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1.
The through-hole porous anodic aluminum oxide (AAO) membranes were fabricated by a simple two-step anodization of aluminum in 0.3 M oxalic acid, 0.3 M sulfuric acid, and 2 wt.% phosphoric acid solutions under different operating conditions followed by the removal of the remaining Al substrate and the pore opening/widening process. The effect of duration of the second anodizing step on the thickness of the porous oxide layer and the influence of other anodizing conditions such as applied voltage, type of electrolyte, and purity of the substrate on the rate of porous oxide growth were discussed in detail. The pore opening procedure for all synthesized membranes was optimized, and the influence of the duration of chemical etching on structural features of AAO membranes, especially pore diameter, was studied. The rate of pore widening was established for AAO membranes formed in various anodizing electrolytes and for different temperatures of 5 wt.% H3PO4 used for alumina dissolution. 相似文献
2.
阳极氧化法制备具有纳米多孔结构的阳极氧化铁膜因其潜在的应用价值而倍受关注。然而,在阳极氧化过程中多孔结构的形成机制至今尚不清楚。本文结合电流密度-电位响应( I- V曲线)及法拉第定律的推导,分析了形成纳米多孔阳极氧化铁膜的过程中阳极电流的组成。结果表明,离子电流(导致离子迁移形成氧化物)和电子电流(导致析出氧气)共同组成阳极电流,并且纳米多孔阳极氧化铁膜的形成与两种电流的占比相关。分段式氧化物之间的空腔以及在阳极氧化初期纳米孔道上覆盖的致密膜,表明氧气泡可能是从氧化膜内部析出。此时,阳离子和阴离子绕过作为模具的氧气泡实现传质,最终导致纳米多孔结构的形成。此外,在阳极氧化铁膜形貌演变过程中,氧气泡不断向外溢出会使表面氧化物被冲破,导致表面孔径不断增大。 相似文献
3.
In this paper, we fabricate two kinds of anodic aluminum oxide (AAO) films with controllable nanopore size by changing electrolytes and electrolytic parameters. The first AAO film with a four-layer structure was fabricated by sequential anodization of aluminum in aqueous solution of H 2SO 4, H 2C 2O 4, malonic acid, and tartaric acid at different anodic oxidation voltages. The average pore diameter of the as-prepared AAO film is 25 nm in the first layer, 54 nm in the second layer, 68 nm in the third layer, and 88 nm in the fourth layer, respectively. The pore densities of each layer decrease downwards to Al substrate, which are 300?×?10 8, 100?×?10 8, 21?×?10 8, and 6.9?×?10 8 cm ?2, respectively. Furthermore, another AAO film with periodically changed pore diameter was fabricated by alternating anodization of aluminum in aqueous solution of H 3PO 4 and tartaric acid under galvanostatic mode. The anodization processes present approximately identical best ordering voltage (195 V) in H 3PO 4 and tartaric acid under galvanostatic mode. The pore diameter with periodic change can be enlarged through a pore-widening treatment. Both AAO films with special nanopore structures can be used not only as templates for preparing nano-array materials whose pore diameter presents periodic change or gradual increase, but also as nanofilters to separate materials in some special media. 相似文献
4.
迄今,人们已采用许多方法制备纳米材料,如刻蚀技术、化学法和模板法等[1].其中,引起科学界广泛兴趣的模板法,在合成有序纳米材料上占有极其重要的地位.常用的模板有两种,一种是有序孔洞阳极氧化铝(Anodic Aluminum Oxide,AAO)模板[2],另一种是含有孔洞无序分布的高分子模板.AAO模板具有耐高温,绝缘性好,孔洞分布均匀有序,而且大小可控等特点[3].可以利用 AAO模板来制备各种纳米纤维和纳米管,如导电聚合物[4]、金属[5]、半导体[6]、碳[7]和其它一些材料.由于纳米材料的应用具有广阔的前景,如光催化、电化学、酶固定等方面,因而不同材料纳米线的制备备受关 相似文献
5.
