论框架下, 用NL-3和NL-Z两组相互作用参数研究了4个同位素链²⁸Ni,⁵⁴Xe,⁷⁸Pt,⁹⁴Pu的基态性质. 发现,在Hatree近似下奇A核结合能理论计算值与实验值的相对误差反而普遍比偶偶核小. 这说明用相对论平均场理论,即使不考虑矢量介子的空间分量,仍可以比较可靠地计算奇A核结合能.     

一种具有自触发功能的高精度梯度波形发生器

提出一种具有自触发功能的高精度梯度波形发生器,其主要特点在于其采用了高精度（24 位）DAC,并具有自触发功能,使梯度波形发生器能独立于脉冲序列发生器工作,从而解决了高精度DAC群延时的问题.     

FX-100核磁共振谱仪上的MLEV-16宽带去偶实验

本文叙述了在FX-100核磁共振谱仪上进行的MLEV-16宽带去偶实验。实验表明:其去偶范围大大增加,效率明显提高,对常规质子去偶的¹³C谱实验所需要的去偶场B₂比谱仪原有的噪声去偶系统的去偶场B₂降低约一个数量级。并且,用谱仪原有的去偶功率实现了¹³C{¹⁹F}氟宽带去偶的¹³C谱的观测,去偶范围达14KHz,可以满足大部分氟化物的¹³C核磁共振研究的要求。     

Interference of homonuclear decoupling and exchange in the solid-state NMR of perfluorocyclohexane

We observe an interference between RF irradiation used for homonuclear decoupling of 19F and conformational exchange in the 13C spectrum of perfluorocyclohexane. We show that these effects can be readily reproduced in simulation, and characterise their dependence on the various NMR and experimental parameters. Their application to observing exchange rates on the kHz timescale is evaluated with respect to T(1rho) measurements and the connections between the two approaches established. The implications for experiments that use homonuclear decoupling of 1H to resolve 1J(CH)couplings in the solid-state are also evaluated in detail.     

Analyses of the complex proton NMR spectra: determination of anisotropic proton chemical shifts of oriented molecules by a two dimensional experiment

NMR spectra of molecules oriented in the liquid crystalline media provide information on the molecular structure and order parameter. However, the numerical iterative analysis of the proton spectra of strongly coupled spins is difficult and time consuming. Such analysis is simplified if nearly accurate starting parameters are available. One such parameter is the chemical shift which in the oriented media is very different from the isotropic values due to anisotropic contributions. In this study, we have explored the possibility of obtaining chemical shifts in the oriented phase to aid the analysis of the spectra. A two dimensional experiment in which FSLG decoupling employed during the t1 period eliminates the homonuclear dipolar couplings and retains only the chemical shifts has been implemented. Experiments on the molecule cis,cis-mucononitrile demonstrate that the chemical shifts obtained by this procedure are nearly the same as the chemical shifts derived by iterative analysis of the one dimensional spectrum of the molecule following the standard procedure. The method has also been used to analyse the spectrum of 1-iodopropane using the chemical shifts obtained from the proposed experiment as the starting parameters.     

Heteronuclear decoupling interference during symmetry-based homonuclear recoupling in solid-state NMR

We examine the influence of continuous-wave heteronuclear decoupling on symmetry-based double-quantum homonuclear dipolar recoupling, using experimental measurements, numerical simulations, and average Hamiltonian theory. There are two distinct regimes in which the heteronuclear interference effects are minimized. The first regime utilizes a moderate homonuclear recoupling field and a strong heteronuclear decoupling field; the second regime utilizes a strong homonuclear recoupling field and a weak or absent heteronuclear decoupling field. The second regime is experimentally accessible at moderate or high magic-angle-spinning frequencies and is particularly relevant for many realistic applications of solid-state NMR recoupling experiments to organic or biological materials.     

强噪声下已知信号的模糊神经网络识别

以计算机模拟为基础研究了用模糊神经网络方法对被噪声严重污染的已知信号进行识别的问题,研究表明,将模糊隶属函数和BP神经网络相结合对信噪比极低的信号有较强的识别能力,本文还从实用性角度讨论了这一识别方法的可行性,这为强噪声下的磁共振信号识别问题提供了新途径.     

物料混合过程的自适应解耦控制

用来描述水泥生料混合系统静态特性的输入输出模型是多变量耦合且非线性的.提出一种可使该系统实现线性化和部分解耦的方案.继而设计了基于线性化解耦模型的自适应控制系统,该系统引入基于改进加权最小二乘法的成分估计器,实现高精度、强鲁棒控制.给出了仿真及实际运行结果,并与常规自适应控制作了对比.     

A new decoupling method for accurate quantification of polyethylene copolymer composition and triad sequence distribution with 13C NMR

(13)C NMR is a powerful analytical tool for characterizing polyethylene copolymer composition and sequence distribution. Accurate characterization of the composition and sequence distribution is critical for researchers in industry and academia. Some common composite pulse decoupling (CPD) sequences used in polyethylene copolymer (13)C NMR can lead to artifacts such as modulations of the decoupled (13)C NMR signals (decoupling sidebands) resulting in systematic errors in quantitative analysis. A new CPD method was developed, which suppresses decoupling sidebands below the limit of detection (less than 1:40,000 compared to the intensity of the decoupled signal). This new CPD sequence consists of an improved Waltz-16 CPD, implemented as a bilevel method. Compared with other conventional CPD programs this new decoupling method produced the cleanest (13)C NMR spectra for polyethylene copolymer composition and triad sequence distribution analyses.     

对流方程的差分格式

用待定系数法构造了对流方程的一些新的差分格式.     

对流扩散方程的一些单调性差分格式

本文分析了逆风格式、格式和修正Dennis格式随网格Reynolds数变化的性质,构造了相应的半隐差分格式,它们具有无条件稳定性和无条件单调性。数值例子说明这些格式可以计算高Reynolds的定态流动问题。     

自动线匹配光泵浦方案的研究

通过对激光驱动Cu等离子体实验的分析,认为对于自动线匹配光泵浦类Ne铜,在适当的条件下能够达到粒子数反转;而能否获得可观的增益,取决于两等离子体的耦合方式及驱动泵浦靶的激光功率密度是否接近最佳值。