电子束蒸发在硅衬底上的多晶铝膜多孔型阳极氧化得到的多孔列阵排布与体材料单晶铝氧化结果比较,有序度存在很大差异,导致这种差异的原因,除了氧化时间、应用电压、电解液等电化学参数外,新引入的结晶度将作为一重要因数影响自组织过程.结晶度的影响主要反映在晶粒间界区域相比于晶粒内部存在的铝原子浓度和阳极氧化反应速度涨落,这种涨落将通过干扰孔底电场的分布,对自组织过程产生微扰,由于微扰具有实时和随机性质,将使铝膜阳极氧化不再象体材铝那样,可以通过单一延长时间来最终改善孔排布的有序度. 相似文献
6.
Porous anodic alumina membranes with Y-branched and double-branched nanopores were fabricated by the stepwise reduction of anodizing potential during the second step of anodization carried out in 0.3 M oxalic acid. The process of nanoporous layer formation and influence of anodizing parameters on structural features of as-obtained anodic aluminum oxide (AAO) membranes were discussed in detail. The pore rearrangement process occurring after the potential decrease was investigated on the basis of the current density vs. time curves, and results were correlated with the field-emission scanning electron microscope images of the pore bottoms taken after different anodizing durations. It was found that the reorganization of nanopores begins after 600 and 500 s from the time of the potential reduction to 42 and 30 V and the process seems to be completed after about 900 and 800 s, respectively. The through-hole AAO membranes were used as templates for the fabrication of gold and polystyrene nanowires via electrochemical deposition and simple immersing in the polymer solution, respectively. The arrays of hierarchically branched nanowires were synthesized, and the dimensions of nanowires were consistent with the shape and structure of used AAO templates. 相似文献
7.
The initial stage of pore formation and the growth process in anodic aluminum oxide (AAO) template have been carefully investigated. Detailed features are found concerning the nanostructure configuration formed on the electropolished aluminum foil and the additional fine structures in the first and second anodization resulting from the current limitation effect during the beginning time of about 2 s. It sheds new light onto the mechanism of the pore-organizing process of AAO templates. 相似文献
8.
The effects induced by an external homogeneous magnetic field on the oxide film growth on aluminum in aqueous solutions of oxalic and sulfuric acid and on surface morphology of the alumina films were studied. Aluminum films of 100 nm thickness were prepared by thermal evaporation on SiO 2/Si and glass-ceramic substrates. The pore diameter for oxalic acid alumina films on the SiO 2/Si substrate decreased by 0.8 nm, the interpore distance by 5.9 nm, and cell diameter by 6.9 nm if a magnetic field of 0.5 T was applied. When aluminum was anodized in sulfuric acid on the same substrate, the significant changes in parameters of porous structure of alumina, which were similar to the ones in oxalic acid, are firstly observed in stronger magnetic fields (of 0.7 T). On the basis of data obtained in this study and of previous investigation on the negative space charge and thermally activated defects in anodic alumina, we concluded that the intensity of the magnetic field is associated with energy of electron traps and that the changes of cell diameter characterize the trap concentration. The energy of electron traps in oxalic acid alumina films was proved to be smaller than the one in films formed in sulfuric acid, but the concentration of traps was of the same order of magnitude. When the substrate was replaced with the glass-ceramic one, the pore diameter in oxalic acid alumina films increased to ca. 17.6 nm. 相似文献
9.
The through-hole porous anodic aluminum oxide (AAO) membranes were fabricated by a simple two-step anodization of aluminum in 0.3?M oxalic acid, 0.3?M sulfuric acid, and 2?wt.% phosphoric acid solutions under different operating conditions followed by the removal of the remaining Al substrate and the pore opening/widening process. The effect of duration of the second anodizing step on the thickness of the porous oxide layer and the influence of other anodizing conditions such as applied voltage, type of electrolyte, and purity of the substrate on the rate of porous oxide growth were discussed in detail. The pore opening procedure for all synthesized membranes was optimized, and the influence of the duration of chemical etching on structural features of AAO membranes, especially pore diameter, was studied. The rate of pore widening was established for AAO membranes formed in various anodizing electrolytes and for different temperatures of 5?wt.% H 3PO 4 used for alumina dissolution. 相似文献
10.
Nanoporous anodic aluminum oxide, which was obtained by two-step electrochemical anodization aluminum process, showed strong physical adsorption capability of tetrahydroxyflavanol (THOF). The fluorescence peak of THOF was also dependent on its environment because the surrounding electron field affected the molecule luminescence in nanoporous alumina. The effect of nanometer size on adsorption and fluorescence of THOF is observed. The mechanism is primarily discussed. 相似文献
11.
通过磁控溅射并引入钛保护层, 利用在0.3 mol·L -1硫酸中20 V电压下二次阳极氧化, 在氧化铟锡(ITO)导电玻璃衬底上直接制备了超薄(约140 nm, 为阳极氧化前Al厚度的一半)、大面积(约4 cm 2)的多孔阳极氧化铝(AAO). 扫描电子显微镜结果表明生成的微孔与衬底垂直, 孔径和孔间距分别约为30和60 nm. 我们发现钛保护层的作用是提高了Al层的附着性并且防止ITO被腐蚀, 在此体系中钛不能被其它的金属如铬、金、银或铜代替. 紫外-可见光谱透过率结果显示在阳极氧化过程中Ti被氧化成为透明的TiO 2, 利用10-20 nm的钛保护层以及二次阳极氧化过程, 能够保证高透明度. 在ITO上直接制备的这种透明、有序的AAO纳米结构在光子学、光伏领域和纳米制备等方面具有潜在应用. 相似文献
12.
多孔铝氧化物薄膜;电解质强度;位错对阳极氧化铝多孔薄膜纳米孔阵列结构的影响 相似文献
13.
提出了在铝阳极氧化膜的生长过程中存在两种力的作用,一种是在阻挡层形成时就已经存在的由于基体铝与氧化铝之间晶格不匹配产生的内应力的作用,另一种是随着纳米孔的形成,存在于纳米孔内壁的表面张力的作用.铝阳极氧化膜纳米孔阵列的自组织过程是在这两种力的共同作用下进行的.这两种力的大小随着纳米孔形貌的变化而改变,当铝阳极氧化膜中的纳米孔呈规则的六角排列时,这两种力达到平衡,此时体系的能量也最低. 相似文献
14.
The kinetics of growth of porous anodic alumina films in pure H 2SO 4, in mixtures of H 2SO 4 and Al 2(SO 4) 3 and in Al(HSO 4) 3, NaHSO 4 and KHSO 4 electrolytes were studied. The latent physicochemical processes at the pore base surface/electrolyte interface, across the
barrier layer, inside the metal/oxide interface and at the pore wall surface/electrolyte interface and their mechanisms were
revealed. High field strength equations were formulated describing the ionic migrations from the pore base surface. These
showed that, at constant current density and temperature, the inverse of the pore base square diameter depends linearly on
the inverse of the H + activity in the anodizing solution and that this diameter increases with H + activity, in agreement with the experimental results. The mechanism of electrolyte anion incorporation inside the barrier
layer and the real distribution of the anion concentration across both the barrier layer and pore walls were deduced. The
effects of the different kinds and concentrations of the electrolyte anions and cations on both the above processes and their
mechanisms were also examined.
Electronic Publication 相似文献
15.
Overall kinetic and potentiometric studies of the growth of porous anodic alumina films in saturated H 2SO 4+Al 2(SO 4) 3 electrolyte showed non-saturation conditions inside the pores and supersaturation conditions at the pore surface/electrolyte
interface where the field and the solid surface catalyse the formation of colloidal Al 2(SO 4) 3 micelles. Suitable high-strength field thermodynamically sustained electrochemical and chemical kinetic equations were formulated.
It was shown that the diameter and surface fraction of charge exchange at the pore bases, the real pore wall surface fraction
where oxide dissolution occurs, and its rate are strongly affected by the conditions. The mechanism of growth and structure
of the films are quite different from those in H 2SO 4. A mechanism of regular film growth is imposed and the critical current density, above which pitting appears, strongly increases.
The formulated theory may predict improved or new Al anodizing technologies.
Electronic Publication 相似文献
16.
An Au thin film, which was sputter-deposited on an Al substrate, was potentiostatically anodized in oxalic acid. The Au film was first anodized and a spongelike nanoporous film grew down to the interface between Au and Al. Then, the Al was anodized and a very thin and fine nanoporous alumina film was formed underneath the nanoporous Au. Under the same anodization conditions, the current density for Al was ~ 40 μA cm − 2, less than 1% of that for Au (~ 30 mA cm − 2). The growth rates of the nanoporous films were ~ 0.7 nm/min for Al and 26 nm/min for Au, indicating that the growth rate of nanoporous alumina was less than 3% of that of nanoporous Au. Al is suitable as the substrate for preparing nanoporous Au films because the electrochemical reactions of both the electrolyte and the substrate are significantly suppressed when the nanopores penetrate Au and the electrolyte reaches the substrate. 相似文献
17.
The homogeneous chemical composition ceria–zirconia–alumina (Ce–Zr–Al–O x) nano-alloy were successfully synthesized by surfactant-assisted parallel flow co-precipitation method and applied as supports for low temperature CO oxidation. The experiment conditions were studied in detailed. At 0.92 wt% Pd loading, 30,000 ppm CO could be completely oxidized to CO 2 at 30 °C at a WHSV of 4,380 ml g ?1 h ?1 over the Pd/Ce–Zr–Al–O x (n Ce:n Zr = 3:1) catalyst. Pd/Ce–Zr–Al–O x catalysts were systematical studied by mean of BET, XRD and TEM analysis. XRD characterization showed that zirconium element entered into cubic structure of ceria and leaded to structure distortion. Addition of aluminum increased specific surface area of ceria–zirconia solid solution substantially. The average pore diameter of Ce–Zr–Al–O x support palladium catalysts were the key impact factor for CO oxidation. When the Pd/Ce–Zr–Al–O x catalysts had highly dispersed palladium nanoparticles, large average pore diameter, suitable surface area and pore volume, the activity of CO oxidation was the best. 相似文献
18.
The electrodes (anode and cathode) have an important role in the efficiency of a microbial fuel cell (MFC), as they can determine the rate of charge transfer in an electrochemical process. In this study, nanoporous gold electrode, prepared from commercially available gold-made compact disk, is utilized as the anode in a two-chamber MFC. The performance of nanoporous gold electrode in the MFC is compared with that of gold film, carbon felt and acid-heat-treated carbon felt electrodes which are usually employed as the anode in the MFCs. Electrochemical surface area of nanoporous gold electrode exhibits a 7.96-fold increase rather than gold film electrode. Scanning electron microscopy analysis also indicates the homogeneous biofilm is formed on the surface of nanoporous gold electrode, while the biofilm formed at the surface of acid-heat-treated carbon felt electrode shows rough structure. Electrochemical studies show although modifications applied on carbon felt electrodes improve its performance, nanoporous gold electrode, due to its structure and better electrochemical properties, acts more efficiently as the MFC’s anode. The maximum power density produced by nanoporous gold anode is 4.71 mW m ?2 at current density of 16.00 mA m ?2, while this value for acid-heat-treated carbon felt anode is 3.551 mW m ?2 at current density of 9.58 mA m ?2. 相似文献
19.
A procedure based on the high-field mechanism of the growth of anodic oxides was developed in order to evaluate the morphological
features of porous layers. Since the thickness of the barrier film, separating the porous layer from the metal, does not change
during the steady-state growth of an anodic porous layer, the rate of displacement of the metal-oxide interface to the metal
direction must be equal to the rate of displacement of the pore base to the oxide direction. As a consequence, porosity can
be expressed in terms of the ratio i
diss/ i
ion, where i
diss is the dissolution current density at the pore base, and i
ion is the ionic current density at the metal-oxide interface. Pore diameter can be determined from geometrical considerations,
while average pore population can be obtained from the ratio of porosity to the average surface area of a single pore. This
procedure was checked by comparison with experimental results relative to membranes prepared in various conditions. The satisfactory
agreement between theoretical and experimental findings indicates that porosity can be evaluated by current density data and
vice-versa. Therefore, anodic alumina membranes may be tailored for different applications by choosing operative conditions
giving the desired value of i
diss/ i
ion. 相似文献
20.
Abstract Aluminium anodization behavior in ammonium sebacate solution ( w = 4%) in ethylene glycol, and in several H 3PO 4-containing electrolytes, has been investigated. A new mechanism is proposed for the formation of porous anodic films. The
model emphasizes the close relationship between pore generation and oxygen evolution. PO 4
3− ions incorporated in the anodic films behave as the primary source of avalanche electrons. It is the avalanche electronic
current through the barrier film that causes oxygen evolution during anodization. When growth of anodic oxide and oxygen evolution
occur simultaneously at the aluminium anode, cavities or pores are formed in the resulting films. Accordingly, the mechanisms
of growth of barrier and porous films are not very different in nature. These findings are a decisive new step towards full
understanding of the nature of anodic alumina films.
Graphical abstract
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